Citation: KANG Ya-Rong, CHEN Fu-Yi. Synthesis and Application of Ag-Cu Bimetallic Dendrites[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1712-1718. doi: 10.3866/PKU.WHXB201305132 shu

Synthesis and Application of Ag-Cu Bimetallic Dendrites

KANG Ya-Rong ,
CHEN Fu-Yi

1.
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, P. R. China

Received Date: 14 March 2013
Available Online: 13 May 2013
Fund Project: 国家自然科学基金(51271148, 50971100) (51271148, 50971100) 凝固技术国家重点实验室自主研究课题(30-TP-2009) (30-TP-2009)航空科学基金(2012ZF53073)资助项目 (2012ZF53073)

We synthesized silver-copper (Ag-Cu) dendritic structures on Cu foil by electrodeposition and subsequent galvanic displacement reaction. The crystalline nature and morphology of the nanostructures were examined by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM), respectively. The morphology of the Cu precursor changed from rod to dendrite, and finally grew into foam as the overpotential was increased. When the Cu precursor was reacted with silver nitrate through galvanic displacement reaction, a foam-like precursor produced a denser, more uniform Ag-Cu dendrite. In addition, the concentration of silver nitrate solution had a considerable effect on the shape of the nanoparticles, with increasing concentration within a certain range promoting dendrite formation. The electrochemical properties of the Ag-Cu dendrite-modified electrode were characterized by linear sweep voltammetry and amperometric current-time curves. The reduction peak potential was about -0.25 V (vs a saturated calomel electrode (SCE)) in the electrolyte solution, which indicates that the as-synthesized Ag-Cu dendrites have favorable electroreduction activity towards hydrogen peroxide (H₂O₂). When an Ag-Cu dendrite was used as a sensor, the electrode exhibited a rapid response time of 3 s, a wide linear range of 0.1-12 mmol·L^-1 H₂O₂, and a remarkable sensitivity of 330.36 μA·(mmol·L^-1)^-1·cm^-2, which is particularly important to improve the accuracy of sensors.
- Electrodeposition,
- Silver-copper nanodendrite,
- Hydrogen peroxide,
- Electro-catalysis,
- Sensor
1. [1]
  
