Citation: XIE Dan-Hua, ZHAO Jian-Xi, LIU Lin, YOU Yi, WEI Xi-Lian. A Highly Viscoelastic Anionic Wormlike Micellar System[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1534-1540. doi: 10.3866/PKU.WHXB201304252 shu

A Highly Viscoelastic Anionic Wormlike Micellar System

XIE Dan-Hua ¹ ,
ZHAO Jian-Xi ^1, ,
LIU Lin ¹ ,
YOU Yi ¹ ,
WEI Xi-Lian ²

1.
1 Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350108, P. R. China;
2 Department of Chemistry, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong, 252059, P. R. China

Received Date: 4 February 2013
Available Online: 25 April 2013
Fund Project: 国家自然科学基金(20873024, 21273040)资助项目 (20873024, 21273040)

The rheological behavior of carboxylate gemini surfactant O,O'-bis(sodium 2- tetradecylcarboxylate)-p-dibenzenediol (referred to as C₁₄Φ₂C₁₄) with a concentration of 140 mmol·L^-1 in aqueous solution in the presence of 100 mmol·L^-1 NaBr was investigated by frequency sweep and steady rate sweep measurements. The solution showed the characteristics of a Maxwell fluid with a single stress relaxation time at low shear frequencies. Analysis by the living polymer model indicated that C₁₄Φ₂C₁₄ formed long (3.6-6.8 μm) wormlike micelles at 25℃, which were observed by cryo-transmission electron microscopy (cryo-TEM). The micelles were entangled with each other, resulting in a very viscous solution (the zero-shear viscosity was as high as 1.10×10⁴ Pa·s) that looked like a gel. On raising the temperature to 70℃, the relative viscosity was still as high as 1.8×10⁴, which is very rare for anionic wormlike micelle systems. The flow activation energy (E_a) was estimated to be (141±5) kJ·mol^-1. The size distribution of C₁₄Φ₂C₁₄ was determined by dynamic light scattering. Large aggregates with a size of ~100 nm were observed at low concentrations of 5-10 mmol·L^-1. These large aggregates readily transformed into rodlike and then wormlike micelles as the surfactant concentration increased.
- Carboxylate gemini surfactant,
- p-Dibenzenediol spacer,
- Wormlike micelle,
- High viscoelasticity,
- Temperature effect,
- Micelle formation mechanism
1. [1]
  
  (1) Dreiss, C. A. Soft Matter 2007, 3, 956. and references therein.doi: 10.1039/b705775j
2. [2]
  (2) Yang, J. Curr. Opin. Colloid Interface Sci. 2002, 7, 276. andreferences therein. doi: 10.1016/S1359-0294(02)00071-7
3. [3]
  (3) Maitland, G. C. Curr. Opin. Colloid Interface Sci. 2000, 5, 301.doi: 10.1016/S1359-0294(00)00069-8
4. [4]
  (4) Magid, L. J.; Li, Z.; Butler, P. D. Langmuir 2000, 16, 10028.doi: 10.1021/la0006216
5. [5]
  (5) Hassan, P. A.; Raghavan, S. R.; Kaler, E.W. Langmuir 2002,18, 2543. doi: 10.1021/la011435i
6. [6]
  (6) Arleth, L.; Bergstrom, M.; Pedersen, J. S. Langmuir 2002, 18,5343. doi: 10.1021/la015693r
7. [7]
  (7) Nakamura, K.; Shikata, T. Langmuir 2006, 22, 9853. doi: 10.1021/la061031w
8. [8]
  (8) Acharya, D. P.; Sato, T.; Kaneko, M.; Singh, Y.; Kunieda, H.J. Phys. Chem. B 2006, 110, 754. doi: 10.1021/jp054631x
9. [9]
  (9) Lu, T.; Xia, L. G.;Wang, X. D.;Wang, A. Q.; Zhang, T.Langmuir 2011, 27, 9815. doi: 10.1021/la2018709
10. [10]
  (10) Mu, J. H.; Li, G. Z. Chem. Phys. Lett. 2001, 345, 100. doi: 10.1016/S0009-2614(01)00799-0
11. [11]
  (11) Mu, J. H.; Li, G. Z. Colloid Polym. Sci. 2001, 279, 872. doi: 10.1007/s003960100508
12. [12]
  (12) Mu, J. H.; Li, G. Z.; Jia, X. L.;Wang, H. X.; Zhang, G. Y.J. Phys. Chem. B 2002, 106, 11685. doi: 10.1021/jp014096a
13. [13]
  (13) Mu, J. H.; Li, G. Z.;Wang, Z.W. Rheol. Acta 2002, 41, 493.doi: 10.1007/s00397-002-0246-y
14. [14]
  (14) Mu, J. H.; Li, G. Z.;Wang, Z.W.; Zheng, L. Q.; Liao, G. Z.;Huang, L. J. Disper. Sci. Technol. 2001, 22, 421. doi: 10.1081/DIS-100107851
15. [15]
  (15) Acharya, D. P.; Kunieda, H.; Shiba, Y.; Aratani, K. J. Phys. Chem. B 2004, 108, 1790.
16. [16]
  (16) Song, B. L.; Hu, Y. F.; Zhao, J. X. J. Colloid Interface Sci. 2009,333, 820. doi: 10.1016/j.jcis.2009.02.030
17. [17]
  (17) Song, B. L.; Hu, Y. F.; Song, Y. M.; Zhao, J. X. J. Colloid Interface Sci. 2010, 341, 94.
18. [18]
  (18) Israelachvili, J. N.; Mitchell, D. J.; Ninham, B.W. Journal of the Chemical Society-Faraday Transactions II 1976, 72, 1525.doi: 10.1039/f29767201525
19. [19]
  (19) Xie, D. H.; Zhao, J. X. Langmuir 2013, 29, 545.
20. [20]
  (20) Granek, R.; Cates, M. E. J. Chem. Phys. 1992, 96, 4758. doi: 10.1063/1.462787
21. [21]
  (21) Oda, R.; Narayanan, J.; Hassan, P. A.; Manohar, C.; Salkar, R.A.; Kern, F.; Candau, S. J. Langmuir 1998, 14, 4364. doi: 10.1021/la971369d
22. [22]
  (22) Raghavan, S. R.; Kaler, E.W. Langmuir 2001, 17, 300. doi: 10.1021/la0007933
23. [23]
  (23) Khatory, A.; Lequeux, F.; Kern, F.; Candau, S. J. Langmuir1993, 9, 1456. doi: 10.1021/la00030a005
24. [24]
  (24) Shrestha, R. G.; Shrestha, L. K.; Aramaki, K. J. Colloid Interface Sci. 2007, 311, 276. doi: 10.1016/j.jcis.2007.02.050
25. [25]
  (25) Candau, S. J.; Hirsch, E.; Zana, R.; Delsanti, M. Langmuir1989, 5, 1225. doi: 10.1021/la00089a018
26. [26]
  (26) Fischer, P.; Rehage, H. Langmuir 1997, 13, 7012. doi: 10.1021/la970571d
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