Citation: QIAO Yin-Po, YIN Hai-Rong, ZHANG Yan-Bin, PAN Yun-Juan, QIAO Lu, LIU Ting. Enhanced Photoluminescence Properties of CaF₂ in CaO-CaF₂-B₂O₃-SiO₂ Glass Doped with Sm₂O₃[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 2056-2061. doi: 10.3866/PKU.WHXB201307091 shu

Enhanced Photoluminescence Properties of CaF₂ in CaO-CaF₂-B₂O₃-SiO₂ Glass Doped with Sm₂O₃

1.
School of Materials Science and Engineering, Shaanxi University of Science & Technology, Xi'an 710021, P. R. China

Received Date: 31 January 2013
Available Online: 9 July 2013
Fund Project: 中国博士后科学基金面上项目(20110491640) (20110491640)陕西省教育厅科研计划项目(11JK0839) (11JK0839)陕西科技大学科研启动基金项目(BJ10-11) (BJ10-11)陕西科技大学创新创业训练计划项目(201310708008, 201210708011)资助 (201310708008, 201210708011)

Aseries of luminescent glass composed of CaO-CaF₂-B₂O₃-SiO₂ doped with samariumoxide (CFBS: Sm) were prepared. The structure, infrared transmittance and fluorescent properties of the samples were investigated by X-ray diffraction (XRD), Fourier transforminfrared (FTIR) spectroscopy and photoluminescence (PL) measurements, respectively. The XRD patterns of the CFBS:S msamples showed that the glass matrix had a non-crystalline structure, while the FTIR spectra exhibited shifts of absorption wavelength sensitive to the structure and function of the samples. The PL spectra of the CFBS:Smglasses showed the characteristic emission of Sm³⁺ centered at 566, 603 and 650 nmunder 404 nmexcitation, and their luminescence color was red-orange (x=0.531, y=0.371). Furthermore, the intensity of emission and fluorescent lifetime of Sm³⁺ at 603 nm (⁴G_5/2) increased with the molar ratio of CaF₂ in the glass samples. The enhanced intensity of emission, fluorescent lifetime and quantumefficiency with increasing molar ratio of CaF₂ may result fromthe reduction of phonon energy in the CFBS:S mglass because some CaF₂ substitutes CaO in the glass matrix.
- Rare earth doped,
- Luminescent glass,
- Calciumfluoride,
- Photoluminescence,
- Fluorescent life,
- Quantumefficiency
1. [1]
  