  (1) Hartley, F. R. Chemistry of Platinum Group Metals: Recent Developments, 1st ed.; Elsevier Science Ltd.: London, 1991;pp 106-120.
2. [2]
  (2) Wen, Z. L.; Yang, S. D.; Song, Q. J.; Hao, L.; Zhang, X. G. Acta Phys. -Chim. Sin. 2010, 26 (6), 1570. [温祝亮, 杨苏东, 宋启军, 郝亮, 张校刚. 物理化学学报, 2010, 26 (6), 1570.]doi: 10.3866/PKU.WHXB20100620
3. [3]
  (3) Ye, S. F.; Hu, X. M.; Ying, D.; Zhang, Y. Environmental Chemistry 2011, 30, 1711. [叶舒帆, 胡筱敏, 英滇, 张杨.环境化学, 2011, 30, 1711.]
4. [4]
  (4) Li,W. B.; ng, H. Acta Phys. -Chim. Sin. 2010, 26 (4), 885.[黎维彬, 龚浩. 物理化学学报, 2010, 26 (4), 885.]doi: 10.3866/PKU.WHXB20100436
5. [5]
  (5) Ming, C. B.; Ye, D. Q.; Yi, H.; Fu, M. L. China Environmental Science 2009, 29, 924. [明彩兵, 叶代启, 易慧, 付名利.中国环境科学, 2009, 29, 924.]
6. [6]
  (6) Jirkovský, J. S.; Panas, I.; Romani, S.; Ahlberg, E.; Schiffrin, D.J. J. Phys. Chem. Lett. 2012, 3, 315.
7. [7]
  (7) Hickman, A. J.; Sanford, M. S. Nature 2012, 484, 177.doi: 10.1038/nature11008
8. [8]
  (8) Sun, X. Z.; Lin, L. H.; Li, Z. C.; Zhang, Z. J.; Feng, J. Y. Mater. Lett. 2009, 63, 2306. doi: 10.1016/j.matlet.2009.07.058
9. [9]
  (9) Li, L. F.; Qiu, T.; Yang, J.; Feng, Y. B.; Zhang, Z. Z. Rare Metal Materials and Engineering 2010, 39, 902. [李良锋, 丘泰,杨建, 冯永宝, 张振忠. 稀有金属材料与工程, 2010, 39,902.]
10. [10]
  (10) Li, Z. Q.; Shen, H.; Chen, L. Chinese Journal of Materials Research 1994, 8, 392. [李宗全, 沈辉, 陈莉. 材料研究学报, 1994, 8, 392.]
11. [11]
  (11) Agrawal, V. V.; Mahalakshmi, P.; Kulkarni, G. U.; Rao, C. N. R.Langmuir 2006, 22, 1846. doi: 10.1021/la052595n
12. [12]
  (12) Zhang, C. M.; Zhang, C. L.; Zhang, J.W.; Zhang, Z. J. Acta Phys. -Chim. Sin. 2004, 20 (5), 554. [张晟卯, 张春丽, 张经纬, 张治军. 物理化学学报, 2004, 20 (5), 554.] doi: 10.3866/PKU.WHXB20040522
13. [13]
  (13) Hu, X. Y.;Wang, Z. Y.; Zhang, T. C.; Zeng, X. Y.; Xu,W.;Zhang, J. X.; Yan, J.; Zhang, J. P.; Zhang, L. D. Appl. Surf. Sci.2008, 254, 3845. doi: 10.1016/j.apsusc.2007.12.006
14. [14]
  (14) Bartlettet, P. N.; Birkin, P. R.;Wang, J. H.; Palmisano, F.;Benedetto, G. D. Anal. Chem. 1998, 70, 3685. doi: 10.1021/ac971088a
15. [15]
  (15) Wang, J.; Lin, Y. H.; Chen, L. Analyst 1993, 118, 277.doi: 10.1039/an9931800277
16. [16]
  (16) Demirci, U. B. J. Power Sources 2007, 172, 676. doi: 10.1016/j.jpowsour.2007.05.009
17. [17]
  (17) Zhao, B.; Liu, Z. R.; Liu, Z. l.; Liu, G. X.; Li, Z.;Wang, J. X.;Dong, X. T. Electrochem. Commun. 2009, 11, 1707.doi: 10.1016/j.elecom.2009.06.035
18. [18]
  (18) de Lara nzález, G. L.; Kahlert, H.; Scholz, F. Electrochim. Acta 2007, 52 (5), 1968. doi: 10.1016/j.electacta.2006.08.006
19. [19]
  (19) Rodríguez-López, J. N.; Lowe, D. J.; Hernández-Ruiz, J.; Hiner,A. N. P.; García-Cánovas, F.; Thorneley, R. N. F. J. Am. Chem. Soc. 2001, 123, 11838. doi: 10.1021/ja011853+
20. [20]
  (20) Zhun, L. Q. Theory and Technology of the Functional Film Layer Electrodeposition; University of Aeronautics andAstronautics of Beijing Press: Beijing, 2005; pp 24-34.[朱立群. 功能膜层的电沉积理论和技术. 北京: 北京航空航天大学出版社, 2005: 24-34.]
21. [21]
  (21) Liu, R.; Sen, A. Chem. Mater. 2011, 24 (1), 48. doi: 10.1021/cm2017714
22. [22]
  (22) Qin, X.; Miao, Z. Y.; Fang, Y. X.; Zhang, D.; Ma, J.; Zhang, L.;Chen, Q.; Shao, X. G. Langmuir 2012, 28, 5218. doi: 10.1021/la300311v
23. [23]
  (23) Qiu, R.; Cha, H. G.; Noh, H. B.; Shim, Y. B.; Zhang, X. L.;Qiao, R.; Zhang, D.; Kim, Y., II; Pal, U.; Kang, Y. S. J. Phys. Chem. C 2009, 113, 15891. doi: 10.1021/jp904222b
24. [24]
  (24) Wei, G. D.; Nan, C.W.; Deng, Y.; Lin, Y. H. Chem. Mater. 2003,15 (23), 4436. doi: 10.1021/cm034628v
25. [25]
  (25) Gu, M.; Yang, F. Z.; Huang, L.; Yao, S. B.; Zhou, S. M. Acta Phys. -Chim. Sin. 2002, 18 (11), 973. [辜敏, 杨防祖,黄令, 姚士冰, 周绍民. 物理化学学报, 2002, 18 (11), 973.]doi: 10.3866/PKU.WHXB20021103
26. [26]
  (26) Chen, X.; Cui, C. H.; Guo, Z.; Liu, J. H.; Huang, X. J.; Yu, S. H.Small 2011, 7, 858. doi: 10.1002/smll.201002331
27. [27]
  (27) Welch, C. M.; Banks C. E.; Simm, A. O.; Compton, R. G. Anal. Bioanal. Chem. 2005, 382, 12. doi: 10.1007/s00216-005-3205-5
28. [28]
  (28) Wu, S.; Zhao, H. T.; Ju, H. X.; Shi, C. G.; Zhao, J.W.Electrochem. Commun. 2006, 8, 1197. doi: 10.1016/j.elecom.2006.05.013
29. [29]
  (29) Liu, J.; Chen, F. Y.; Zhang, J. Y.; Fan, L. H.; Zhang, J. S.Chinese Journal of Materials Research 2012, 26, 49. [刘婧,陈福义, 张吉烨, 樊丽红, 张金生. 材料研究学报, 2012, 26,49.]
30. [30]
  (30) Zhao, X. H.; Chen, F. Y.; Liu, J. Precious Metals 2012, 33 (1),21. [赵秀华, 陈福义, 刘婧. 贵金属, 2012, 33 (1), 21.]
31. [31]
  (31) Huang, J. S.;Wang, D.W.; Hou, H. Q.; You, T. Y. Adv. Funct. Mater. 2008, 18, 441. doi: 10.1002/adfm.200700729
32. [32]
  (32) Shi, L.; Liu, X. Q.; Niu,W. X.; Li, H. J.; Han, S.; Chen, J.; Xu,G. G. Biosens. Bioelectron. 2009, 24, 1159. doi: 10.1016/j.bios.2008.07.001
33. [33]
  (33) Qin, X.;Wang, H. C.;Wang, X. S.; Miao, Z. Y.; Fang, Y. X.;Chen, Q.; Shao, X. G. Electrochim. Acta 2011, 56 (9), 3170.doi: 10.1016/j.electacta.2011.01.058
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