Citation: HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei. Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 1998-2004. doi: 10.3866/PKU.WHXB201307031 shu

Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package

1.
Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 8 April 2013
Available Online: 3 July 2013
Fund Project: 中国科学院知识创新工程重要方向项目(KJCX2-YW-W26) (KJCX2-YW-W26)北京市科技计划项目(Z111100056011007) (Z111100056011007)国家自然科学基金(21001103,51025726)资助 (21001103,51025726)

We fabricated activated carbon (AC)-based supercapacitors encased in flexible packaging using a novel organic electrolyte, triethylmethylammonium tetrafluoroborate/acetonitrile+propylene carbonate (MeEt₃NBF₄/(AN+PC)), and two conventional organic electrolytes, tetraethylammonium tetrafluoroborate/acetonitrile (Et₄NBF₄/AN) and tetraethylammonium tetrafluoroborate/propylene carbonate (Et₄NBF₄/PC). Cyclic voltammetry and electrochemical impedance spectroscopy measurements in various voltage windows were conducted. In addition, a comprehensive comparison of these three electrolytes was conducted via data obtained from cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge-discharge, leakage current, self-discharge, cyclic life, and coulombic efficiency within the 0-3 V voltage window. The results indicate that MeEt₃NBF₄/(AN+PC) combining the advantages of AN and PC exhibits excellent performance.
- Supercapacitor,
- Organic electrolyte,
- Activated carbon
1. [1]
  
