Citation: SHI Qin, MEN Chun-Yan, LI Juan. Preparation and Electrochemical Capacitance Properties of Graphene Oxide/Polypyrrole Intercalation Composite[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1691-1697. doi: 10.3866/PKU.WHXB201306031 shu

Preparation and Electrochemical Capacitance Properties of Graphene Oxide/Polypyrrole Intercalation Composite

1.
College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China

Received Date: 8 March 2013
Available Online: 3 June 2013
Fund Project: 新疆大学博士启动基金项目(BS110112) (BS110112) 乌鲁木齐科技计划项目(H101133001) (H101133001)国家自然科学基金(21262035)资助 (21262035)

Graphene oxide/polypyrrole ( /PPy) intercalation composite was successfully prepared via in-situ chemical oxidative polymerization of pyrrole monomers by using methyl orange (MO) as a template agent. The morphology and microstructure of the composite were characterized by X-ray diffraction (XRD) analysis, Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). In addition, the electrochemical properties of the composite material were investigated by cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy techniques in two different aqueous electrolytes (1 mol·L^-1 Na₂SO₄ and 1 mol·L^-1 H₂SO₄). The results indicated that the /PPy intercalation composite displayed considerable specific capacitance in both neutral and acid electrolytes, which is attributed to taking full advantage of the superior properties and synergy of graphene oxide and polypyrrole. The /PPy intercalation composite exhibited the specific capacitance of 449.1 and 619.0 F·g^-1 in the Na₂SO₄ and H₂SO₄ electrolytes, respectively, at a current density of 0.5 A·g^-1. This is significantly higher than the corresponding specific capacitance of pure PPy. After 800 cycling test, the specific capacitance of the composite remained about 92% and 62% of the initial capacitance in the two different electrolytes, respectively. A higher initial capacitance was obtained in the acidic electrolyte, but the composite showed better electrochemical cyclic stability in the neutral electrolyte.
- Graphene oxide,
- Polypyrrole,
- Intercalation composite,
- Electrode material,
- Electrochemical capacitance property
1. [1]
  
