Citation: LI Na, ZHAO Feng-Qi, GAO Hong-Xu, HU Rong-Zu, XIAO Li-Bai, YAO Er-Gang, HUANG Xin-Ping, CHANG Pei. Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2101-2106. doi: 10.3866/PKU.WHXB201307153 shu

Thermokinetics of the Formation Reactions of Metal (Li, Na, Pb, Cu) Salts of 3-Nitro-1,2,4-triazol-5-one

  • Received Date: 3 June 2013
    Available Online: 15 July 2013

    Fund Project: 国家自然科学基金(21173163) (21173163)燃烧与爆炸技术重点实验室基金(9140C350307110C3506)资助项目 (9140C350307110C3506)

  • The thermokinetics of the formation reactions of metal (Li, Na, Pb, Cu) salts of 3-nitro-1,2,4-triazol- 5-one (NTO) was studied using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (activation energy, pre-exponential constant, and reaction order), rate constant, three thermokinetic parameters (activation enthalpy, activation entropy, and activation free energy) and the enthalpies of the reactions to prepare the metal salts of NTO in the temperature range of 25-40℃ were obtained. The title reactions occur easily in the studied temperature range. Based on Hess' law, the values of ΔfHm0 (Li(NTO)·2H2O, aq, 298.15 K) and ΔfHm0 (Na(NTO)·2H2O, aq, 298.15 K) are obtained.

  • 加载中
    1. [1]

      (1) Zhao, F. Q.; Hu, R. Z.; Xu, S. Y. Chin. J. Explos. Propell. 2008,31, 18. [赵凤起, 胡荣祖,徐司雨. 火炸药学报, 2008, 31, 18.]

    2. [2]

      (2) Sinditskii, V. P.; Smirnov, S. P.; E rshev, V. Y. J. Propell. Explos. Pyrotech. 2007, 32, 277.

    3. [3]

      (3) Trzcinski, W. A.; Szymanczyk, L. J. Energ. Mater. 2006, 23,151.

    4. [4]

      (4) Lee, J. S.; Jaw, K. S. J. Therm. Anal. Calorim. 2006, 85, 463.doi: 10.1007/s10973-005-7325-0

    5. [5]

      (5) Fan, X. Z.; Li, J. Z.; Zhang, L. Y.; Wang, B. Z.; Liu, X. G. Chin. J. Energ. Mater. 2007, 15, 316. [樊学忠, 李吉祯, 张腊莹, 王伯周,刘小刚. 含能材料, 2007, 15, 316.]

    6. [6]

      (6) Hu, R. Z.; Meng, Z. H.; Kang, B. Thermochim. Acta 1996, 275,159. doi: 10.1016/0040-6031(95)02680-0

    7. [7]

      (7) Song, J. R.; Hu, R. Z.; Li, F. P. Chinese Science Bulletin 1996,41, 1806.

    8. [8]

      (8) Kulkarni, P. B.; Purandare, G. N.; Nair, J. K.; Talawar, M. B.;Mukundan, T.; Asthana, S. N. J. Hazard. Mater. 2005, 119, 53.doi: 10.1016/j.jhazmat.2004.12.014

    9. [9]

      (9) Ma, H. X.; Song, J. R.; Hu, R. Z. Thermochim. Acta 2002, 389,43. doi: 10.1016/S0040-6031(02)00015-1

    10. [10]

      (10) Xie, Y.; Hu, R. Z.; Zhang, T. L. J. Therm. Anal. 1993, 39, 41.doi: 10.1007/BF02235445

    11. [11]

      (11) Singh, G.; Felix, S. P. J. Mol. Struct. 2003, 649, 71. doi: 10.1016/S0022-2860(02)00717-2

    12. [12]

      (12) Zhang, T. L.; Hu, R. Z.; Li, F. P.; Chen, L.; Yu, K. B. Chinese Science Bulletin 1993, 38, 1350.

    13. [13]

      (13) Zhang, T. L.; Hu, R. Z.; Li, F. P. Chin. J. Energ. Mater. 1993, 1,1.

    14. [14]

      (14) Yi, J. H.; Zhao, F. Q.; Xu, S. Y.; Gao, H. X.; Hu, R. Z.; Hao, H.X.; Pei, Q.; Gao, Y. Acta Phys. -Chim. Sin. 2007, 23, 1316. [仪建华, 赵凤起,徐司雨, 高红旭,胡荣祖, 郝海霞,裴庆,高茵.物理化学学报, 2007, 23, 1316.] doi: 10.1016/S1872-1508(07)60065-5

    15. [15]

      (15) Zhao, F. Q.; Zhang, H.; An, T.; Zhang, X. H.; Yi, J. H.; Xu, S.Y.; Wang, Y. L. Acta Phys. -Chim. Sin. 2013, 29, 777. [赵凤起,张衡,安亭,张晓宏, 仪建华,徐司雨, 汪营磊.物理化学学报, 2013, 29, 777.] doi: 10.3866/PKU.WHXB20130111

    16. [16]

      (16) Zhao, F. Q.; Xue, L.; Xing, X. L.; Hu, R. Z.; Gao, H. X.; Yi, J.H.; Xu, S. Y.; Pei, Q. Sci. China Chem. 2011, 54, 463.

