Citation: LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou. Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K₂Mn₄O₈ Nanocomposites as Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1681-1690. doi: 10.3866/PKU.WHXB201305223 shu

Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K₂Mn₄O₈ Nanocomposites as Supercapacitors

1.
1 School of Material Science and Engineering, Tongji University, Shanghai 200092, P. R. China;
2 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 200092, P. R. China

Received Date: 27 February 2013
Available Online: 22 May 2013
Fund Project: 国家自然科学基金(51175162)资助项目 (51175162)

Nanocomposites of partially reduced graphene oxide ( )-K₂Mn₄O₈ were synthesized via a hydrothermal process at different temperatures and molar feed ratios of to KMnO₄. X-ray diffraction (XRD) analysis confirmed that both α-MnO₂ and a novel crystal phase of K₂Mn₄O₈ were obtained under the investigated hydrothermal conditions. X-ray photoelectron spectroscopy (XPS) revealed diverse changes of the oxygen-containing functional groups on the surface of depending on temperature and molar feed ratio. The microstructure of the composites was studied to help understand their electrochemical properties. A flaky structure of reduced graphene oxide (r ) covered by nanoparticles was observed by scanning electron microscope (SEM), which was considered to be favorable for charge transfer. The capacitive properties of the composites were compared using cyclic voltammograms and galvanostatic charge-discharge measurements. The specific capacitance of the optimal sample was calculated to be 251 F·g^-1 with an energy density of 32 Wh·kg^-1 and a power density of 18.2 kW·kg^-1 in 1 mol·L^-1 Na₂SO₄ electrolyte at a current density of 1 A·g^-1 between 0 and 1 V. Moreover, the capacitance retention ratio of this sample remained at 88% after 1000 cycles at a high current density of 5 A·g^-1.
- Supercapacitor,
- Reduced graphene oxide,
- Potassium manganese oxide,
- Manganese oxide,
- Composite,
- Capacitive behavior
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Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors

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Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K₂Mn₄O₈ Nanocomposites as Supercapacitors