  (1) Anderson, P. W. Science 1995, 267 (5204), 1616.
2. [2]
  (2) Patek, K. Glass Lasers; Butterworth& Co Press: Ottawa, 1970;pp 112-126.
3. [3]
  (3) Gan, F.; Xu, L. Photonic Glasses; World Scientific Press:Singapore, 2006; pp 62-96.
4. [4]
  (4) Zhu, Z. F.; Liu, D. G.; Liu, H.; Li, G. J.; Du, J.; He, Z. L.J. Lumines. 2012, 132, 261. doi: 10.1016/j.jlumin.2011.08.045
5. [5]
  (5) Li, P. L.; Yang, Z. P.; Wang, Z. J.; Xiong, Z. J.; Guo, Q. L. Acta Phys. -Chim. Sin. 2008, 24 (1),179. [李盼来, 杨志平,王志军,熊志军, 郭庆林. 物理化学学报, 2008, 24 (1), 179.] doi: 10.3866/PKU.WHXB20080133
6. [6]
  (6) Yang, X.; Zhou, H.; Shen, B.; Zhang, L. Acta Phys. -Chim. Sin.2010, 26 (1), 244. [杨旭,周宏,沈彬,张玲.物理化学学报, 2010, 26 (1), 244.] doi: 10.3866/PKU.WHXB20100124
7. [7]
  (7) Wang, B. Q.; Xia, C. H.; Fu, Q.; Wang, P. W.; Shan, X. D.; Yu,D. P. Acta. Phys.-Chim. Sin. 2008, 24 (7), 1165. [王百齐,夏春辉,富强, 王朋伟,单旭东, 俞大鹏.物理化学学报, 2008, 24 (7), 1165.] doi: 10.3866/PKU.WHXB20080708
8. [8]
  (8) Anwar, M. S.; Kumar, S.; Arshi, N. J. Alloy. Compd. 2011, 509 (13), 4525. doi: 10.1016/j.jallcom.2011.01.067
9. [9]
  (9) Yin, L. X.; Huang, J. F.; Huang, Y. Chin. Ceram. Commun.2010, 105-106, 345.
10. [10]
  (10) Kumar, J. S.; Pavani, K.; Sasikala, T.; Rao, A. S.; Giri, N. K.;Rai, S. B.; Moorthy, L. R. Solid State Sci. 2011, 13 (8),1548. doi: 10.1016/j.solidstatesciences.2011.05.020
11. [11]
  (11) Banyasz, I.; Berneschi, S.; Lohner, T. Characterisation of SlabWaveguides, Fabricated in CaF2 and Er-doped Tungsten-telluriteGlass by MeVEnergy N+ Ion Implantation, UsingSpectroscopic Ellipsometry and m-Line Spectroscopy. InProceedings of SPIE-The International Society for Optical Engineering, Silicon Photonics and Photonic Integrated CircuitsConference, SPIE, Belingham, Wash, 2010, 7719, 77190G.
12. [12]
  (12) Babu, P.; Jang, K. H.; Kim, E. S. J. Korean Phys. Soc. 2009, 54,1488. doi: 10.3938/jkps.54.1488
13. [13]
  (13) Qiao, Y. P.; Zhu, Z. F.; Hua, S. J. J. Funct. Mater. 2012, 43 (3),363. [乔荫颇, 朱振峰,华斯嘉. 功能材料, 2012, 43 (3), 363.]
14. [14]
  (14) Qiao, Y. P.; Zhu, Z. F.; Zhang, Y. B. Acta Phys. -Chim. Sin.2012, 28 (3), 706. [乔荫颇,朱振峰, 张燕斌.物理化学学报,2012, 28 (3), 706.] doi: 10.3866/PKU.WHXB201112162
15. [15]
  (15) Zhu, Z. F.; Zhang, Y. B.; Qiao, Y. P.; Liu, D. G. J. Non-Cryst. Solids 2012, 358, 1550. doi: 10.1016/j.jnoncrysol.2012.04.015
16. [16]
  (16) Zhu, Z. F.; Zhang, Y. B.; Qiao, Y. P.; Liu, H.; Liu, D. G.J. Lumines. 2013, 134, 724. doi: 10.1016/j.jlumin.2012.07.003
17. [17]
  (17) Soukoulis, C. M.; Kafesaki, M.; Economou, E. N. Adv. Mater.2006, 18 (15), 1941.
18. [18]
  (18) Pendry, J. B.; Schurig, D.; Smith, D. R. Science 2006, 312,1780. doi: 10.1126/science.1125907
19. [19]
  (19) Qiao, Y. P.; Zhao, X. P. Colloids Surf. A: Physicochem. Eng. Aspects 2009, 340, 33. doi: 10.1016/j.colsurfa.2009.02.036
20. [20]
  (20) Qiao, Y. P.; Zhao, X. P.; Su, Y. Y. J. Mater. Chem. 2011, 21,394. doi: 10.1039/c0jm02002h
21. [21]
  (21) Malchukova, E.; Boizot, B.; Petite, G. J. Non-Cryst. Solids2007, 353, 2397. doi: 10.1016/j.jnoncrysol.2007.04.003
22. [22]
  (22) You, H. P.; Hayakawa, T.; Nogami, M. J. Non-Cryst. Solids2006, 352, 2778. doi: 10.1016/j.jnoncrysol.2006.03.059
23. [23]
  (23) Arunkumar, S.; Marimuthu, K. J. Alloy. Compd. 2013, 565,104. doi: 10.1016/j.jallcom.2013.02.151
24. [24]
  (24) Hager, I. Z.; El-Mallawany, R.; Bulou, A. Physica B: Condes. Mat. 2011, 406, 972. doi: 10.1016/j.physb.2010.12.041
25. [25]
  (25) Lee, S.; Lee, M.; LimK. J. Luminescence 2007, 122-123, 990.
26. [26]
  (26) Zhang, Y.; Lu, C. H.; Sun, L. Y.; Xu, Z. Z.; Ni, Y. R. Mater. Res. Bull. 2009, 44 (1), 179. doi: 10.1016/j.materresbull.2008.03.004
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沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced Photoluminescence Properties of CaF2 in CaO-CaF2-B2O3-SiO2 Glass Doped with Sm2O3

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通讯作者: 陈斌, bchen63@163.com

Enhanced Photoluminescence Properties of CaF₂ in CaO-CaF₂-B₂O₃-SiO₂ Glass Doped with Sm₂O₃