Citation: MA Kai-Guo, FANG Tan, BAI Jin-Yi, GUO Hai-Qing. Effects of Derivatives of 3-Mercaptoisobutyric Acid on the Aqueous Synthesis of CdTe Quantum Dots[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1814-1818. doi: 10.3866/PKU.WHXB201305301 shu

Effects of Derivatives of 3-Mercaptoisobutyric Acid on the Aqueous Synthesis of CdTe Quantum Dots

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 4 February 2013
Available Online: 30 May 2013
Fund Project: 国家重点基础研究发展规划项目(973) (2011CB933300)资助 (973) (2011CB933300)

Mercapto acids can affect the obtaining CdTe quantum dots (QDs) with narrow size distribution and high fluorescent quantum yield (QY) that emit in the red to near-infrared region. To study their effects on CdTe QDs, three types of derivatives of 3-mercaptoisobutyric acid (MIBA) were designed and synthesized: hydrophilic side-chain derivative N-acetylcysteine (ACys), hydrophobic side-chain derivatives 3-mercapto-2-methylbutyric acid (MMBA) and 3-mercapto-2,2-dimethylpropanoic acid (MDMPA), and hydrophilic main-chain derivatives 3-mercaptoisobutoyl-3-aminopropanoic acid (MIBAPA), 3-mercaptoisobutoylglycine (MIBGly) and 3-mercaptoisobutoylaspartic acid (MIBAsp). To evaluate the effects of these MIBA derivatives on the properties of CdTe QDs, they were used as capping agents during hydrothermal synthesis of the QDs with sodium tellurite as the tellurium source. The effects of the mercapto acids were revealed by comparing the growth rate, and full width at half-maximum (FWHM) of the fluorescent peak of CdTe QDs capped with different mercapto acids. All three types of MIBA derivatives gave CdTe QDs with relatively narrow FWHM, similar to MIBA. The hydrophilic MIBA derivatives (ACys, MIBGly, MIBAPA, and MIBAsp) produced CdTe QDs with longer emission wavelength than those from hydrophobic derivatives. Hydrophilic side-chain MIBA, derivative ACys gave CdTe QDs with stronger fluorescence.
- 3-Mercaptoisobutyric acid,
- 3-Mercaptoisobutoylamino acid,
- N-Acetylcysteine,
- Aqueous synthesis
1. [1]
  
