Citation: QIAN Jia-Sheng, LIU Ming-Xian, GAN Li-Hua, LÜ Yao-Kang, CHEN Ling-Yan, YE Rui-Jie, CHEN Long-Wu. Synthesis and Electrochemical Performance of Microporous Carbon Using a Zinc(II)-Organic Coordination Polymer[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1494-1500. doi: 10.3866/PKU.WHXB201304271 shu

Synthesis and Electrochemical Performance of Microporous Carbon Using a Zinc(II)-Organic Coordination Polymer

1.
Department of Chemistry, Tongji University, Shanghai 200092, P. R. China

Received Date: 17 January 2013
Available Online: 27 April 2013
Fund Project: 国家自然科学基金(21207099, 21273162) (21207099, 21273162) 上海市科学技术委员会(11nm0501000, 12ZR1451100) (11nm0501000, 12ZR1451100) 上海市教委重点学科建设项目(J50102) (J50102)中央高校基本科研业务费(2011KJ023)资助 (2011KJ023)

Microporous carbon was prepared using a novel procedure based on a zinc(II)-organic coordination polymer. The polymer was prepared through the coordination interaction of zinc ions with tartaric acid, and then it was introduced into the open networks of resorcinol/formaldehyde (R/F) resol using hydrogen-bonding interactions. The R/F resol and zinc-organic coordination compound system copolymerized to produce an R/F and zinc-organic coordination copolymer. The copolymer was then heat-treated at 950℃ to decompose and evaporate zinc to fabricate microporous carbon materials. The carbon materials possessed relatively regular large micropores, with a specific surface area of up to 1260 m²·g^-1 and a total pore volume of 0.63 cm³·g^-1. The resultant microporous carbon materials were used as supercapacitor electrodes, exhibiting an equivalent series resistance of 0.46 Ω, and ideal capacitive behavior with a rectangular shape in cyclic voltammograms. Galvanostatic charge/discharge measurements of the carbon materials gave a specific capacitance of 196 F·g^-1 at a current density of 1 A· g^-1 and 137 F·g^-1 at a large current density of 10 A·g^-1. A high retention of 98% was measured for the long-term cycling stability (~1000 cycles) of the mesoporous carbon. Overall, the microporous carbon materials exhibited very od electrochemical performance. This study highlights the potential of well-designed microporous carbon materials as electrodes for diverse supercapacitor applications.
- Microporous carbon,
- Synthesis,
- Electrochemical performance,
- Zinc(II)-organic coordination polymer,
- Hydrogen-bonding interaction,
- Electrode material
1. [1]
  
