Citation: HU Zheng-Fa, MENG Tao, ZHANG Wei, CUI Yue-Peng, LUO Li, WANG Yin-Hai. Preparation and Luminescence Properties of Dy³⁺-Doped Full-Color Emitting Ca₉La(PO₄)₇ Phosphors[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2271-2275. doi: 10.3866/PKU.WHXB201307162 shu

Preparation and Luminescence Properties of Dy³⁺-Doped Full-Color Emitting Ca₉La(PO₄)₇ Phosphors

1.
School of Physics and Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, P. R. China

Received Date: 9 May 2013
Available Online: 16 July 2013
Fund Project: 广东省重大科技专项(2011A080801015) (2011A080801015) 国家自然科学基金(21271048) (21271048)广东省佛山市南海绿色照明专项(A201107)资助 (A201107)

Dy³⁺-doped Ca₉La(PO₄)₇ phosphors were synthesized by a high-temperature solid-state reaction. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to determine the crystal structure and size of the prepared materials. Photoluminescence excitation and emission spectra of the Dy³⁺-doped Ca₉La(PO₄)₇:Dy³⁺ phosphors were measured. The samples exhibited a broad absorption band in the range of 300-460 nmand a series of individual absorption peaks of Dy³⁺. Blue (481 nm) and yellow (573 nm) emissions combined to generate the observable white-light emission of the Dy³⁺-doped Ca₉La(PO₄)₇:Dy³⁺ phosphors with suitable Commission Internationale de L'Eclairage (CIE) chromaticity coordinates around the colorless point (0.313, 0.329) when the phosphors were excited at 350 nm. Concentration quenching was clearly observed as the concentration of Dy³⁺ dopant was increased. The most intense emission corresponded to a optimummolar fraction of doped Dy³⁺ ions of 0.05. The mechanismof concentration quenching was dominated by electric dipole?dipole interactions.
- Ca₉La(PO₄)₇:Dy³⁺,
- Phosphors,
- High temperature solid state reaction,
- Luminescence property,
- concentration quenching
1. [1]
  
