Citation: ZHANG Cui-Mei, ZHANG Zhi-Guo, HUANG Cun-Shun, ZHANG Qun, CHEN Yang. Photodissociation Dynamics of Carbonyl Sulfide in Helium Droplets[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 1886-1890. doi: 10.3866/PKU.WHXB201306191 shu

Photodissociation Dynamics of Carbonyl Sulfide in Helium Droplets

1.
1 Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China;
2 State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Received Date: 3 May 2013
Available Online: 19 June 2013
Fund Project: 国家自然科学基金项目(21073187, 21273212, 21173205) (21073187, 21273212, 21173205)国家重点基础研究项目(973)(2010CB923302) (973)(2010CB923302)中国科学技术大学-同步辐射联合基金(KY2340000021)资助 (KY2340000021)

The photodissociation dynamics of carbonyl sulfide (OCS) in helium droplets was studied using a velocity-map-imaging technique. The CO fragments were detected by (2+1)-resonance-enhanced multiphoton ionization. It was found that in the helium droplet environment, rotational cooling is much more efficient than vibrational cooling. The velocity map images for both CO (v=0) and CO (v=1) exhibit nearly isotropic angular distributions. The kinetic energy distributions show that most of the translational energies are relaxed in the finite-sized superfluid helium system. However, the average translational energies of the CO (v=1) images are higher than those of the CO (v=0) images. The relevant mechanism is briefly discussed.
- Heliumdroplet,
- Time-sliced ion imaging,
- OCS
1. [1]
  
