Citation: LI Xiang-Hong, XIE Xiao-Guang. Inhibition Effect of Pyrimidine Derivatives on the Corrosion of Steel in Hydrochloric Acid Solution[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2221-2231. doi: 10.3866/PKU.WHXB201307301 shu

Inhibition Effect of Pyrimidine Derivatives on the Corrosion of Steel in Hydrochloric Acid Solution

LI Xiang-Hong ^1,2, ,
XIE Xiao-Guang ¹

1.
1 School of Chemical Science and Technology, Yunnan University, Kunming 650091, P. R. China;
2 Faculty of Science, Southwest Forestry University, Kunming 650224, P. R. China

Received Date: 22 May 2013
Available Online: 30 July 2013
Fund Project: 国家自然科学基金(51361027)资助项目 (51361027)

The inhibition effect of two pyrimidine derivatives, 2- hydroxypyrimidine (HP) and 2- mercaptopyrimidine (MP), on the corrosion of cold rolled steel (CRS) in 1.0-5.0 mol·L^-1 HCl is investigated by mass loss, potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS), and quantum chemical calculations. The results show that HP and MP are both od inhibitors of corrosion of CRS in 1.0 mol·L^-1 HCl solution. The adsorption of these inhibitors onto the CRS surface obeys the Langmuir adsorption isotherm. Inhibition efficiency increases with inhibitor concentration, and decreases with hydrochloric acid concentration. The thermodynamic parameters of adsorption (adsorption equilibrium constant (K) and adsorption free energy (ΔG⁰)) and kinetic parameters of corrosion (apparent activation energy (E_a), pre-exponential factor (A), corrosion rate constant (k), and kinetic reaction constant (B)) are also calculated. Based on these parameters, the mechanism of inhibition is discussed. Potentiodynamic polarization curves show that HP and MP act as mixed-type inhibitors. EIS exhibit one capacitive loop, and the charge transfer resistance increases with inhibitor concentration. The results of quantum chemical calculations indicate that MP exhibits higher adsorptive ability than HP, which is in od agreement with the experimental data.
- Corrosion inhibitor,
- 2-Hydroxypyrimidine,
- 2-Mercaptopyrimidine,
- Steel,
- Hydrochloric acid,
- Adsorption,
- Quantumchemical calculation
1. [1]
  
