Citation: DU Shu-Qing, YUAN Yu-Feng, TU Wei-Xia. Microwave-Hydrothermal Synthesis and Photocatalytic Activity of Zn₂GeO₄ Nanoribbons[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 2062-2068. doi: 10.3866/PKU.WHXB201306213 shu

Microwave-Hydrothermal Synthesis and Photocatalytic Activity of Zn₂GeO₄ Nanoribbons

1.
State Key Laboratory of Organic-Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 26 April 2013
Available Online: 21 June 2013
Fund Project: 国家自然科学基金(21106006)资助项目 (21106006)

Zn₂GeO₄ nanoribbons were synthesized via a microwave-hydrothermal method. The effects of reaction factors, such as reaction temperature, amount of reactants and template, were investigated and optimized for the formation of Zn₂GeO₄ nanoribbons. The products were characterized by various techniques including field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS). Photocatalytic activities of the synthesized Zn₂GeO₄ nanostructures were evaluated for the degradation of aqueous methyl orange. Experimental results indicated that Zn₂GeO₄ nanoribbons can be synthesized from Zn(CH₃COO)₂ and GeO₂ (molar ratio 2: 1) under microwave irradiation at 160℃ for 20 min. The nanoribbons have uniformsizes with widths of 100 nm and are tens of micrometers in length. Compared with conventional hydrothermal methods, Zn₂GeO₄ nanoribbons from microwave-hydrothermal synthesis have less native defects, lower PL spectra, 50.7% larger specific surface area, and 54.7% higher photocatalytic activity.
- Microwave-hydrothermal synthesis,
- Zn₂GeO₄,
- Nanoribbon,
- Photocatalyst,
- Degradation of organics
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沈阳化工大学材料科学与工程学院沈阳 110142

Microwave-Hydrothermal Synthesis and Photocatalytic Activity of Zn2GeO4 Nanoribbons

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通讯作者: 陈斌, bchen63@163.com

Microwave-Hydrothermal Synthesis and Photocatalytic Activity of Zn₂GeO₄ Nanoribbons