Citation: WANG Wu-Gang, ZHANG Shao-Long, ZHANG Lan-Lan, WANG Yan, LIU Xiao-Ling, NG Yan-Jun, DOU Tao. Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO₂/Al₂O₃ Molar Ratios[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 2035-2040. doi: 10.3866/PKU.WHXB201306183 shu

Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO₂/Al₂O₃ Molar Ratios

1.
State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation, College of Chemistry Engineering, University of Petroleum-Beijing, Beijing 102249, P. R. China

Received Date: 25 April 2013
Available Online: 18 June 2013
Fund Project: 国家重点基础研究发展计划(973)项目(2012CB215002) (973)项目(2012CB215002)国家自然科学基金(21276278, 21176255) (21276278, 21176255)中国石油天然气集团公司项目(2011A-2101)资助 (2011A-2101)

Nanosheet ZSM-5 zeolites with different SiO₂/Al₂O₃ molar ratios have been hydrothermally synthesized by an organic surfactant with a diquaternary ammoniumgroup. The samples were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, X-ray fluorescence spectroscopy (XRF), scanning electron microscopy (SEM) and ²⁷Al magic angle spinning nuclear magnetic resonance (²⁷Al MAS-NMR) techniques. The synthesis conditions of the nanosheets ZSM-5 were studied, including the synthesis factors such as crystallization temperature and time, the amount of structure-directing agent (SDA) and alkalinity. The results showed that shorter crystallization times were required when synthesis was conducted at higher crystallization temperatures, higher SiO₂/Al₂O₃ ratios, larger amounts of structure-directing agent were used, and higher SiO₂/Al₂O₃ ratios. The morphology, BET and mesopore volume changed with increasing SiO₂/Al₂O₃.
- Nanosheet,
- ZSM-5 zeolite,
- Synthetic chemistry,
- SiO₂/Al₂O₃ ratio
1. [1]
  