  (1) Li, X. H.; Deng, S. D.; Fu, H. Acta Phys. -Chim. Sin. 2011, 27,2841. [李向红, 邓书端,付惠.物理化学学报, 2011, 27,2841.] doi: 10.3866/PKU.WHXB20112841
2. [2]
  (2) Bentiss, F.; Traisnel, M.; Gengembre, L.; Lagrenée, M. Appl. Surf. Sci. 1999, 152, 237. doi: 10.1016/S0169-4332(99)00322-0
3. [3]
  (3) Yan, Y.; Li, W. H.; Cai, L. K.; Hou, B. R. Electrochim. Acta2008, 53, 5953. doi: 10.1016/j.electacta.2008.03.065
4. [4]
  (4) Wang, L. J. Yunnan Univ. 2001, 23, 203. [王林.云南大学学报, 2001, 23, 203.]
5. [5]
  (5) Monticell, C.; Brunoro, G.; Frignani, A. J. Electrochem. Soc.1992, 139, 706.
6. [6]
  (6) Lin, Z. H.; Wang, F. C.; Tian, Z. Q. Acta Phys. -Chim. Sin. 1992,8, 87. [林仲华, 王逢春,田中群. 物理化学学报, 1992, 8, 87.]doi: 10.3866/PKU.WHXB19920116
7. [7]
  (7) Zucchi, F.; Trabanelli, G.; Brunoro, G. Mater. Corros. 1993, 44,264.
8. [8]
  (8) Wang, L. Corrosion Sci. 2001, 41, 1637.
9. [9]
  (9) Li, X. H.; Deng, S. D.; Fu, H. Chin. J. Appl. Chem. 2012, 29,209. [李向红, 邓书端,付惠.应用化学, 2012, 29, 209.]
10. [10]
  (10) Makhlouf, M. T.; El-Shahawy, A. S.; El-Shatory, S. A. Mater. Chem. Phys. 1996, 43, 153. doi: 10.1016/0254-0584(95)01611-W
11. [11]
  (11) Li, X. H.; Deng, S. D.; Fu, H. Corrosion Sci. 2009, 51, 1344.doi: 10.1016/j.corsci.2009.03.023
12. [12]
  (12) Kokalj, A.; Peljhan, S.; Finšgar, M.; Milošev, I. J. Am. Chem. Soc. 2010, 132, 16657. doi: 10.1021/ja107704y
13. [13]
  (13) Feng, L. J.; Yang, H. Y.; Wang, F. H. Electrochim. Acta 2011,58, 427. doi: 10.1016/j.electacta.2011.09.063
14. [14]
  (14) El Adnani, Z.; Mcharfi, M.; Sfaira, M.; Benzakour, M.;Benjelloun, A. T.; Ebn Touhami, M. Corrosion Sci. 2013, 68,223. doi: 10.1016/j.corsci.2012.11.020
15. [15]
  (15) Zhang, J.; Zhao, W. M.; Guo, W. Y.; Wang, Y.; Li, Z. P. Acta Phys. -Chim. Sin. 2008, 24, 1239. [张军,赵卫民,郭文跃,王勇,李中谱. 物理化学学报, 2008, 24, 1239.] doi: 10.3866/PKU.WHXB20080720
16. [16]
  (16) Materials Studio 4.1; Accelrys Inc.: San Die , CA, 2006.
17. [17]
  (17) Becke, A. D. J. Chem. Phys. 1988, 88, 2547. doi: 10.1063/1.454033
18. [18]
  (18) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785. doi: 10.1103/PhysRevB.37.785
19. [19]
  (19) Klamt, A.; Schüürmann, G. J. Chem. Soc. Perkin. Trans. 1993,2, 799.
20. [20]
  (20) Cano, E.; Polo, J. L.; Iglesia, A. L.; Bastidas, J. M. Adsorption2004, 10, 219. doi: 10.1023/B:ADSO.0000046358.35572.4c
21. [21]
  (21) Zhang, F.; Tang, Y. M.; Cao, Z. Y.; Jing, W. H.; Wu, Z. L.; Chen,Y. Z. Corrosion Sci. 2012, 61, 1. doi: 10.1016/j.corsci.2012.03.045
22. [22]
  (22) Behpour, M.; Ghoreishi, S. M.; Soltani, N.; Salavati-Niasari, M.Corrosion Sci. 2009, 51, 1073. doi: 10.1016/j.corsci.2009.02.011
23. [23]
  (23) Bentiss, F.; Lebrini, M.; Lagrenée, M. Corrosion Sci. 2005, 47,2915. doi: 10.1016/j.corsci.2005.05.034
24. [24]
  (24) Vra?ar, L. M.; Dra??, D. M. Corrosion Sci. 2002, 44, 1669. doi: 10.1016/S0010-938X(01)00166-4
25. [25]
