Citation: CHI Ting-Yu, LI Han, WANG Geng-Chao. Hierarchically Porous Carbon/DMcT/PEDOT-PSS Ternary Composite as a Cathode Material for Lithium-Ion Battery[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 1981-1988. doi: 10.3866/PKU.WHXB201306272 shu

Hierarchically Porous Carbon/DMcT/PEDOT-PSS Ternary Composite as a Cathode Material for Lithium-Ion Battery

1.
Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials, Science and Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 12 April 2013
Available Online: 27 June 2013
Fund Project: 国家自然科学基金项目(51173042) (51173042)上海市教委科研创新项目(11ZZ55) (11ZZ55)

Activated hierarchically porous carbon (aHPC) was fabricated by calcination, etching and KOH activation using phenol-formaldehyde resin (PF) as the carbon precursor and nano-CaCO₃ dispersion as the double pore-forming agent. On this basis, the aHPC/2,5-dimercapto-1,3,4-thiadiazole (DMcT) composite was prepared through a solution immersion method using aHPC as the substrate, and poly(3,4-ethylenedioxythiophene)-poly(4-styrenesulfonate) (PEDOT-PSS) was coated subsequently onto the surface of aHPC/DMcT by in situ oxidative polymerization to prepare the aHPC/DMcT/PEDOT-PSS composite. The structure, morphology, and electrochemical properties of the composite were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and electrochemical measurements. The results showed that the amount of the functional groups in aHPC pores increased after HPC was activated by KOH, resulting in an enhancement (52%) of the adsorption of DMcT. Moreover, almost all of the DMcT was absorbed into the aHPC pores. It was found that the initial discharge capacity of the aHPC/DMcT composite was 236 mAh·g^-1 and its specific capacity remained at 65 mAh·g^-1 after 20 cycles. For comparison, with a surface coated with a layer of PEDOT-PSS conductive film, the initial discharge capacity of the aHPC/DMcT/PEDOT-PSS composite was up to 280 mAh·g^-1 and it remained at 138 mAh·g^-1 after 20 cycles (49.1% capacity retention).
1. [1]
  
