Citation: LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou. Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K₂Mn₄O₈ Nanocomposites as Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1681-1690. doi: 10.3866/PKU.WHXB201305223 shu

Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K₂Mn₄O₈ Nanocomposites as Supercapacitors

1.
1 School of Material Science and Engineering, Tongji University, Shanghai 200092, P. R. China;
2 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 200092, P. R. China

Received Date: 27 February 2013
Available Online: 22 May 2013
Fund Project: 国家自然科学基金(51175162)资助项目 (51175162)

Nanocomposites of partially reduced graphene oxide ( )-K₂Mn₄O₈ were synthesized via a hydrothermal process at different temperatures and molar feed ratios of to KMnO₄. X-ray diffraction (XRD) analysis confirmed that both α-MnO₂ and a novel crystal phase of K₂Mn₄O₈ were obtained under the investigated hydrothermal conditions. X-ray photoelectron spectroscopy (XPS) revealed diverse changes of the oxygen-containing functional groups on the surface of depending on temperature and molar feed ratio. The microstructure of the composites was studied to help understand their electrochemical properties. A flaky structure of reduced graphene oxide (r ) covered by nanoparticles was observed by scanning electron microscope (SEM), which was considered to be favorable for charge transfer. The capacitive properties of the composites were compared using cyclic voltammograms and galvanostatic charge-discharge measurements. The specific capacitance of the optimal sample was calculated to be 251 F·g^-1 with an energy density of 32 Wh·kg^-1 and a power density of 18.2 kW·kg^-1 in 1 mol·L^-1 Na₂SO₄ electrolyte at a current density of 1 A·g^-1 between 0 and 1 V. Moreover, the capacitance retention ratio of this sample remained at 88% after 1000 cycles at a high current density of 5 A·g^-1.
- Supercapacitor,
- Reduced graphene oxide,
- Potassium manganese oxide,
- Manganese oxide,
- Composite,
- Capacitive behavior
1. [1]
  
