Citation: LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei. Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2101-2106. doi: 10.3866/PKU.WHXB201307153 shu

Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one

1.
Laboratory of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China

Received Date: 3 June 2013
Available Online: 15 July 2013
Fund Project: 国家自然科学基金(21173163) (21173163)燃烧与爆炸技术重点实验室基金(9140C350307110C3506)资助项目 (9140C350307110C3506)

The thermokinetics of the formation reactions of metal (Li, Na, Pb, Cu) salts of 3-nitro-1,2,4-triazol- 5-one (NTO) was studied using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (activation energy, pre-exponential constant, and reaction order), rate constant, three thermokinetic parameters (activation enthalpy, activation entropy, and activation free energy) and the enthalpies of the reactions to prepare the metal salts of NTO in the temperature range of 25-40℃ were obtained. The title reactions occur easily in the studied temperature range. Based on Hess' law, the values of Δ_fH_m⁰ (Li(NTO)·2H₂O, aq, 298.15 K) and Δ_fH_m⁰ (Na(NTO)·2H₂O, aq, 298.15 K) are obtained.
- Metal salts of 3-nitro-1,2,4-triazol-5-one,
- Formation reaction,
- Microcalorimeter,
- Thermokinetics
1. [1]
  
  (1) Zhao, F. Q.; Hu, R. Z.; Xu, S. Y. Chin. J. Explos. Propell. 2008,31, 18. [赵凤起, 胡荣祖,徐司雨. 火炸药学报, 2008, 31, 18.]
2. [2]
  (2) Sinditskii, V. P.; Smirnov, S. P.; E rshev, V. Y. J. Propell. Explos. Pyrotech. 2007, 32, 277.
3. [3]
  (3) Trzcinski, W. A.; Szymanczyk, L. J. Energ. Mater. 2006, 23,151.
4. [4]
  (4) Lee, J. S.; Jaw, K. S. J. Therm. Anal. Calorim. 2006, 85, 463.doi: 10.1007/s10973-005-7325-0
5. [5]
  (5) Fan, X. Z.; Li, J. Z.; Zhang, L. Y.; Wang, B. Z.; Liu, X. G. Chin. J. Energ. Mater. 2007, 15, 316. [樊学忠, 李吉祯, 张腊莹, 王伯周,刘小刚. 含能材料, 2007, 15, 316.]
6. [6]
  (6) Hu, R. Z.; Meng, Z. H.; Kang, B. Thermochim. Acta 1996, 275,159. doi: 10.1016/0040-6031(95)02680-0
7. [7]
  (7) Song, J. R.; Hu, R. Z.; Li, F. P. Chinese Science Bulletin 1996,41, 1806.
8. [8]
  (8) Kulkarni, P. B.; Purandare, G. N.; Nair, J. K.; Talawar, M. B.;Mukundan, T.; Asthana, S. N. J. Hazard. Mater. 2005, 119, 53.doi: 10.1016/j.jhazmat.2004.12.014
9. [9]
  (9) Ma, H. X.; Song, J. R.; Hu, R. Z. Thermochim. Acta 2002, 389,43. doi: 10.1016/S0040-6031(02)00015-1
10. [10]
  (10) Xie, Y.; Hu, R. Z.; Zhang, T. L. J. Therm. Anal. 1993, 39, 41.doi: 10.1007/BF02235445
11. [11]
  (11) Singh, G.; Felix, S. P. J. Mol. Struct. 2003, 649, 71. doi: 10.1016/S0022-2860(02)00717-2
12. [12]
  (12) Zhang, T. L.; Hu, R. Z.; Li, F. P.; Chen, L.; Yu, K. B. Chinese Science Bulletin 1993, 38, 1350.
13. [13]
  (13) Zhang, T. L.; Hu, R. Z.; Li, F. P. Chin. J. Energ. Mater. 1993, 1,1.
14. [14]
  (14) Yi, J. H.; Zhao, F. Q.; Xu, S. Y.; Gao, H. X.; Hu, R. Z.; Hao, H.X.; Pei, Q.; Gao, Y. Acta Phys. -Chim. Sin. 2007, 23, 1316. [仪建华, 赵凤起,徐司雨, 高红旭,胡荣祖, 郝海霞,裴庆,高茵.物理化学学报, 2007, 23, 1316.] doi: 10.1016/S1872-1508(07)60065-5
15. [15]