  (1) Toennies, J. P.; Vilesov, A. F. Angew. Chem. Int. Edit. 2004, 43,2622.
2. [2]
  (2) Grebenev, S.; Hartmann, M.; Havenith, M.; Sartakov, B.;Toennies, J. P.; Vilesov, A. F. J. Chem. Phys. 2000, 112, 4485.doi: 10.1063/1.481011
3. [3]
  (3) Hartmann, M.; Pörtner, N.; Sartakov, B.; Toennies, J. P.;Vilesov, A. F. J. Chem. Phys. 1999, 110, 5109. doi: 10.1063/1.479111
4. [4]
  (4) Choi, M. Y.; Douberly, G. E.; Falconer, T. M.; Lewis, W. K.;Lindsay, C. M.; Merritt, J. M.; Stiles, P. L.; Miller, R. E. Int. Rev. Phys. Chem. 2006, 25, 15. doi: 10.1080/01442350600625092
5. [5]
  (5) Toennies, J. P.; Vilesov, A. F. Annu. Rev. Phys. Chem. 1998, 49,1. doi: 10.1146/annurev.physchem.49.1.1
6. [6]
  (6) Braun, A.; Drabbels, M. J. Chem. Phys. 2007, 127, 114305. doi: 10.1063/1.2767263
7. [7]
  (7) Braun, A.; Drabbels, M. J. Chem. Phys. 2007, 127, 114303. doi: 10.1063/1.2767261
8. [8]
  (8) Braun, A.; Drabbels, M. J. Chem. Phys. 2007, 127, 114304. doi: 10.1063/1.2767262
9. [9]
  (9) Pentlehner, D.; Nielsen, J. H.; Slenczka, A.; Mølmer, K.;Stapelfeldt, H. Phys. Rev. Lett. 2013, 110, 093002. doi: 10.1103/PhysRevLett.110.093002
10. [10]
  (10) Sato, Y.; Matsumi, Y.; Kawasaki, M.; Tsukiyama, K.; Bersohn,R. J. Phys. Chem. 1995, 99, 16307. doi: 10.1021/j100044a017
11. [11]
  (11) Brouard, M.; Quadrini, F.; Vallance, C. J. Chem. Phys. 2007,127, 084305. doi: 10.1063/1.2757619
12. [12]
  (12) Suzuki, T.; Katayanagi, H.; Nanbu, S.; Aoyagi, M. J. Chem. Phys. 1998, 109, 5778. doi: 10.1063/1.477200
13. [13]
  (13) Sugita, A.; Mashino, M.; Kawasaki, M.; Matsumi, Y.; Bersohn,R.; Trott-Kriegeskorte, G.; Gericke, K. H. J. Chem. Phys. 2000,112, 7095. doi: 10.1063/1.481324
14. [14]
  (14) Kim, M. H.; Li, W.; Lee, S. K.; Suits, A. G. Can. J. Chem. 2004,82, 880. doi: 10.1139/v04-072
15. [15]
  (15) Rakitzis, T. P. Science 2004, 303, 1852. doi: 10.1126/science.1094186
16. [16]
  (16) Brouard, M.; Green, A. V.; Quadrini, F.; Vallance, C. J. Chem. Phys. 2007, 127, 084304. doi: 10.1063/1.2757618
17. [17]
  (17) Rijs, A. M.; Backus, E. H. G.; de Lange, C. A.; Janssen, M. H.M.; Westwood, N. P. C.; Wang, K.; McKoy, V. J. Chem. Phys.2002, 116, 2776. doi: 10.1063/1.1434993
18. [18]
  (18) Katayanagi, H.; Suzuki, T. Chem. Phys. Lett. 2002, 360, 104.doi: 10.1016/S0009-2614(02)00788-1
19. [19]
  (19) Grebenev, S.; Havenith, M.; Madeja, F.; Toennies, J. P.; Vilesov,A. F. J. Chem. Phys. 2000, 113, 9060. doi: 10.1063/1.1286243
20. [20]
  (20) Kunze, M.; Markwick, P. R. L.; Pörtner, N.; Reuss, J.; Havenith,M. J. Chem. Phys. 2002, 116, 7473. doi: 10.1063/1.1467330
21. [21]
  (21) Grebenev, S. Science 1998, 279, 2083. doi: 10.1126/science.279.5359.2083
22. [22]
  (22) Zhang, C.; Zhang, Z.; Huang, C.; Zhang, Q.; Chen, Y. Chin. J. Chem. Phys. 2013, 26, 270. doi: 10.1063/1674-0068/26103/270-276
23. [23]
  (23) van den Brom, A. J.; Rakitzis, T. P.; van Heyst, J.; Kitsopoulos,T. N.; Jezowski, S. R.; Janssen, M. H. M. J. Chem. Phys. 2002,117, 4255. doi: 10.1063/1.1496464
24. [24]
  (24) Mo, Y. X.; Katayanagi, H.; Heaven, M. C.; Suzuki, T. Phys. Rev. Lett. 1996, 77, 830. doi: 10.1103/PhysRevLett.77.830
25. [25]
  (25) Katayanagi, H.; Mo, Y. X.; Suzuki, T. Chem. Phys. Lett. 1995,247, 571. doi: 10.1016/S0009-2614(95)01253-2
26. [26]
  (26) Eppink, A. T. J. B.; Parker, D. H. Rev. Sci. Instrum. 1997, 68,3477. doi: 10.1063/1.1148310
27. [27]
  (27) Dribinski, V.; Ossadtchi, A.; Mandelshtam, V. A.; Reisler, H.Rev. Sci. Instrum. 2002, 73, 2634. doi: 10.1063/1.1482156
28. [28]
  (28) Braun, A.; Drabbels, M. Rev. Sci. Instrum. 2005, 76, 113103.doi: 10.1063/1.2130941
29. [29]
  (29) Lewis, W. K.; Applegate, B. E.; Sztáray, J.; Sztáray, B.; Baer, T.;Bemish, R. J.; Miller, R. E. J. Am. Chem. Soc. 2004, 126,11283. doi: 10.1021/ja030653q
30. [30]
  (30) Fárnšk, M.; Henne, U.; Samelin, B.; Toennies, J. P. Phys. Rev. Lett. 1998, 81, 3892. doi: 10.1103/PhysRevLett.81.3892
31. [31]
  (31) Loginov, E.; Callegari, C.; Ancilotto, F.; Drabbels, M. J. Phys. Chem. A 2011, 115, 6779. doi: 10.1021/jp111146n
32. [32]
  (32) Stienkemeier, F.; Higgins, J.; Ernst, W.; Scoles, G. Phys. Rev. Lett. 1995, 74, 3592. doi: 10.1103/PhysRevLett.74.3592
33. [33]
  (33) Ancilotto, F.; Lerner, P. B.; Cole, M. W. J. Low Temp. Phys.1995, 101, 1123. doi: 10.1007/BF00754527
34. [34]
  (34) Stienkemeier, F.; Higgins, J.; Ernst, W. E.; Scoles, G. Z Physica B 1995, 98, 413. doi: 10.1007/BF01338416
35. [35]
  (35) Smolarek, S.; Brauer, N. B.; Buma, W. J.; Drabbels, M. J. Am. Chem. Soc. 2010, 132, 14086. doi: 10.1021/ja1034655
36. [36]
  (36) Zhang, X.; Brauer, N. B.; Berden, G.; Rijs, A. M.; Drabbels, M.J. Chem. Phys. 2012, 136, 044305. doi: 10.1063/1.3678011
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