  (1) Yu, P.; Zhang, X.; Chen, Y.; Ma, Y.; Qi, Z. Mater. Chem. Phys.2009, 118, 303. doi: 10.1016/j.matchemphys.2009.07.057
2. [2]
  (2) Zhang, D.; Zhang, X.; Chen, Y.; Wang, C.; Ma, Y.; Dong, H.;Jiang, L.; Meng, Q.; Hu, W. Phys. Chem. Chem. Phys. 2012, 14,10899. doi: 10.1039/c2cp41051f
3. [3]
  (3) Ammam, M.; Fransaer, J. J. Electrochem. Soc. 2011, 158, A14.
4. [4]
  (4) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157,11. doi: 10.1016/j.jpowsour.2006.02.065
5. [5]
  (5) Sun, X.; Zhang, X.; Zhang, H.; Zhang, D.; Ma, Y. J. Solid State Electrochem. 2012, 16, 2597. doi: 10.1007/s10008-012-1678-7
6. [6]
  (6) Kurig, H.; Janes, A.; Lust, E. J. Electrochem. Soc. 2010, 157,A272.
7. [7]
  (7) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. Acta Phys. - Chim. Sin. 2012, 28, 2641. [仲皓想,赵春宝,骆浩,张灵志.物理化学学报, 2012, 28, 2641.] doi: 10.3866/PKU.WHXB201207181
8. [8]
  (8) Lu, W.; Hartman, R.; Qu, L. T.; Dai, L. M. J. Phys. Chem. Lett.2011, 2, 655. doi: 10.1021/jz200104n
9. [9]
  (9) Kim, B.; Chung, H.; Kim, W. Nanotechnology 2012, 23.
10. [10]
  (10) Sun, X. Z.; Zhang, X.; Zhang, D. C.; Ma, Y. W. Acta Phys. - Chim. Sin. 2012, 28, 367. [孙现众,张熊,张大成, 马衍伟.物理化学学报, 2012, 28, 367.] doi: 10.3866/PKU.WHXB201112131
11. [11]
  (11) Liu, P.; Verbrugge, M.; Soukiazian, S. J. Power Sources 2006,156, 712. doi: 10.1016/j.jpowsour.2005.05.055
12. [12]
  (12) Portet, C.; Taberna, P. L.; Simon, P.; Flahaut, E. J. Power Sources 2005, 139, 371. doi: 10.1016/j.jpowsour.2004.07.015
13. [13]
  (13) Sillars, F. B.; Fletcher, S. I.; Mirzaeian, M.; Hall, P. J. Phys. Chem. Chem. Phys. 2012, 14, 6094. doi: 10.1039/c2cp40089h
14. [14]
  (14) Lewandowski, A.; Olejniczak, A.; Galinski, M.; Stepniak, I. J. Power Sources 2010, 195, 5814. doi: 10.1016/j.jpowsour.2010.03.082
15. [15]
  (15) Pandey, G. P.; Kumar, Y.; Hashmi, S. A. Indian J. Chem. Sect. A-Inorg. Bio-Inorg. Phys. Theor. Anal. Chem. 2010, 49, 743.
16. [16]
  (16) Kurig, H.; Vestli, M.; Tonurist, K.; Janes, A.; Lust, E. J. Electrochem. Soc. 2012, 159, A944.
17. [17]
  (17) Ruiz, V.; Huynh, T.; Sivakkumar, S. R.; Pandolfo, A. G. RSC Adv. 2012, 2, 5591. doi: 10.1039/c2ra20177a
18. [18]
  (18) Balducci, A.; Dugas, R.; Taberna, P. L.; Simon, P.; Plee, D.;Mastra stino, M.; Passerini, S. J. Power Sources 2007, 165,922. doi: 10.1016/j.jpowsour.2006.12.048
19. [19]
  (19) Tyunina, E. Y.; Afanasiev, V. N.; Chekunova, M. D. Journal of Chemical& Engineering Data 2011, 56, 3222. doi: 10.1021/je200309v
20. [20]
  (20) Moumouzlas, G.; Panopoulos, D. K.; Ritzoulis, G. Journal of Chemical and Engineering Data 1991, 36, 20. doi: 10.1021/je00001a006
21. [21]
  (21) Borenstien, A.; Noked, M.; Okashy, S.; Aurbach, D. J. Electrochem. Soc. 2013, 160, A1282.
22. [22]
  (22) Wang, G. X.; Shao, Z. P.; Yu, Z. L. Nanotechnology 2007, 18,205705.
23. [23]
  (23) Chen, H.; Wang, F.; Tong, S. S.; Guo, S. L.; Pan, X. M. Appl. Surf. Sci. 2012, 258, 6097. doi: 10.1016/j.apsusc.2012.03.009
24. [24]
  (24) Liu, X. M.; Zhang, R.; Zhan, L.; Long, D. H.; Qiao, W. M.;Yang, J. H.; Ling, L. C. New Carbon Mater. 2007, 22, 153. doi: 10.1016/S1872-5805(07)60015-8
25. [25]
  (25) Ferg, E.; Rossouw, C.; Loyson, P. J. Power Sources 2013, 226,299. doi: 10.1016/j.jpowsour.2012.10.087
26. [26]
  (26) Kotz, R.; Carlen, M. Electrochim. Acta 2000, 45, 2483. doi: 10.1016/S0013-4686(00)00354-6
27. [27]
  (27) Lust, E.; Jänes, A.; Arulepp, M. J. Electroanal. Chem. 2004,562, 33. doi: 10.1016/j.jelechem.2003.07.034
28. [28]
  (28) Arulepp, M.; Permann, L.; Leis, J.; Perkson, A.; Rumma, K.;Jänes, A.; Lust, E. J. Power Sources 2004, 133, 320. doi: 10.1016/j.jpowsour.2004.03.026
29. [29]
  (29) Ruch, P. W.; Cericola, D.; Foelske-Schmitz, A.; Kötz, R.;Wokaun, A. Electrochim. Acta 2010, 55, 4412. doi: 10.1016/j.electacta.2010.02.064
30. [30]
  (30) Ruch, P. W.; Cericola, D.; Foelske, A.; Kötz, R.; Wokaun, A.Electrochim. Acta 2010, 55, 2352. doi: 10.1016/j.electacta.2009.11.098
1. [1]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
2. [2]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
3. [3]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
4. [4]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
5. [5]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
6. [6]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
7. [7]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
8. [8]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
9. [9]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
10. [10]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
11. [11]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040
12. [12]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
13. [13]
  Quanliang Chen , Zhaohui Zhou . Research on the Active Site of Nitrogenase over Fifty Years. University Chemistry, 2024, 39(7): 287-293. doi: 10.3866/PKU.DXHX202310133
14. [14]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
15. [15]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
16. [16]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082
17. [17]
  Fuxian Wan , Ying Li , Yuanhong Zhang , Shuhua Zhu , Jing Xu , Yanfang Wang , Lili Zhang . Exploration and Practice of Teaching in Agricultural Characteristic Organic Chemistry Course. University Chemistry, 2024, 39(2): 298-306. doi: 10.3866/PKU.DXHX202308041
18. [18]
  Zhichang Xiao , Xiaohui Li , Ling Zhang , Huimin Liu . Exploration of Ideological and Political Construction in University Foundation Course of Organic Chemistry. University Chemistry, 2024, 39(2): 314-320. doi: 10.3866/PKU.DXHX202308058
19. [19]
  Xinyu Zhu , Meili Pang . Application of Functional Group Addition Strategy in Organic Synthesis. University Chemistry, 2024, 39(3): 218-230. doi: 10.3866/PKU.DXHX202308106
20. [20]
  Gang Liu , Heng Zhang , Ying Ma , Shiling Yuan , Qisheng Song , Zhenghu Xu , Jichao Sun . Exploration and Practice on Improving the Teaching Quality of Organic Chemistry Laboratory Course. University Chemistry, 2024, 39(4): 70-74. doi: 10.3866/PKU.DXHX202309079

Get Citation

PDF

XML

Metrics

PDF Downloads(1194)
Abstract views(894)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142