Citation: LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei. Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2101-2106. doi: 10.3866/PKU.WHXB201307153 shu

Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one

1.
Laboratory of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China

Received Date: 3 June 2013
Available Online: 15 July 2013
Fund Project: 国家自然科学基金(21173163) (21173163)燃烧与爆炸技术重点实验室基金(9140C350307110C3506)资助项目 (9140C350307110C3506)

The thermokinetics of the formation reactions of metal (Li, Na, Pb, Cu) salts of 3-nitro-1,2,4-triazol- 5-one (NTO) was studied using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (activation energy, pre-exponential constant, and reaction order), rate constant, three thermokinetic parameters (activation enthalpy, activation entropy, and activation free energy) and the enthalpies of the reactions to prepare the metal salts of NTO in the temperature range of 25-40℃ were obtained. The title reactions occur easily in the studied temperature range. Based on Hess' law, the values of Δ_fH_m⁰ (Li(NTO)·2H₂O, aq, 298.15 K) and Δ_fH_m⁰ (Na(NTO)·2H₂O, aq, 298.15 K) are obtained.
- Metal salts of 3-nitro-1,2,4-triazol-5-one,
- Formation reaction,
- Microcalorimeter,
- Thermokinetics
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沈阳化工大学材料科学与工程学院沈阳 110142