Citation: CHEN Zong-Yuan, ZHANG Rui, YANG Xing-Long, WU Wang-Suo, GUO Zhi-Jun, LIU Chun-Li. Adsorption of Co(Ⅱ) and Ni(Ⅱ) on Beishan Granite：Surface Complexation Model and Linear Free Energy Relationship[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 2019-2026. doi: 10.3866/PKU.WHXB201306271 shu

Adsorption of Co(Ⅱ) and Ni(Ⅱ) on Beishan Granite：Surface Complexation Model and Linear Free Energy Relationship

1.
1 School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000, P. R. China;
2 Beijing National Laboratory for Molecular Sciences, Radiochemistry & Radiation Chemistry Key Laboratory for Fundamental Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 29 March 2013
Available Online: 27 June 2013
Fund Project: 国家自然科学基金(91226113, 11075006, 91026010) (91226113, 11075006, 91026010)核设施退役和放射性废物治理科研专项(科工计[2012]494号, [2007]840号, [2012]851号) (科工计[2012]494号, [2007]840号, [2012]851号)

The adsorption of Co(Ⅱ) and Ni(Ⅱ) on crushed Beishan granite (BS03, 600 m) was studied by a batch experimental method. The distribution coefficient (K_d) was found to vary as a function of the pH, ionic strength, and the initial concentrations of Co(Ⅱ) and Ni(Ⅱ). In the low pH range, the K_d values of Co(Ⅱ) and Ni(Ⅱ) decreased significantly as the ionic strength increased, whereas the effect of the ionic strength was weak in the high pH range. The adsorption of Co(Ⅱ) and Ni(Ⅱ) on granite was quantitatively interpreted by a model with one cation exchange reaction and two inner-sphere surface complexation reactions. A linear free energy relationship (LFER) between the equilibrium constants (K) of the surface complexation reactions and the hydrolysis stability constants of the divalent transition metals (^OHK) was established. Predictions based on the LFER are in od agreement with the experimental results for the adsorption of Pb(Ⅱ) and Cu(Ⅱ) on granite.
- Beishan granite,
- Adsorption,
- Co(Ⅱ),
- Ni(Ⅱ),
- Surface complexation model,
- Linear free energy relationship
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