  (1) Wang, G.; Zhang, L.; Zhang, J. Chem. Soc. Rev. 2012, 41 (2),797. doi: 10.1039/c1cs15060j
2. [2]
  (2) Wang, X.; Li, G.; Chen, Z.; Augustyn, V.; Ma, X.;Wang, G.;Dunn, B.; Lu, Y. Adv. Energy Mater. 2011, 1 (6), 1089. doi: 10.1002/aenm.201100332
3. [3]
  (3) Chen, Z.;Wen, J.; Yan, C.; Rice, L.; Sohn, H.; Shen, M.; Cai,M.; Dunn, B.; Lu, Y. Adv. Energy Mater. 2011, 1 (4), 551. doi: 10.1002/aenm.201100114
4. [4]
  (4) Guo, P. Z.; Ji, Q. Q.; Zhang, L. L.; Zhao, S. Y.; Zhao, X. S. ActaPhys. -Chim. Sin. 2011, 27 (12), 2836. [郭培志, 季倩倩, 张丽莉, 赵善玉, 赵修松. 物理化学学报, 2011, 27 (12), 2836.] doi: 10.3866/PKU.WHXB20112836
5. [5]
  (5) Lin, Y. H.;Wei, T. Y.; Chien, H. C.; Lu, S. Y. Adv. Energy Mater.2011, 1 (5), 901. doi: 10.1002/aenm.201100256
6. [6]
  (6) Yu, G.; Hu, L.; Vosgueritchian, M.;Wang, H.; Xie, X.;McDonough, J. R.; Cui, X.; Cui, Y.; Bao, Z. Nano Lett. 2011, 11 (7), 2905. doi: 10.1021/nl2013828
7. [7]
  (7) Sharma, P.; Bhatti, T. S. Energy Convers. Manag. 2010, 51 (12),2901. doi: 10.1016/j.enconman.2010.06.031
8. [8]
  (8) Zhang, L. L.; Zhao, X. S. Chem. Soc. Rev. 2009, 38 (9), 2520.doi: 10.1039/b813846j
9. [9]
  (9) Ghosh, A.; Lee, Y. H. ChemSusChem 2012, 5 (3), 480. doi: 10.1002/cssc.201100645
10. [10]
  (10) Sop?i?, S.; Mandi?, Z.; Inzelt, G.; Rokovi?, M. K.; Meštrovi?,E. J. Power Sources 2011, 196 (10), 4849. doi: 10.1016/j.jpowsour.2011.01.070
11. [11]
  (11) Bharali, P.; Kuratani, K.; Takeuchi, T.; Kiyobayashi, T.;Kuriyama, N. J. Power Sources 2011, 196 (18), 7878. doi: 10.1016/j.jpowsour.2011.03.097
12. [12]
  (12) Zhang, Y.; Feng, H.;Wu, X.;Wang, L.; Zhang, A.; Xia, T.;Dong, H.; Li, X.; Zhang, L. Int. J. Hydrog. Energy 2009, 34 (11), 4889. doi: 10.1016/j.ijhydene.2009.04.005
13. [13]
  (13) Hu, Y. Y.; Hu, Z. A.; Zhang, Y. J.; Lu, A. L.; Xu, H.; Zhang, Z.Y.; Yang, Y. Y.; Li, L.;Wu, H. Y. Acta Phys. -Chim. Sin. 2013,29 (2), 305. [胡英瑛, 胡中爱, 张亚军, 鲁爱莲, 徐欢, 张子瑜, 杨玉英, 李丽, 吴红英. 物理化学学报, 2013, 29 (2),305.] doi: 10.3866/PKU.WHXB201211201
14. [14]
  (14) Lee, J.W.; Ahn, T.; Kim, J. H.; Ko, J. M.; Kim, J. D.Electrochim. Acta 2011, 56 (13), 4849. doi: 10.1016/j.electacta.2011.02.116
15. [15]
  (15) Xu, J.; Gao, L.; Cao, J.;Wang,W.; Chen, Z. J. Solid StateElectrochem. 2011, 15 (9), 2005. doi: 10.1007/s1008-010-1222-6
16. [16]
  (16) Fan, Z.; Chen, J.; Cui, K.; Sun, F.; Xu, Y.; Kuang, Y.Electrochim. Acta 2007, 52 (9), 2959. doi: 10.1016/j.electacta.2006.09.029
17. [17]
  (17) Burke, A. Electrochim. Acta 2007, 53 (3), 1083. doi: 10.1016/j.electacta.2007.01.011
18. [18]
  (18) Cottineau, T.; Toupin, M.; Delahaye, T.; Brousse, T.; Bélanger,D. Appl. Phys. A 2006, 82 (4), 599. doi: 10.1007/s00339-005-3401-3
19. [19]
  (19) Li, Y.; Xie, H.;Wang, J.; Chen, L. Mater. Lett. 2011, 65 (2), 403.doi: 10.1016/j.matlet.2010.10.048
20. [20]
  (20) Chen, Z.; Jiao, Z.; Pan, D.; Li, Z.;Wu, M.; Shek, C. H.;Wu, C.M.; Lai, J. K. Chem. Rev. 2012, 112 (7), 3833. doi: 10.1021/cr2004508
21. [21]
  (21) Beaudrouet, E.; Le Gal La Salle, A.; Guyomard, D. Electrochim.Acta 2009, 54 (4), 1240. doi: 10.1016/j.electacta.2008.08.072
22. [22]
  (22) Zhang, J.; Jiang, J.; Zhao, X. S. J. Phys. Chem. C 2011, 115 (14), 6448. doi: 10.1021/jp200724h
23. [23]
  (23) Yu, G.; Hu, L.; Liu, N.;Wang, H.; Vosgueritchian, M.; Yang, Y.;Cui, Y.; Bao, Z. Nano Lett. 2011, 11 (10), 4438. doi: 10.1021/nl2026635
24. [24]
  (24) Wang, Y. T.; Lu, A. H.; Zhang, H. L.; Li,W. C. J. Phys. Chem. C2011, 115 (13), 5413. doi: 10.1021/jp110938x
25. [25]
  (25) Wang, H.; Peng, C.; Peng, F.; Yu, H.; Yang, J. Mater. Sci. Eng. B2011, 176 (14), 1073. doi: 10.1016/j.mseb.2011.05.043
26. [26]
  (26) Zhu, G.; Li, H.; Deng, L.; Liu, Z. H. Materials Letters 2010, 64 (16), 1763. doi: 10.1016/j.matlet.2010.05.019
27. [27]
  (27) Pang, X.; Ma, Z. Q.; Zuo, L. Acta Phys. -Chim. Sin. 2009, 25 (12), 2433. [庞旭, 马正青, 左列. 物理化学学报, 2009,25 (12), 2433.] doi: 10.3866/PKU.WHXB20091211
28. [28]
  (28) Zhao, J. Z.; Tao, Z. L.; Liang, J.; Chen, J. Cryst. Growth Des.2008, 8 (8), 2799. doi: 10.1021/cg701044b
29. [29]
  (29) Devaraj, S.; Munichandraiah, N. J. Phys. Chem. C 2008, 112 (11), 4406. doi: 10.1021/jp7108785
30. [30]
  (30) Yu, J.; Zhao, T.; Zeng, B. Electrochem. Commun. 2008, 10 (9),1318. doi: 10.1016/j.elecom.2008.06.028
31. [31]