  (1) Winter, M.; Brodd, R. J. Chem. Rev. 2004, 104, 4245. doi: 10.1021/cr020730k
2. [2]
  (2) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; KluwerAcademic Plenum Publishers: New York, 1999; pp 1-200.
3. [3]
  (3) Rolison, D. R. Science 2003, 299, 1698. doi: 10.1126/science.1082332
4. [4]
  (4) Miller, J. R.; Simon, P. Science 2008, 321, 651. doi: 10.1126/science.1158736
5. [5]
  (5) Wang, G.; Zhang, L.; Zhang, J. Chem. Soc. Rev. 2012, 41, 797.doi: 10.1039/c1cs15060j
6. [6]
  (6) Simon, P.; tsi, Y. Nat. Mater. 2008, 7, 845. doi: 10.1038/nmat2297
7. [7]
  (7) Guo, P.; Gu, Y.; Lei, Z.; Cui, Y.; Zhao, X. S. Microporous Mesoporous Mat. 2012, 156, 176. doi: 10.1016/j.micromeso.2012.02.043
8. [8]
  (8) Kyotani, T.; Ma, Z.; Tomita, A. Carbon 2003, 41, 1451. doi: 10.1016/S0008-6223(03)00090-3
9. [9]
  (9) Wang, D.; Li, F.; Liu, M.; Lu, G.; Cheng, H. Angew. Chem. Int. Edit. 2008, 47, 373.
10. [10]
  (10) Mahata, P.; Madras, G.; Natarajan, S. J. Phys. Chem. B 2006,110, 13759.
11. [11]
  (11) Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.;Wachter, J.;O'Keeffe, M.; Yaghi, O. M. Science 2002, 295, 469. doi: 10.1126/science.1067208
12. [12]
  (12) Farrusseng, D.; Aguado, S.; Pinel, C. Angew. Chem. Int. Edit.2009, 48, 7502. doi: 10.1002/anie.v48:41
13. [13]
  (13) Robson, R. J. Chem. Soc., Dalton Trans. 2000, 3735.
14. [14]
  (14) Jiang, H.; Liu, B.; Lan, Y.; Kuratani, K.; Akita, T.; Shioyama,H.; Zong, F.; Xu, Q. J. Am. Chem. Soc. 2011, 133, 11854. doi: 10.1021/ja203184k
15. [15]
  (15) Liu, B.; Shioyama, H.; Akita, T.; Xu, Q. J. Am. Chem. Soc.2008, 130, 5390. doi: 10.1021/ja7106146
16. [16]
  (16) Kajdos, A.; Kvit, A.; Jones, F.; Jagiello, J.; Yushin, G. J. Am. Chem. Soc. 2010, 132, 3252. doi: 10.1021/ja910307x
17. [17]
  (17) Zhao, C.;Wang,W.; Yu, Z.; Zhang, H.;Wang, A.; Yang, Y.J. Mater. Chem. 2010, 20, 976. doi: 10.1039/b911913b
18. [18]
  (18) Li, X.; Rong, J.;Wei, B. ACS Nano 2010, 4, 6039. doi: 10.1021/nn101595y
19. [19]
  (19) Lin, R.; Taberna, P. L.; Chmiola, L.; Guay, D.; tsi, Y.;Simon, P. J. Electrochem. Soc. 2009, 156, A7.
20. [20]
  (20) Wu, Q.; He, K.; Mi, H.; Zhang, X. Mater. Chem. Phys. 2007,101, 367. doi: 10.1016/j.matchemphys.2006.06.013
21. [21]
  (21) Cheng, Q.; Tang, J.; Ma, J.; Zhang, H.; Shinya, N.; Qin, L. Phys. Chem. Chem. Phys. 2011, 13, 17615. doi: 10.1039/c1cp21910c
22. [22]
  (22) Xie, K.; Qin, X.;Wang, X.;Wang, Y.; Tao, H.;Wu, Q.; Yang, L.;Hu, Z. Adv. Mater. 2012, 24, 347. doi: 10.1002/adma.201103872
23. [23]
  (23) Tamon, H.; Ishizaka, H.; Araki, T.; Okazaki, M. Carbon 1998,36, 1257. doi: 10.1016/S0008-6223(97)00202-9
24. [24]
  (24) Tseng, R. L.; Tseng, S. K. J. Colloid Interface Sci. 2005, 287,428. doi: 10.1016/j.jcis.2005.02.033
25. [25]
  (25) Kim, K.; Park, S. Electrochim. Acta 2012, 78, 147. doi: 10.1016/j.electacta.2012.05.116
26. [26]
  (26) Wu, X.; Hong, X.; Nan, J.; Luo, Z.; Zhang, Q.; Li, L.; Chen, H.;Hui, K. S. Microporous Mesoporous Mat. 2012, 160, 25. doi: 10.1016/j.micromeso.2012.04.013
27. [27]
  (27) Ji, Q. Q.; Guo, P. Z.; Zhao, X. S. Acta Phys. -Chim. Sin. 2010,26, 1254. [季倩倩, 郭培志, 赵修松. 物理化学学报, 2010,26, 1254.] doi: 10.3866/PKU.WHXB20100330
28. [28]
  (28) Pell,W. G.; Conway, B. E. J. Power Sources 1996, 63, 255. doi: 10.1016/S0378-7753(96)02525-6
29. [29]
  (29) Cao, G. F.; Liao, Y.; Zhang, X. H.; Chen, J. H. Acta Phys. -Chim. Sin. 2011, 27, 1679. [曹国飞, 廖奕, 张小华,陈金华. 物理化学学报, 2011, 27, 1679.] doi: 10.3866/PKU.WHXB20110623
30. [30]
  (30) Liu, C. L.;Wen, Y. H.; Cheng, J.; Guo, Q. G.; Cao, G. P.; Liu,L.; Yang, Y. S. Acta Phys. -Chim. Sin. 2005, 21, 786. [刘春玲,文越华, 程杰, 郭全贵, 曹高萍, 刘朗, 杨裕生. 物理化学学报, 2005, 21, 786.] doi: 10.3866/PKU.WHXB20050717
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