  (15) Zhao, F. Q.; Zhang, H.; An, T.; Zhang, X. H.; Yi, J. H.; Xu, S.Y.; Wang, Y. L. Acta Phys. -Chim. Sin. 2013, 29, 777. [赵凤起,张衡,安亭,张晓宏, 仪建华,徐司雨, 汪营磊.物理化学学报, 2013, 29, 777.] doi: 10.3866/PKU.WHXB20130111
16. [16]
  (16) Zhao, F. Q.; Xue, L.; Xing, X. L.; Hu, R. Z.; Gao, H. X.; Yi, J.H.; Xu, S. Y.; Pei, Q. Sci. China Chem. 2011, 54, 463.
17. [17]
  (17) Xue, L.; Zhao, F. Q.; Xing, X. L.; Gao, H. X.; Xu, S. Y.; Hu, R.Z. Acta Phys. -Chim. Sin. 2009, 25, 2414. [薛亮,赵凤起,邢晓玲, 高红旭,徐司雨, 胡荣祖.物理化学学报, 2009, 25,2414.] doi: 10.3866/PKU.WHXB20091129
18. [18]
  (18) Xing, X. L.; Zhao, F. Q.; Yi, J. H.; Gao, H. X.; Xu, S. Y.; Pei,Q.; Hao, H. X.; Hu, R. Z. J. Therm. Anal. Calorim. 2010, 99,704.
19. [19]
  (19) Xing, X. L.; Xue, L.; Zhao, F. Q.; Gao, H. X.; Pei, Q.; Hu, R. Z.Chin. J. Chem. 2010, 28, 1370.
20. [20]
  (20) Zhao, F. Q.; Hu, R. Z.; Zhang, H.; Gao, H. X.; Zhao, H. A.; Ma,H. X. Chem. Res. Chin. Univ. 2010, 26, 829.
21. [21]
  (21) Xue, L.; Zhao, F. Q.; Xing, X. L.; Gao, H. X.; Hu, R. Z.,Thermochim. Acta 2009, 32, 54.
22. [22]
  (22) Xiao, L. B.; Xing, X. L.; Fan, X. Z.; Zhao, F. Q.; Zhou, Z. M.;Huang, H. F.; An, T.; Hao, H. X.; Pei, Q. J. Therm. Anal. Calorim. 2012, 110, 1431. doi: 10.1007/s10973-011-2036-1
23. [23]
  (23) Xiao, L. B.; Zhao, F. Q.; Xing, X. L.; Huang, H. F.; Zhou, Z.M.; An, T.; Tan, Y. Thermochim. Acta 2012, 546, 138. doi: 10.1016/j.tca.2012.07.003
24. [24]
  (24) Hu, R. Z.; Gao, S. L.; Zhao, F. Q.; Zhang, T. L.; Zhang, J. J.Thermal Analysis Kinetics, 2nd ed.; Science Press: Beijing,2008.
25. [25]
  (25) Meng, Z. H.; Hu, R. Z. J. Therm. Anal. 1995, 45, 79. doi: 10.1007/BF02548666
26. [26]
  (26) Weast, R. C. CRC Handbook of Chemistry and Physics, 70thed.; CRC Press Inc.: Florida, USA, 1989-1990; pp 73-85.
1. [1]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
2. [2]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
3. [3]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
4. [4]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
5. [5]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
7. [7]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
8. [8]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
9. [9]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
10. [10]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
11. [11]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
12. [12]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
13. [13]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
14. [14]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
15. [15]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
16. [16]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
17. [17]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
18. [18]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
19. [19]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
20. [20]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369

Get Citation

PDF

XML

Metrics

PDF Downloads(515)
Abstract views(768)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142