  (1) Medintz, I. L.; Uyeda, H. T.; ldman, E. R.; Mattoussi, H. Nat. Mater. 2005, 4 (6), 435. doi: 10.1038/nmat1390
2. [2]
  (2) Michalet, X.; Pinaud, F. F.; Bentolila, L. A.; Tsay, J. M.; Doose,S.; Li, J. J.; Sundaresan, G.;Wu, A. M.; Gambhir, S. S.;Weiss,S. Science 2005, 307 (5709), 538. doi: 10.1126/science.1104274
3. [3]
  (3) Ling, X.; Deng, D.W.; Zhong,W. Y.; Yu, J. S. Spectrosc. Spect. Anal. 2008, 28 (6), 1317. [凌霞, 邓大伟, 钟文英, 于俊生.光谱学与光谱分析, 2008, 28 (6), 1317.]
4. [4]
  (4) Liu, X.; Chen, D. N.; Qu, J. L.; Yang, J. T.; Luo, Y. X.; Roy, I.;Wang, X. M.; Lin, X. T.; Zhong, L.; Prasad, P. N.; Xu, G. X.;Niu, H. B. Spectrosc. Spect. Anal. 2010, 30 (5), 1290.[刘夏, 陈丹妮, 屈军乐, 杨坚泰, 罗永祥, Roy, Indrajit, 王晓梅, 林晓潭, 钟磊, Prasad, N Paras, 许改霞, 牛憨笨. 光谱学与光谱分析, 2010, 30 (5), 1290.]
5. [5]
  (5) Zhang, L. P.; Hu, B.;Wang, J. H. Chem. J. Chin. Univ. 2011, 32 (3), 688. [张立佩, 胡博, 王建华. 高等学校化学学报,2011, 32 (3), 688.]
6. [6]
  (6) Wang, S. S.;Wang, X. T.; Guo, M. M.; Yu, J. S. Chem. J. Chin. Univ. 2012, 33 (6), 1195. [王珊珊, 王雪婷, 郭明明, 于俊生.高等学校化学学报, 2012, 33 (6), 1195.]
7. [7]
  (7) Gaponik, N.; Talapin, D. V.; Rogach, A. L.; Hoppe, K.;Shevchenko, E. V.; Kornowski, A.; Eychmuller, A.;Weller, H.J. Phys. Chem. B 2002, 106 (29), 7177. doi: 10.1021/jp025541k
8. [8]
  (8) Peng, J.; Fang, X. M.; Chen, Z. H.; Zhang, Z. G. Acta Phys. -Chim. Sin. 2012, 28 (1), 232. [彭静, 方晓明, 陈志鸿, 张正国. 物理化学学报, 2012, 28 (1), 232.] doi: 10.3866/PKU.WHXB201111151
9. [9]
  (9) Wang, Y.; Hou, Y. B.; Tang, A.W.; Feng, B.; Li, Y.; Teng, F.Acta Phys. -Chim. Sin. 2008, 24 (2), 296. [王琰, 侯延冰, 唐爱伟, 封宾, 李妍, 滕枫. 物理化学学报, 2008, 24 (2),296.] doi: 10.3866/PKU.WHXB20080219
10. [10]
  (10) Xu, Z.; Li, D. M.; Yao, Y. L.; Xiong, T. T. Acta Phys. -Chim. Sin.2009, 25 (6), 1201. [许臻, 李冬梅, 姚亚玲, 熊婷婷. 物理化学学报, 2009, 25 (6), 1201.] doi: 10.3866/PKU.WHXB20090626
11. [11]
  (11) Zheng, L. S.; Feng, M.; Zhan, H. B. Acta Phys. -Chim. Sin.2012, 28 (1), 208. [郑立思, 冯苗, 詹红兵. 物理化学学报,2012, 28 (1), 208.] doi: 10.3866/PKU.WHXB201228208
12. [12]
  (12) Rogach, A. L.; Franzl, T.; Klar, T. A.; Feldmann, J.; Gaponik,N.; Lesnyak, V.; Shavel, A.; Eychmuller, A.; Rakovich, Y. P.;Donegan, J. F. J. Phys. Chem. C 2007, 111 (40), 14628. doi: 10.1021/jp072463y
13. [13]
  (13) Zhang, H.;Wang, L. P.; Xiong, H. M.; Hu, L. H.; Yang, B.; Li,W. Adv. Mater. 2003, 15 (20), 1712.
14. [14]
  (14) Bao, H. B.; ng, Y. J.; Li, Z.; Gao, M. Y. Chem. Mater. 2004,16 (20), 3853. doi: 10.1021/cm049172b
15. [15]
  (15) Zhang, H.;Wang, D. Y.; Mohwald, H. Angew. Chem. Int. Edit.2006, 45 (5), 748.
16. [16]
  (16) He, Y.; Sai, L. M.; Lu, H. T.; Hu, M.; Lai,W. Y.; Fan, Q. L.;Wang, L. H.; Huang,W. Chem. Mater. 2007, 19 (3), 359. doi: 10.1021/cm061863f
17. [17]
  (17) Zou, L.; Gu, Z. Y.; Zhang, N.; Zhang, Y. L.; Fang, Z.; Zhu,W.H.; Zhong, X. H. J. Mater. Chem. 2008, 18 (24), 2807. doi: 10.1039/b801418c
18. [18]
  (18) Gaponik, N.; Hickey, S. G.; Dorfs, D.; Rogach, A. L.;Eychmuller, A. Small 2010, 6 (13), 1364. doi: 10.1002/smll.v6:13
19. [19]
  (19) Gaponik, N.; Rogach, A. L. Phys. Chem. Chem. Phys. 2010, 12 (31), 8685. doi: 10.1039/c000916d
20. [20]
  (20) Li, Y. L.; Jing, L. H.; Qiao, R. R.; Gao, M. Y. Chem. Commun.2011, 47 (33), 9293. doi: 10.1039/c1cc11331c
21. [21]
  (21) Lesnyak, V.; Gaponik, N.; Eychmuller, A. Chem. Soc. Rev.2013, 42 (7), 2905. doi: 10.1039/c2cs35285k
22. [22]
  (22) Acar, H. Y.; Kas, R.; Yurtsever, E.; Ozen, C.; Lieberwirth, I.J. Phys. Chem. C 2009, 113 (23), 10005. doi: 10.1021/jp811104s
23. [23]
  (23) Fang, T.; Ma, K. G.; Ma, L. L.; Bai, J. Y.; Li, X.; Song, H. H.;Guo, H. Q. J. Phys. Chem. C 2012, 116 (22), 12346. doi: 10.1021/jp302820u
24. [24]
  (24) Ma, K. G.; Fang, T.; Bai, J. Y.; Guo, H. Q. RSC Adv. 2013, 3 (15), 4935. doi: 10.1039/c3ra22877k
25. [25]
  (25) Ma, K. G.; Bai, J. Y.; Fang, T.; Guo, H. Q. Nano doi: 10.1142/S1793292013500495.
26. [26]
  (26) Aldeek, F.; Balan, L.; Lambert, J.; Schneider, R.Nanotechnology 2008, 19 (47), 475401. doi: 10.1088/0957-4484/19/47/475401
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