  (1) Zheng, T.; Li, P.; Xiao, S. C.; Wang, D.; Lü, J. W.; Meng, Z. W.Acta Phys. -Chim. Sin. 2011, 27, 2095. [郑涛,李攀,肖生春,王丹,吕景文,门志伟. 物理化学学报, 2011, 27, 2095.]doi: 10.3866/PKU.WHXB20110906
2. [2]
  (2) Li, P. L.; Yang, Z. P.; Wang, Z. J.; Xiong, Z. J.; Guo, Q. L. Acta Phys. -Chim. Sin. 2008, 24, 179. [李盼来,杨志平,王志军,熊志军, 郭庆林.物理化学学报, 2008, 24, 179.] doi: 10.3866/PKU.WHXB20080133
3. [3]
  (3) Nakamura, S.; Fasol, G. The Blue Laser Diode; Spring-Verlag:Berlin, 1997; p 1.
4. [4]
  (4) Wang, Z. J.; Yang, Z. P.; Guo, Q. L.; Li, P. L. Acta Phys. -Chim. Sin. 2010, 26, 3317. [王志军, 杨志平,郭庆林, 李盼来.物理化学学报, 2010, 26, 3317.] doi: 10.3866/PKU.WHXB20101226
5. [5]
  (5) Yang, Z. P.; Liu, P. F.; Song, Y. C.; Han, Y.; Zhao, Y. H.; Zhou,D. Z. J. Chin. Rare Earth Soc. 2012, 30 (5), 570. [杨志平, 刘鹏飞, 宋延春,韩月,赵引红, 周东站. 中国稀土学报, 2012,30 (5), 570.]
6. [6]
  (6) Liu, X. H.; Xiong, W. D.; Chen, F. M.; Hu, Z. F.; Zhang, W.Mater. Res. Bull. 2013, 48, 281. doi: 10.1016/j.materresbull.2012.10.050
7. [7]
  (7) Galceran, M.; Pujol, M. C.; Gluchowski, P.; Carvajal, J. J.;Mateos, X.; Aguiló, M.; Díaz, F. Opt. Mater. 2010, 32,1493. doi: 10.1016/j.optmat.2010.06.008
8. [8]
  (8) Zhong, J. P.; Liang, H. B.; Han, B.; Su, Q.; Yao, Y. Chem. Phys. Lett. 2008, 453, 192. doi: 10.1016/j.cplett.2008.01.032
9. [9]
  (9) Amami, J.; Hreniak, D.; Guyot, Y.; Pazik, R.; utaudier, C.;Boulon, G.; Ayadi, M.; Strek, W. J. Lumin. 2006, 119-120, 383.
10. [10]
  (10) Liu, X. H.; Xiong, W. D.; Chen, F. M.; Zhang, W.; Hu, Z. F.Mater. Res. Bull. 2012, 47, 3417. doi: 10.1016/j.materresbull.2012.07.012
11. [11]
  (11) Guo, C.; Yang, H. K.; Jeong, J. H. J. Lumin. 2010, 130,1390. doi: 10.1016/j.jlumin.2010.02.052
12. [12]
  (12) Chen, X. P.; Xiao, F.; Ye, S.; Huang, X. Y.; Dong, G. P.; Zhang,Q. Y. J. Alloy. Compd. 2011, 509, 1355. doi: 10.1016/j.jallcom.2010.10.061
13. [13]
  (13) Rao, B. V.; Jang, K. W.; Lee, H. S.; Yi, S. S.; Jeong, J. H.J. Alloy. Compd. 2010, 496, 251. doi: 10.1016/j.jallcom.2009.12.175
14. [14]
  (14) Bao, A.; Yang, H.; Tao, C. Y. Curr. Appl. Phys. 2009, 9,1252. doi: 10.1016/j.cap.2009.02.008
15. [15]
  (15) Ning, Q. Y.; Wang, B. Q.; Guo, F. F.; Qiao, C. J.; Wang, X. F.J. Funct. Mater. 2012, 43 (9), 1126. [宁青菊,王邦青, 郭芳芳, 乔畅君,王秀峰.功能材料, 2012, 43 (9), 1126.]
16. [16]
  (16) Liu, W. R.; Chiu, Y. C.; Yeh, Y. T.; Jang, S. M.; Chen, T. M.J. Electrochem. Soc. 2009, 156 (7), 165. doi: 10.1149/1.3121531
17. [17]
  (17) Zhou, G. X.; Zhao, W. R.; Song, E. H.; Dou, X. H.; Yi, C. Y.;Zhou, M. K. Spectroscopy and Spectral Analysis 2011, 31 (8),2058. [周国雄, 赵韦人,宋恩海, 豆喜华,易春雨, 周民康.光谱学与光谱分析, 2011, 31 (8), 2058.]
18. [18]
  (18) Yang, W. J.; Chen, T. M. Appl. Phys. Lett. 2006, 88 (10), 1903.
19. [19]
  (19) Huang, C. H.; Luo, L. Y.; Chen, T. M. J. Electrochem. Soc.2011, 158 (11), 341. doi: 10.1149/2.029111jes
20. [20]
  (20) Sun, J. Y.; Zhang, X. Y.; Xiao, Z. G.; Du, H. Y. Mater. Res. Bull.2011, 46, 2179. doi: 10.1016/j.materresbull.2011.07.033
21. [21]
  (21) Shinde, K. N.; Nagpure, I. M.; Dhoble, S. J.; dbole, S. V.;Bhide, M. K. Indian J. Phys. 2009, 83, 503. doi: 10.1007/s12648-009-0010-6
22. [22]
  (22) Fernandes, M.; Bermudez, Z. V.; Saferreira, R. A.; Carlos, L. D.;Silva, M. M.; Smith, M. J. Chem. Matter. 2007, 19, 3892. doi: 10.1021/cm062832n
23. [23]
  (23) Liang, C. H.; Qi, X. D.; Chang, Y. S. J. Electrochem. Soc. 2010,157, 169. doi: 10.1149/1.3336958
24. [24]
  (24) Blass, G. Philips Res. Rep. 1969, 24, 131.
25. [25]
  (25) Dexter, D. L. J. Chem. Phys. 1953, 21 (5), 836. doi: 10.1063/1.1699044
26. [26]
  (26) Dexter, D. L.; Schulman, J. H. J. Chem. Phys. 1954, 22 (6),1063. doi: 10.1063/1.1740265
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescence Properties of Dy3+-Doped Full-Color Emitting Ca9La(PO4)7 Phosphors

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Preparation and Luminescence Properties of Dy³⁺-Doped Full-Color Emitting Ca₉La(PO₄)₇ Phosphors