Citation: LIN Xue, YU Li-Li, Yan Li-Na, GUAN Qing-Feng, Yan Yong-Sheng, ZHAO Han. Controllable Synthesis and Photocatalytic Activity of Spherical, Flowerlike and Threadlike Bismuth Vanadates[J]. Acta Physico-Chimica Sinica, ;2013, 29(08): 1771-1777. doi: 10.3866/PKU.WHXB201305131 shu

Controllable Synthesis and Photocatalytic Activity of Spherical, Flowerlike and Threadlike Bismuth Vanadates

1.
1 College of Chemistry, Key Laboratory of Preparation and Application of Environmentally Friendly Materials of the Ministry of Education, Jilin Normal University, Siping 136000, Jilin Province, P. R. China;
2 School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, P. R. China;
3 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, P. R. China

Received Date: 29 January 2013
Available Online: 13 May 2013
Fund Project: 环境友好材料制备与应用教育部重点实验室项目和吉林省科技发展计划项目(20130522071JH)资助 (20130522071JH)

Spherical, flowerlike, and threadlike bismuth vanadates (BiVO₄) were synthesized via a controllable hydrothermal method without using any surfactant or template. The optical and photocatalytic properties of the BiVO₄ samples were investigated. The phase structures of the BiVO₄ samples were observed by X-ray diffraction (XRD), which indicated that the as-prepared samples possessed monoclinic cells. Transmission electron microscope (TEM) observations showed that BiVO₄ crystals with different morphologies were fabricated simply by manipulating the parameters of the hydrothermal reaction. On the basis of the structural analysis of samples obtained under different conditions, a possible mechanism for the formation of these distinct morphologies was proposed. UV-visible diffuse reflectance spectra (UV-Vis DRS) of the samples revealed that the band gaps of the BiVO₄ photocatalysts were about 2.19-2.33 eV. The as-prepared BiVO₄ photocatalysts exhibited higher photocatalytic activities toward the degradation of rhodamine B (RhB) under visible light irradiation (λ>420 nm) than commercial P25 TiO₂ and traditional N-doped TiO₂ (N-TiO₂). Spherical BiVO₄ showed the highest photocatalytic activity of the samples, decolorizing up to 100% of RhB upon visible light irradiation for 180 min. The reason for the different photocatalytic activities of the BiVO₄ samples fabricated at different pH was systematically studied by considering their structure and morphology.
- BiVO₄,
- Microsphere,
- Microflower,
- Microwire,
- Controllable synthesis,
- Photocatalytic degradation
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