Citation: ZHU Qi-Rong, LI Hui-Qin, LI Ning, CHAI Jing, GAO Run-Gang, LIANG Qi. Nanotribological and Wear Properties of Graphene[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1582-1587. doi: 10.3866/PKU.WHXB201305031 shu

Nanotribological and Wear Properties of Graphene

ZHU Qi-Rong ¹ ,
LI Hui-Qin ¹ ,
LI Ning ¹ ,
CHAI Jing ² ,
GAO Run-Gang ² ,
LIANG Qi ^1,

1.
1 Instrumental Analysis Center, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 Research Institute of Micro/Nano Science and Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 29 January 2013
Available Online: 3 May 2013
Fund Project: 国家自然科学基金(10974134)资助项目 (10974134)

We prepared few-layer graphene samples by liquid-phase exfoliation in ethanol. By controlling the solvent temperature, sonication time and power, and centrifugation speed and time, we fabricated several-layer graphene from highly oriented pyrolytic graphite (HOPG). The obtained supernatant was added dropwise onto freshly cleaved mica surfaces. Nanotribological study of the samples under high vacuum by atomic force microscope (AFM) showed that frictional force decreased as the number of monolayers (ML) of graphene increased, and their frictional coefficient remained constant when the sample was thicker than about 4 ML. When the coverage reached 7 ML, the frictional coefficient was close to zero. In wear experiments, 2-ML graphene exhibited better wear resistance than the 4-ML sample and had no dependence on directional friction. We also measured the adhesion force of samples containing different numbers of layers of graphene and the mica surface, and found that substrate adhesion is not the main reason for the wear resistance properties of 2-ML graphene. Compared with single-layer graphene, the low friction coefficient of few-layer graphene makes it promising for application in areas such as data storage devices, nanoelectromechanical systems, and anti-wear coatings.
- Highly oriented pyrolytic graphite,
- Graphene,
- Nanotribology,
- Atomic force microscope,
- Wear
1. [1]
  
  (1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A.Science 2004, 306, 666. doi: 10.1126/science.1102896
2. [2]
  (2) Castro Neto, A. H.; Guinea, F.; Peres, N. M. R.; Novoselov, K.S.; Geim, A. K. Rev. Mod. Phys. 2009, 81, 109. doi: 10.1103/RevModPhys.81.109
3. [3]
  (3) Balandin, A. A.; Ghosh, S.; Bao,W. Z.; Calizo, I.; Teweldebrhan,D.; Miao, F.; Lau, C. N. Nano Lett. 2008, 8 (3), 902.doi: 10.1021/nl0731872
4. [4]
  (4) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.doi: 10.1038/nmat1849
5. [5]
  (5) Geim, A. K. Science 2009, 324, 1530. doi: 10.1126/science.1158877
6. [6]
  (6) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Katsnelson, M. I.; Gri rieva, I. V.; Dubonos, S. V.; Firsov, A.A. Nature 2005, 438, 197. doi: 10.1038/nature04233
7. [7]
  (7) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80 (6), 1339. doi: 10.1021/ja01539a017
8. [8]
  (8) Hamilton, C. E.; Lomeda, J. R.; Sun, Z.; Tour, J. M.; Barron, A.R. Nano Lett. 2009, 9 (10), 3460. doi: 10.1021/nl9016623
9. [9]
  (9) Renia, A.; Jia, X. T.; Ho, J.; Nezich, D.; Son, H.; Bulovic, V.;Dresselhaus, M. S.; Kong, J. Nano Lett. 2009, 9 (1), 30.doi: 10.1021/nl801827v
10. [10]
  (10) Obraztsov, A. N. Nat. Nanotechnol. 2009, 4, 212. doi: 10.1038/nnano.2009.67
11. [11]
  (11) Berger, C.; Song, Z.; Li, X.;Wu, X.; Brown, N.; Naud, C.;Mayou, D.; Li, T.; Hass, J.; Marchenkov, A. N.; Conrad, E. H.;First, P. N.; de Heer,W. A. Science 2006, 312, 1191.doi: 10.1126/science.1125925
12. [12]
  (12) Donnet, C., Erdemir, A. Surf. Coat. Tech. 2004, 180-181, 76.
13. [13]
  (13) Lee, C.; Li, Q.; Kalb,W.; Liu, X. Z.; Berger, H.; Carpick, R.W.;Hone, J. Science 2010, 328, 76. doi: 10.1126/science.1184167
14. [14]
  (14) Filleter, T.; McChesney, J. L.; Bostwick, A.; Rotenberg, E.;Emtsev, K. V.; Seyller, T.; Horn, K.; Bennewitz, R. Phys. Rev. Lett. 2009, 102, 086102. doi: 10.1103/PhysRevLett.102.086102
15. [15]
  (15) Kim, K. S.; Lee, H. J.; Lee, C.; Lee, S. K.; Jang, H.; Ahn, J. H.;Kim, J. H.; Lee, H. J. ACS Nano 2011, 5, 5107. doi: 10.1021/nn2011865
16. [16]
  (16) Shin, Y. J.; Stromberg, R.; Nay, R.; Huang, H.;Wee, A. T. S.;Yang, H.; Bhatia, C. S. Carbon 2011, 49, 4070. doi: 10.1016/j.carbon.2011.05.046
17. [17]
  (17) Lin, L. Y.; Kim, D. E.; Kim,W. K.; Jun, S. C. Surf. Coat. Tech.2011, 205, 4864. doi: 10.1016/j.surfcoat.2011.04.092
18. [18]
  (18) Sandoz-Rosado, E. J.; Tertuliano, O. A.; Terrell, E. J. Carbon2012, 50, 4078. doi: 10.1016/j.carbon.2012.04.055
19. [19]
  (19) Marchetto, D.; Held, C.; Hausen, F.;Wählisch, F.; Dienwiebel,M.; Bennewitz, R. Tribol. Lett. 2012, 48, 77. doi: 10.1007/s11249-012-9945-4
20. [20]
  (20) Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri,M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth,S.; Geim, A. K. Phys. Rev. Lett. 2006, 97, 187401. doi: 10.1103/PhysRevLett.97.187401
21. [21]
  (21) Lui, C. H.; Liu, L.; Mak, K. F.; Flynn, G.W.; Heinz, T. F.Nature 2009, 462, 339. doi: 10.1038/nature08569
22. [22]
  (22) Li, Q. Y.; Lee, C. G.; Carpick, R.W.; Hone, J. Phys. Status Solidi B 2010, 247, 2909. doi: 10.1002/pssb.v247.11/12
23. [23]
  (23) Du, X. Q.; Li, H. Q.; Zhu, Q. R.; Zou, Z. Q.; Liang, Q. Acta Phys. -Chim. Sin. 2011, 27 (10), 2457. [杜晓青, 李慧琴,朱齐荣, 邹志强, 梁齐. 物理化学学报, 2011, 27 (10), 2457.]doi: 10.3866/PKU.WHXB20111010
24. [24]
  (24) Liang, Q.; Li, H. N.; Xu, Y. B.; Xiao, X. D. J. Phys. Chem. B2006, 110, 403. doi: 10.1021/jp054939o
25. [25]
  (25) Shin, Y. J.;Wang, Y.; Huang, H.; Kalon, G.;Wee, A. T. S.; Shen,Z. X.; Bhatia, C. S.; Yang, H. Langmuir 2010, 26 (6), 3798.doi: 10.1021/la100231u
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