Citation: HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei. Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 1998-2004. doi: 10.3866/PKU.WHXB201307031 shu

Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package

1.
Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 8 April 2013
Available Online: 3 July 2013
Fund Project: 中国科学院知识创新工程重要方向项目(KJCX2-YW-W26) (KJCX2-YW-W26)北京市科技计划项目(Z111100056011007) (Z111100056011007)国家自然科学基金(21001103,51025726)资助 (21001103,51025726)

We fabricated activated carbon (AC)-based supercapacitors encased in flexible packaging using a novel organic electrolyte, triethylmethylammonium tetrafluoroborate/acetonitrile+propylene carbonate (MeEt₃NBF₄/(AN+PC)), and two conventional organic electrolytes, tetraethylammonium tetrafluoroborate/acetonitrile (Et₄NBF₄/AN) and tetraethylammonium tetrafluoroborate/propylene carbonate (Et₄NBF₄/PC). Cyclic voltammetry and electrochemical impedance spectroscopy measurements in various voltage windows were conducted. In addition, a comprehensive comparison of these three electrolytes was conducted via data obtained from cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge-discharge, leakage current, self-discharge, cyclic life, and coulombic efficiency within the 0-3 V voltage window. The results indicate that MeEt₃NBF₄/(AN+PC) combining the advantages of AN and PC exhibits excellent performance.
- Supercapacitor,
- Organic electrolyte,
- Activated carbon
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沈阳化工大学材料科学与工程学院沈阳 110142