Citation: CHENG Wei-Na, HU Xin-Gen, SHAO Shuang. Macrocyclic Hydrophobic Effect:Enthalpic Pairwise Interactions of Crown Ethers in Mixtures of DMF and Water[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2114-2122. doi: 10.3866/PKU.WHXB201305103 shu

Macrocyclic Hydrophobic Effect:Enthalpic Pairwise Interactions of Crown Ethers in Mixtures of DMF and Water

  • Received Date: 26 March 2013
    Available Online: 10 May 2013

    Fund Project: 国家自然科学基金(21073132)资助项目 (21073132)

  • The dilution enthalpies of four crown ethers, namely 12-crown-4, 15-crown-5, 18-crown-6, and 4,13-diaza-18-crown-6, in pure water and mixtures of N,N-dimethylformamide (DMF) and water of various mass fraction (w=0-0.3) were determined at 298.15 K by isothermal titration microcalorimetry. The corresponding enthalpic pairwise interaction coefficients (hxx) were evaluated according to the McMillan-Mayer theory. Values of hxx were all positive and large, which indicates that hydrophobic components predominate in crown-crown self-interactions. There are two main kinds of mechanisms: (1) When hydrophobic-hydrophobic interactions occur, cosphere overlapping reduces the formation of water structure, which makes a positive contribution to hxx. (2) Hydrophobic-hydrophilic interactions increasingly destroy the water structure because of cosphere overlapping, which also makes a positive contribution to hxx. In addition, hxx values of the four crown ethers follow the order: hxx(18-crown-6)>hxx(4,13-diaza-18-crown-6)≈ hxx(15-crown-5) >hxx(12-crown-4), which indicates that the larger the size of the crown ether ring, the stronger the hydrophobic-hydrophobic interaction; namely, that crown ethers are subject to macrocyclic hydrophobic effects.

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