  (25) Solmaz, R.; Kardas, G.; Yazici, B.; Erbil, M. Colloids Surf. A2008, 312, 7. doi: 10.1016/j.colsurfa.2007.06.035
26. [26]
  (26) Moretti, G.; Guidi, F.; Grion, G. Corrosion Sci. 2004, 46, 387.doi: 10.1016/S0010-938X(03)00150-1
27. [27]
  (27) Li, X. H.; Deng, S. D.; Mu, G. N.; Fu, H.; Yang, F. Z. Corrosion Sci. 2008, 50, 420. doi: 10.1016/j.corsci.2007.08.014
28. [28]
  (28) Granese, S. L.; Rosales, B. M.; Oviede, C.; Zerbino, J. O.Corrosion Sci. 1992, 33, 1439. doi: 10.1016/0010-938X(92)90182-3
29. [29]
  (29) Mathur, P. B.; Vasudevan, T. Corrosion 1982, 38, 171. doi: 10.5006/1.3579270
30. [30]
  (30) Cao, C. Corrosion Sci. 1996, 38, 2073. doi: 10.1016/S0010-938X(96)00034-0
31. [31]
  (31) Behpour, M.; Ghoreishi, S. M.; Mohammadi, N.; Soltani, N.;Salavati-Niasari, M. Corrosion Sci. 2010, 52, 4046. doi: 10.1016/j.corsci.2010.08.020
32. [32]
  (32) Labjar, N.; Lebrini, M.; Bentiss, F.; Chihib, N. E.; El Hajjaji, S.;Jama, C. Mater. Chem. Phys. 2010, 119, 330. doi: 10.1016/j.matchemphys.2009.09.006
33. [33]
  (33) Lebrini, M.; Lagrenée, M.; Vezin, H.; Traisnel, M.; Bentiss, F.Corrosion Sci. 2007, 49, 2254. doi: 10.1016/j.corsci.2006.10.029
34. [34]
  (34) Priya, A. R. S.; Muralidharam, V. S.; Subramania, A. Corrosion2008, 64, 541. doi: 10.5006/1.3278490
35. [35]
  (35) Osório, W. R.; Moutinho, D. J.; Peixoto, L. C.; Ferreira, I. L.;Garcia, A. Electrochim. Acta 2011, 56, 8412. doi: 10.1016/j.electacta.2011.07.028
36. [36]
  (36) Lagrenée, M.; Mernari, B.; Bouanis, M.; Traisnel, M.; Bentiss,F. Corrosion Sci. 2002, 44, 573. doi: 10.1016/S0010-938X(01)00075-0
37. [37]
  (37) Li, D. Z.; Zhang, S. G.; Bian, H.; Zhang, L. C. Comput. Appl. Chem. 2009, 26, 324. [李大枝, 张士国,卞贺,张立超.计算机与应用化学, 2009, 26, 324. ]
38. [38]
  (38) Parr, R. G.; Yang, W. J. Am. Chem. Soc. 1984, 106, 4049. doi: 10.1021/ja00326a036
39. [39]
  (39) Gómez, B.; Likhanova, N. V.; Aguilar, M. A. D.; Olivares, O.;Hallen, J. M.; Martínez-Magadán, J. M. J. Phys. Chem. A 2005,109, 8950. doi: 10.1021/jp052188k
40. [40]
  (40) Lashkari, M.; Arshadi, M. R. Chem. Phys. 2004, 299, 131. doi: 10.1016/j.chemphys.2003.12.019
41. [41]
  (41) Schweinsberg, D. P.; Ashworth, V. Corrosion Sci. 1988, 28, 539.doi: 10.1016/0010-938X(88)90022-4
42. [42]
  (42) Banerjee, G.; Malhotra, S. N. Corrosion 1992, 48, 10. doi: 10.5006/1.3315912
43. [43]
  (43) Feng, Y.; Chen, S.; Zhang, H.; Li, P.;Wu, L.; Guo, W. Appl. Surf. Sci. 2006, 253, 2812. doi: 10.1016/j.apsusc.2006.05.061
44. [44]
  (44) Ju, H.; Kai, Z. P.; Li, Y. Corrosion Sci. 2008, 50, 865. doi: 10.1016/j.corsci.2007.10.009
45. [45]
  (45) Lukovits, I.; Kálmán, E.; Zucchi, F. Corrosion 2001, 57, 3. doi: 10.5006/1.3290328
46. [46]
  (46) Sastri, V. S.; Perumareddi, J. R. Corrosion 1997, 53, 617. doi: 10.5006/1.3290294
47. [47]
  (47) Awad, M. K.; Mustafa, M. R.; Elnga, M. M. A. J. Mol. Struct. -Theochem 2010, 959, 66. doi: 10.1016/j.theochem.2010.08.008
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