  (1) Srivastava, R.; Choi, M.; Ryoo, R. Chem. Commun. 2006, 4489.
2. [2]
  (2) Tian, Y.; Li, Y. D. Journal of Chemical Industry and Engineering 2013, 64 (2), 393. [田野,李永丹.化工学报,2013, 64 (2), 393.]
3. [3]
  (3) Zhang, C.; Liu, Q.; Xu, Z.; Wan, K. Microporous Mesoporous Mat. 2003, 62, 157. doi: 10.1016/S1387-1811(03)00427-X
4. [4]
  (4) Bernasconi, S.; van Bokhoven, J. A.; Krumeich, F.; Pirngruber,G. D.; Prins, R. Microporous Mesoporous Mat. 2003, 66,21. doi: 10.1016/j.micromeso.2003.08.022
5. [5]
  (5) Triantafillidis, C. S.; Vlessidis, A. G.; Nalbandian, L.;Evmiridis, N. P. Microporous Mesoporous Mat. 2001, 47,369. doi: 10.1016/S1387-1811(01)00399-7
6. [6]
  (6) Ogura, M.; Shinomiya, S. Y.; Tateno, J.; Nara, Y.; Nomura, M.;Kikuchi, E.; Matsukata, M. Appl. Catal. 2001, 219, 33. doi: 10.1016/S0926-860X(01)00645-7
7. [7]
  (7) Wang, J.; Chen, D. M.; Gu, H. W.; Teng, H.; Ren, X. Q. Nanjing Technol. Univ. (Nat. Sci.) 2010, 32 (4), 100. [王军,陈德民,顾海威,滕晖,任晓乾.南京工业大学学报, 2010, 32 (4),100.]
8. [8]
  (8) Jacobsen, C. J. H.; Madsen, C.; Houzvicka, J.; Schmidt, I.;Carlsson, A. J. Am. Chem. Soc. 2000, 122, 7116. doi: 10.1021/ja000744c
9. [9]
  (9) Schmidt, I.; Krogh, A.;Wienberg, K.; Carlsson, A.; Brorson,M.; Jacobsen, C. J. H. Chem. Commun. 2000, 2157.
10. [10]
  (10) Yang, Z. X.; Xia, Y. D.; Mokaya, R. Adv. Mater. 2004, 16, 727.
11. [11]
  (11) Xiao, F. S.; Wang, L.; Yin, C.; Lin, K.; Di, Y.; Li, J.; Xu, R.; Su,D. S.; Schlögl, R.; Yokoi, T.; Tatsumi, T. Angew. Chem. 2006,118, 3162.
12. [12]
  (12) Na, K.; Kim, J.; Ryoo, R. Science 2011, 333, 328. doi: 10.1126/science.1204452
13. [13]
  (13) Choi, M.; Na, K.; Kim, J.; Sakamoto, Y.; Terasaki, O.; Ryoo, R.Nature 2009, 461, 246. doi: 10.1038/nature08288
14. [14]
  (14) Na, K.; Choi, M.; Park, W.; Sakamoto, Y.; Terasaki, O.; Ryoo,R. J. Am. Chem. Soc. 2010, 132, 4169. doi: 10.1021/ja908382n
15. [15]
  (15) Na, K.; Park, W.; Seo, Y.; Ryoo, R. Chem. Mater. 2011, 23,1273. doi: 10.1021/cm103245m
16. [16]
  (16) Ma, H.; Zhao, Z. L.; Tang, S. J.; Hu, J.; Liu, H. L. Acta Phys. -Chim. Sin. 2011, 27 (3), 689. [马辉,赵志玲,唐圣杰, 胡军, 刘洪来. 物理化学学报, 2011, 27 (3), 389.] doi: 10.3866/PKU.WHXB20110335
17. [17]
  (17) Kim, J.; Choi, M.; Ryoo, R. J. Catal. 2010, 269, 219. doi: 10.1016/j.jcat.2009.11.009
18. [18]
  (18) Seo, Y.; Cho, K.; Jung, Y.; Ryoo, R. ACS Catal. 2013, 3,713. doi: 10.1021/cs300824e
19. [19]
  (19) Hu, S.; Shan, J.; Zhang, Q.; Wang, Y.; Liu, Y. S.; ng, Y. J.;Wu, Z. J.; Dou, T. Appl. Catal. A 2012, 445-446, 215.
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Hongyan Chen , Yajun Hou , Shui Hu , Zhuoxun Wei , Fang Zhu , Chengyong Su . Construction of Synthetic Chemistry Experiment of the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 58-63. doi: 10.12461/PKU.DXHX202409109
5. [5]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008
6. [6]
  Xinyu You , Xin Zhang , Shican Jiang , Yiru Ye , Lin Gu , Hexun Zhou , Pandong Ma , Jamal Ftouni , Abhishek Dutta Chowdhury . Efficacy of Ca/ZSM-5 zeolites derived from precipitated calcium carbonate in the methanol-to-olefin process. Chinese Journal of Structural Chemistry, 2024, 43(4): 100265-100265. doi: 10.1016/j.cjsc.2024.100265
7. [7]
  Yong Shu , Xing Chen , Sai Duan , Rongzhen Liao . How to Determine the Equilibrium Bond Distance of Homonuclear Diatomic Molecules: A Case Study of H₂. University Chemistry, 2024, 39(7): 386-393. doi: 10.3866/PKU.DXHX202310102
8. [8]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
9. [9]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
10. [10]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
11. [11]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
12. [12]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
13. [13]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
14. [14]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
15. [15]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137
16. [16]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
17. [17]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
18. [18]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
19. [19]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
20. [20]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170

Get Citation

PDF

XML

Metrics

PDF Downloads(959)
Abstract views(862)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO2/Al2O3 Molar Ratios

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Characterization of Nanosheet ZSM-5 Zeolites with Different SiO₂/Al₂O₃ Molar Ratios