    17. [17]

      (17) Xue, L.; Zhao, F. Q.; Xing, X. L.; Gao, H. X.; Xu, S. Y.; Hu, R.Z. Acta Phys. -Chim. Sin. 2009, 25, 2414. [薛亮,赵凤起,邢晓玲, 高红旭,徐司雨, 胡荣祖.物理化学学报, 2009, 25,2414.] doi: 10.3866/PKU.WHXB20091129

    18. [18]

      (18) Xing, X. L.; Zhao, F. Q.; Yi, J. H.; Gao, H. X.; Xu, S. Y.; Pei,Q.; Hao, H. X.; Hu, R. Z. J. Therm. Anal. Calorim. 2010, 99,704.

    19. [19]

      (19) Xing, X. L.; Xue, L.; Zhao, F. Q.; Gao, H. X.; Pei, Q.; Hu, R. Z.Chin. J. Chem. 2010, 28, 1370.

    20. [20]

      (20) Zhao, F. Q.; Hu, R. Z.; Zhang, H.; Gao, H. X.; Zhao, H. A.; Ma,H. X. Chem. Res. Chin. Univ. 2010, 26, 829.

    21. [21]

      (21) Xue, L.; Zhao, F. Q.; Xing, X. L.; Gao, H. X.; Hu, R. Z.,Thermochim. Acta 2009, 32, 54.

    22. [22]

      (22) Xiao, L. B.; Xing, X. L.; Fan, X. Z.; Zhao, F. Q.; Zhou, Z. M.;Huang, H. F.; An, T.; Hao, H. X.; Pei, Q. J. Therm. Anal. Calorim. 2012, 110, 1431. doi: 10.1007/s10973-011-2036-1

    23. [23]

      (23) Xiao, L. B.; Zhao, F. Q.; Xing, X. L.; Huang, H. F.; Zhou, Z.M.; An, T.; Tan, Y. Thermochim. Acta 2012, 546, 138. doi: 10.1016/j.tca.2012.07.003

    24. [24]

      (24) Hu, R. Z.; Gao, S. L.; Zhao, F. Q.; Zhang, T. L.; Zhang, J. J.Thermal Analysis Kinetics, 2nd ed.; Science Press: Beijing,2008.

    25. [25]

      (25) Meng, Z. H.; Hu, R. Z. J. Therm. Anal. 1995, 45, 79. doi: 10.1007/BF02548666

    26. [26]

      (26) Weast, R. C. CRC Handbook of Chemistry and Physics, 70thed.; CRC Press Inc.: Florida, USA, 1989-1990; pp 73-85.


  • 加载中
    1. [1]

      Yeyun Zhang Ling Fan Yanmei Wang Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044

    2. [2]

      Jiageng Li Putrama . 数值积分耦合非线性最小二乘法一步确定反应动力学参数. University Chemistry, 2025, 40(6): 364-370. doi: 10.12461/PKU.DXHX202407098

    3. [3]

      Xuzhen Wang Xinkui Wang Dongxu Tian Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074

    4. [4]

      Dexin Tan Limin Liang Baoyi Lv Huiwen Guan Haicheng Chen Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048

    5. [5]

      Yiying Yang Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074

    6. [6]

      Shanghua Li Malin Li Xiwen Chi Xin Yin Zhaodi Luo Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003

    7. [7]

      Yang Lv Yingping Jia Yanhua Li Hexiang Zhong Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059

    8. [8]

      Zhuo WANGJunshan ZHANGShaoyan YANGLingyan ZHOUYedi LIYuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    9. [9]

      Limei CHENMengfei ZHAOLin CHENDing LIWei LIWeiye HANHongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    10. [10]

      Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029

    11. [11]

      Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093

    12. [12]

      Jiayu Gu Siqi Wang Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012

    13. [13]

      Jinfu Ma Hui Lu Jiandong Wu Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052

    14. [14]

      Jiajie CaiChang ChengBowen LiuJianjun ZhangChuanjia JiangBei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H2 production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084

    15. [15]

      Yue Wu Jun Li Bo Zhang Yan Yang Haibo Li Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028

    16. [16]

      You Wu Chang Cheng Kezhen Qi Bei Cheng Jianjun Zhang Jiaguo Yu Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027

    17. [17]

      Yan Li Xinze Wang Xue Yao Shouyun Yu . 基于激发态手性铜催化的烯烃EZ异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053

    18. [18]

      Chengqian Mao Yanghan Chen Haotong Bai Junru Huang Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014

    19. [19]

      Yahui HANJinjin ZHAONing RENJianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395

    20. [20]

      Wenjie SHIFan LUMengwei CHENJin WANGYingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360

Metrics
  • PDF Downloads(515)
  • Abstract views(888)
  • HTML views(9)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return