  (1) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
2. [2]
  (2) Yin, L. C.; Wang, J. L.; Lin, F. J.; Yang, J.; Nuli, Y. Energy Environ. Sci. 2012, 5, 6966. doi: 10.1039/c2ee03495f
3. [3]
  (3) Wang, J. Z.; Lu, L.; Choucair, M.; Stride, J. A.; Xu, X.; Liu, H.K. J. Power Sources 2011, 196 (16), 7030. doi: 10.1016/j.jpowsour.2010.09.106
4. [4]
  (4) Xin, S.; Guo, Y. G.; Wan, L. J. Accounts Chem. Res. 2012, 45 (10), 1759. doi: 10.1021/ar300094m
5. [5]
  (5) Visco, S. J.; DeJonghe, L. C. J. Electrochem. Soc. 1988, 135 (12), 2905. doi: 10.1149/1.2095460
6. [6]
  (6) Yu, L.; Wang, X. H.; Li, J.; Jing, X. B.; Wang, F. S. Chem. J. Chin. Univ. 2000, 21 (2), 311. [于雷, 王献红, 李季, 景遐斌, 王佛松.高等学校化学学报, 2000, 21 (2), 311.]
7. [7]
  (7) Zhang, J. H.; Zhang, Y. S.; Zheng, M. P.; Qi, L.; Feng, B.; Li, L.Acta Phys. -Chim. Sin. 2007, 23 (Supp), 51. [张敬华, 张永生, 郑绵平, 其鲁,冯波,李立.物理化学学报, 2007, 23 (Supp), 51.] doi: 10.3866/PKU.WHXB2007Supp12
8. [8]
  (8) Henderson, J. C.; Kiya, Y.; Hutchison, G. R.; Abruna, H. D.J. Phys. Chem. C 2008, 112 (10), 3989. doi: 10.1021/jp076774k
9. [9]
  (9) Oyama, N.; Tatsuma, T.; Sato, T.; Sotomura, T. Nature 1995,373, 598. doi: 10.1038/373598a0
10. [10]
  (10) Xue, L. J.; Li, J. X.; Hu, S. Q.; Zhang, M. X.; Zhou, Y. H.;Zhan, C. M. Electrochem. Commun. 2003, 5 (10), 903. doi: 10.1016/j.elecom.2003.08.018
11. [11]
  (11) Kiya, Y.; Hutchison, G. R.; Henderson, J. C.; Sarukawa, T.;Hatozaki, O.; Oyama, N.; Abruña, H. D. Langmuir 2006, 22 (25), 10554. doi: 10.1021/la061213q
12. [12]
  (12) Kiya, Y.; Iwata, A.; Sarukawa, T.; Henderson, J. C.; Abruña, H.D. J. Power Sources 2007, 173, 522. doi: 10.1016/j.jpowsour.2007.04.086
13. [13]
  (13) Chi, T. Y.; Li, H.; Li, X. W.; Bao, H.; Wang, G. C. Electrochim. Acta 2013, 96, 206. doi: 10.1016/j.electacta.2013.02.100
14. [14]
  (14) Canobre, S. C.; Almeida, D. A. L.; Fonseca, C. P.; Neves, S.Electrochem. Acta 2009, 54 (26), 6383. doi: 10.1016/j.electacta.2009.06.002
15. [15]
  (15) Jin, L. F.;Wang, G. C.; Li, X. W.; Li, L. B. J. Appl. Electrochem.2011, 41 (4), 377. doi: 10.1007/s10800-010-0246-z
16. [16]
  (16) Ortega, P.; Vera, L.; Guzman, M. Macromol. Chem. Phys. 1997,198 (9), 2949. doi: 10.1002/macp.1997.021980923
17. [17]
  (17) Park, J. E.; Park, S. G.; Koukitu, A.; Hatozaki, O.; Oyama, N.Synth. Met. 2004, 140 (2-3), 121. doi: 10.1016/j.synthmet.2003.04.001
18. [18]
  (18) Wang, G. C.; Jin, L. F.; Ye, J. K.; Li, X. W. Mater. Chem. Phys.2010, 122 (1), 224. doi: 10.1016/j.matchemphys.2010.02.038
19. [19]
  (19) Xing, W.; Huang, C. C.; Zhuo, S. P.; Yuan, X.; Wang, G. Q.;Hulicova-Jurcakova, D.; Yan, Z. F.; Lu, G. Q. Carbon 2009, 47 (7), 1715. doi: 10.1016/j.carbon.2009.02.024
20. [20]
  (20) Yi, J.; Li, X. P.; Hu, S. J.; Li, W. S.; Zhou, L.; Xu, M. Q.; Lei, J.F.; Hao, L. S. J. Power Sources 2011, 196 (16), 6670. doi: 10.1016/j.jpowsour.2010.12.017
21. [21]
  (21) Hasegawa, G.; Kanamori, K.; Nakanishi, K. Microporous Mesoporous Mat. 2012, 155 (1), 265. doi: 10.1016/j.2012.02.001
22. [22]
  (22) Yang, J.; Zhou, X. Y.; Zou, Y. L. ; Tang, J. J. Electrochim. Acta2011, 56 (24), 8576. doi: 10.1016/j.electacta.2011.07.047
23. [23]
  (23) Guo, B. K.; Wang, X. Q.; Fulvio, P. F.; Chi, M. F.; Mahurin, S.M.; Sun, X. G.; Dai, S. Adv. Mater. 2011, 23 (40), 4661. doi: 10.1002/adma.201102032
24. [24]
  (24) Kim, Y.; Jo, C.; Lee, J.; Lee, C. W.; Yoon, S. J. Mater. Chem.2012, 22, 1453. doi: 10.1039/c1jm15053g
25. [25]
  (25) Pope, J. M.; Sato, T.; Shoji, E.; Oyama, N.;White, K. C.; Buttry,D. A. J. Electrochem. Soc. 2002, 149 (7), A939. doi: 10.1149/1.1482768
26. [26]
  (26) Sun, X. M.; Li, Y. D. Angew. Chem. Int. Edit. 2004, 43 (5), 597.doi: 10.1002/anine.200353212
27. [27]
  (27) Han, Y. Q.; Lu, Y. Synth. Met. 2008, 158 (19-20), 744. doi: 10.1016/j.synthmet.2008.04.028
28. [28]
  (28) Li, J. X.; Zhan, H.; Zhou, Y. H. Electrochem. Commun. 2003, 5 (7), 555. doi: 10.1016/S1388-2481(03)00121-8
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
3. [3]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
4. [4]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
5. [5]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
8. [8]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
9. [9]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
10. [10]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
11. [11]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
12. [12]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
14. [14]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
15. [15]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
16. [16]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
17. [17]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
18. [18]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
19. [19]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
20. [20]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105

Get Citation

PDF

XML

Metrics

PDF Downloads(807)
Abstract views(1369)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142