  (1) Snook, G. A.; Kao, P.; Best, A. S. J. Power Sources 2011, 196,1. doi: 10.1016/j.jpowsour.2010.06.084
2. [2]
  (2) Wang, G. P.; Zhang, L.; Zhang, J. J. Chem. Soc. Rev. 2012, 41,797. doi: 10.1039/c1cs15060j
3. [3]
  (3) Wang, J. P.; Xu, Y. L.; Zhu, J. B.; Ren, P. G. J. Power Sources2012, 208, 138. doi: 10.1016/j.jpowsour.2012.02.018
4. [4]
  (4) Wang, J. P.; Xu, Y. L.;Wang, J.; Du, X. F. Synthetic Metals2011, 161, 1141. doi: 10.1016/j.synthmet.2011.01.011
5. [5]
  (5) Zhang, D. C.; Zhang, X.; Chen, Y.; Yu, P.;Wang, C. H.; Ma, Y.W. J. Power Sources 2011, 196, 5990. doi: 10.1016/j.jpowsour.2011.02.090
6. [6]
  (6) Zhu, J. B.; Xu, Y. L.;Wang, J.;Wang, J. P. Acta Phys. -Chim. Sin. 2012, 28, 373. [朱剑波, 徐友龙, 王杰, 王景平. 物理化学学报, 2012, 28, 373.] doi: 10.3866/PKU.WHXB201112021
7. [7]
  (7) Sahoo, S.; Nayak, G. C.; Das, C. K. Macromol. Symp. 2012,315, 177. doi: 10.1002/masy.v315.1
8. [8]
  (8) Li, L. Y.; Xia, K. Q.; Li, L.; Shang, S. M.; Guo, Q. Z.; Yan, G. P.J. Nanopart. Res. 2012, 14, 908. doi: 10.1007/s11051-012-0908-3
9. [9]
  (9) Xu, J. J.;Wang, K.; Zu, S. Z.; Han, B. H.;Wei, Z. X. ACS Nano2010, 4, 5019. doi: 10.1021/nn1006539
10. [10]
  (10) Xu, C. H.; Sun, J.; Gao, L. J. Mater. Chem. 2011, 21, 11253.doi: 10.1039/c1jm11275a
11. [11]
  (11) Ding, B.; Lu, X. J.; Yuan, C. Z.; Yang, S. D.; Han, Y. Q.; Zhang,X. G.; Che, Q. Electrochimica Acta 2012, 62, 132. doi: 10.1016/j.electacta.2011.12.011
12. [12]
  (12) Zhang, H. Y.; Hu, Z. A.; Zhang, F. H.; Liang, P. J.; Zhang, Y. J.;Yang, Y. Y.; Zhang, Z. Y.;Wu, H. Y. Chinese Journal of Applied Chemisty 2012, 29, 674. [张海英, 胡中爱, 张富海, 梁鹏举,张亚军, 杨玉英, 张子瑜, 吴红英. 应用化学, 2012, 29, 674.]
13. [13]
  (13) Zhu, C. Z.; Zhai, J. F.;Wen, D.; Dong, S. J. J. Mater. Chem.2012, 22, 6300. doi: 10.1039/c2jm16699b
14. [14]
  (14) Chang, H. H.; Chang, C. K.; Tsai, Y. C.; Liao, C. S. Carbon2012, 50, 2331. doi: 10.1016/j.carbon.2012.01.056
15. [15]
  (15) Yang, X. M.; Zhu, Z. X.; Dai, T. Y.; Lu, Y. Macromol. Rapid Commun. 2005, 26, 1736.
16. [16]
  (16) Tang, L. H.;Wang, Y.; Li, Y. M.; Feng, H. B.; Lu, J.; Li, J. H.Adv. Funct. Mater. 2009, 19, 2782. doi: 10.1002/adfm.v19:17
17. [17]
  (17) Feng, X. M.; Li, R. M.; Yan, Z. Z.; Liu, X. F.; Chen, R. F.; Ma,Y.W.; Li, X. A.; Fan, Q. L.; Huang,W. IEEE Transaction on Nanotechnology 2012, 11, 1080. doi: 10.1109/TNANO.2012.2200259
18. [18]
  (18) Fan, Z. J.; Kai,W.; Yan, J.;Wei, T.; Zhi, L. J.; Feng, J.; Ren, Y.M.; Song, L. P.;Wei, F. ACS Nano 2011, 5, 191. doi: 10.1021/nn102339t
19. [19]
  (19) Zhang, L. L.; Zhao, S. Y.; Tian, X. N.; Zhao, X. S. Langmuir2010, 26, 17624. doi: 10.1021/la103413s
20. [20]
  (20) Gu, Z. M.; Li, C. Z.;Wang, G. C.; Zhang, L.; Li, X. H.;Wang,W. D.; Jin, S. L. Journal of Polymer Science Part B: Polymer Physics 2010, 48, 1329. doi: 10.1002/polb.v48:12
21. [21]
  (21) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
22. [22]
  (22) Zu, S. Z.; Han, B. H. J. Phys. Chem. C 2009, 113, 13651.
23. [23]
  (23) Meyer, J. C.; Geim, A. K.; Katsnelson, M. I.; Novoselov, K. S.;Obergfell, D.; Roth, S.; Girit, C.; Zettl, A. Solid State Communication 2007, 143, 101. doi: 10.1016/j.ssc.2007.02.047
24. [24]
  (24) Tian, Y.; Yang, F. L.; Yang,W. S. Synthetic Metals 2006, 156,1052. doi: 10.1016/j.synthmet.2006.06.023
25. [25]
  (25) Cai, Y. M.; Qin, Z. Y.; Chen, L. Progress in Natural Science: Material International 2011, 21, 460. doi: 10.1016/S1002-0071(12)60083-5
26. [26]
  (26) Sahoo, S.; Karthikeyan, G.; Nayak, G. C.; Das, C. K. Synthetic Metals 2011, 161, 1723.
27. [27]
  (27) Zhang, K.; Zhang, L. L.; Zhao, X. S.;Wu, J. S. Chem. Mater.2010, 22, 1392. doi: 10.1021/cm902876u
28. [28]
  (28) Sahoo, S.; Dhibar, S.; Das, C. K. Express Polymer Letters 2012,6, 965. doi: 10.3144/expresspolymlett.2012.102
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
3. [3]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
6. [6]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
7. [7]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
8. [8]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
9. [9]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
10. [10]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
11. [11]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
12. [12]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
13. [13]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
14. [14]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
15. [15]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
16. [16]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
17. [17]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
18. [18]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
19. [19]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
20. [20]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

Get Citation

PDF

XML

Metrics

PDF Downloads(1289)
Abstract views(1078)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142