  (31) Qiu, G.; Huang, H.; Dharmarathna, S.; Benbow, E.; Stafford, L.;Suib, S. L. Chem. Mater. 2011, 23 (17), 3892. doi: 10.1021/cm2011692
32. [32]
  (32) Yang, Y. Y.; Xiao, L. F.; Zhao, Y. Q.;Wang, F. Y. Int. J.Electrochem. Sci. 2008, 3 (1), 67.
33. [33]
  (33) Subramanian, V.; Zhu, H.W.; Vajtai, R.; Ajayan, P. M.;Wei, B.Q. J. Phys. Chem. B 2005, 109 (43), 20207. doi: 10.1021/jp0543330
34. [34]
  (34) Xiao,W.;Wang, D. L.; Lou, X.W. J. Phys. Chem. C 2010, 114 (3), 1694. doi: 10.1021/jp909386d
35. [35]
  (35) Xu, M.; Kong, L.; Zhou,W.; Li, H. J. Phys. Chem. C 2007, 111 (51), 19141. doi: 10.1021/jp076730b
36. [36]
  (36) Wang, H.; Lu, Z.; Qian, D.; Li, Y.; Zhang,W. Nanotechnology2007, 18 (11), 115616. doi: 10.1088/0957-4484/18/11/115616
37. [37]
  (37) Li, Z.;Wang, J.; Liu, S.; Liu, X.; Yang, S. J. Power Sources2011, 196 (19), 8160. doi: 10.1016/j.jpowsour.2011.05.036
38. [38]
  (38) Cheng, Q.; Tang, J.; Ma, J.; Zhang, H.; Shinya, N.; Qin, L. C.Carbon 2011, 49 (9), 2917. doi: 10.1016/j.carbon.2011.02.068
39. [39]
  (39) Yan, J.; Fan, Z.;Wei, T.; Qian,W.; Zhang, M.;Wei, F. Carbon2010, 48 (13), 3825. doi: 10.1016/j.carbon.2010.06.047
40. [40]
  (40) Zhu, Y.; Murali, S.; Stoller, M. D.; Ganesh, K. J.; Cai,W.;Ferreira, P. J.; Pirkle, A.;Wallace, R. M.; Cychosz, K. A.;Thommes, M.; Su, D.; Stach, E. A.; Ruoff, R. S. Science 2011,332 (6037), 1537. doi: 10.1126/science.1200770
41. [41]
  (41) Miller, J. R.; Outlaw, R. A.; Holloway, B. C. Science 2010, 329 (5999), 1637. doi: 10.1126/science.1194372
42. [42]
  (42) Le, L. T.; Ervin, M. H.; Qiu, H.; Fuchs, B. E.; Lee,W. Y.Electrochem. Commun. 2011, 13 (4), 355. doi: 10.1016/j.elecom.2011.01.023
43. [43]
  (43) Huang, X.; Yin, Z.;Wu, S.; Qi, X.; He, Q.; Zhang, Q.; Yan, Q.;Boey, F.; Zhang, H. Small 2011, 7 (14), 1876. doi: 10.1002/smll.201002009
44. [44]
  (44) Luo, D. C.; Zhang, G. X.; Liu, J. F.; Sun, X. M. J. Phys. Chem.C 2011, 115 (23), 11327. doi: 10.1021/jp110001y
45. [45]
  (45) Marcano, D. C.; Kosynkin, D. V.; Berlin, J. M.; Sinitskii, A.;Sun, Z.; Slesarev, A.; Alemany, L. B.; Lu,W.; Tour, J. M. ACSNano 2010, 4 (8), 4806. doi: 10.1021/nn1006368
46. [46]
  (46) Tang, N.; Tian, X.; Yang, C.; Pi, Z. Materials Research Bulletin2009, 44 (11), 2062. doi: 10.1016/j.materresbull.2009.07.012
47. [47]
  (47) Chen,W. F.; Yan, L. F.; Bangal, P. R. J. Phys. Chem. C 2010,114 (47), 19885. doi: 10.1021/jp107131v
48. [48]
  (48) Nesbitt, H.W.; Banerjee, D. American Mineralogist 1998, 83 (3-4), 305.
49. [49]
  (49) Gao, J.; Tong, X.; Li, X.; Miao, H.; Xu, J. J. Chem. Technol.Biotechnol. 2007, 82 (7), 620. doi: 10.1002/jctb.1717
50. [50]
  (50) Xia, H.;Wang, Y.; Lin, J.; Lu, L. Nanoscale Res. Lett. 2012, 7 (1), 33. doi: 10.1186/1556-276X-7-33
51. [51]
  (51) Di Fabio, A.; Mastra stino, A. G. M.; Soavi, F. J. Electrochem.Soc. 2001, 148, A845.
52. [52]
  (52) Tang, N.; Tian, X.; Yang, C.; Pi, Z. Mater. Res. Bull. 2009, 44 (11), 2062. doi: 10.1016/j.materresbull.2009.07.012
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
4. [4]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
5. [5]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
6. [6]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
8. [8]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
9. [9]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
10. [10]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
11. [11]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
12. [12]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
13. [13]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
14. [14]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
15. [15]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
16. [16]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
17. [17]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
18. [18]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
19. [19]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
20. [20]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023

Get Citation

PDF

XML

Metrics

PDF Downloads(934)
Abstract views(1381)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors

Metrics

通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K₂Mn₄O₈ Nanocomposites as Supercapacitors