Citation: LI Jing, ZHANG Mei-Yi, PAN Gang, CHEN Hao. Influence of Adsorption Mode on Metastable-Equilibrium Adsorption of As(V) on TiO₂ Particles[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1541-1549. doi: 10.3866/PKU.WHXB201304242 shu

Influence of Adsorption Mode on Metastable-Equilibrium Adsorption of As(V) on TiO₂ Particles

1.
Research Centre for Eco-Environmental Sciences, Chinese academy of sciences, Beijing 100085, P. R. China

Received Date: 21 January 2013
Available Online: 24 April 2013
Fund Project: 国家自然科学基金(21007083, 21277161, 20537020)资助项目 (21007083, 21277161, 20537020)

Column and batch adsorptions of As(V) on TiO₂ particles were conducted to investigate the influence of adsorption mode on metastable-equilibrium adsorption. Under the same thermodynamic conditions, a fixed amount of As(V) was added to both column and batch adsorption systems. Batch adsorption achieved equilibrium more quickly than column adsorption, and the equilibrated adsorption capacity of 0.42 mg·g^-1 for the batch adsorption system was considerably greater than 0.25 mg·g^-1 determined for the column adsorption system. Moreover, the adsorption irreversibility of the batch adsorption system was weaker than that of the column adsorption system. This indicated that the change of adsorption reaction mode (i.e., kinetic processes) could result in different metastable-equilibrium adsorption states under the same thermodynamic conditions. The discrepancy of adsorption behavior between column and batch adsorption systems should be caused by their different liquid film diffusion coefficients and total mass transfer coefficients, as well as different microscopic metastable-equilibrium adsorption states.
- Adsorption mode,
- Column adsorption,
- Batch adsorption,
- Adsorption irreversibility,
- Initial concentration effect
1. [1]
  
  (1) Yuan, T.; Luo, Q. F. Environ. Sci. 2001, 22, 25. [袁涛, 罗启芳. 环境科学, 2001, 22, 25.]
2. [2]
  (2) Tang,W. S.; Li, Q.; Gao, S. A.; Shang, J. K. J. Hazard. Mater.2011, 192, 131.
3. [3]
  (3) Kim, M. S.; Chung, J. G. J. Colloid Interface Sci. 2001, 233,31. doi: 10.1006/jcis.2000.7225
4. [4]
  (4) Baker, H. M.; Massadeh, A. M.; Younes, H. A. Environ. Monit. Assess. 2008, 157, 319.
5. [5]
  (5) Gupta, V. K.; Gupta, M.; Sharma, S. Water Res. 2001, 35, 1125.doi: 10.1016/S0043-1354(00)00389-4
6. [6]
  (6) Westerhoff, P.; Highfield, D.; Badruzzaman, M.; Yoon, Y. J.Environ. Eng.-ASCE 2005, 131, 262. doi: 10.1061/(ASCE)0733-9372(2005)131:2(262)
7. [7]
  (7) Nagy, M. Langmuir 1994, 10, 563. doi: 10.1021/la00014a037
8. [8]
  (8) Meszaros, R.; Nagy, M.; Varga, I.; Laszlo, K. Langmuir 1999,15, 1307. doi: 10.1021/la980849h
9. [9]
  (9) Zhang, M. Y. Study on Initial Concentration Effect of ArsenateAdsorption on TiO2 Surfaces. Ph. D. Dissertation, ResearchCentre for Eco-Environmental Sciences, Chinese Academy ofSciences, Beijing, 2009. [张美一. As(V)在TiO2 颗粒上吸附的初始浓度效应研究[D]. 北京: 中国科学院生态环境研究中心, 2009.]
10. [10]
  (10) Pan, G.; Liss, P. S. J. Colloid Interface Sci. 1998, 201, 77. doi: 10.1006/jcis.1998.5397
11. [11]
  (11) Ma, Z. C.; Pan, G.;Wei, Y.; Chen, H. Chem. J. Chin. Univ.2005, 26, 476. [马子川, 潘纲, 魏雨, 陈灏. 高等学校化学学报, 2005, 26, 476.]
12. [12]
  (12) Pan, G. Acta Sci. Circum. 2003, 23, 156. [潘纲. 环境科学学报, 2003, 23, 156]
13. [13]
  (13) Li, J.; Chen, H.; Pan, G.; Gao, M. Y. Acta Sci. Circum. 2006, 26,1606. [李晋, 陈灏, 潘纲, 高美媛. 环境科学学报,2006, 26, 1606.]
14. [14]
  (14) He, G. Z.; Pan, G.; Zhang, M. Y.;Wu, Z. Y. J. Phys. Chem. C2009, 113, 17076. doi: 10.1021/jp9044918
15. [15]
  (15) Pan, G.; He, G. Z. Physics 2009, 38, 496. [潘纲, 何广智.物理, 2009, 38, 496.]
16. [16]
  (16) el, J.; Kadirvelu, K.; Raja pal, C.; Garg, V. K. J. Hazard. Mater. 2005, 125, 211. doi: 10.1016/j.jhazmat.2005.05.032
17. [17]
  (17) Miller, S. M.; Spaulding, M. L.; Zimmerman, J. B. Water Res.2011, 45, 5745. doi: 10.1016/j.watres.2011.08.040
18. [18]
  (18) Chadwick, M. D.; odwin, J.W.; Lawson, E. J.; Mills, P. D.A.; Vincent, B. Colloids Surf. A: Physicochem. Eng. Aspects2002, 203, 229. doi: 10.1016/S0927-7757(01)01101-3
19. [19]
  (19) Gulledge, J. H.; O'Connor, J. T. J. Am. Water Works Ass. 1973,8, 548.
20. [20]
  (20) Morterra, C. J. Chem. Soc. Faraday Trans. I 1988, 84, 1617.doi: 10.1039/f19888401617
21. [21]
  (21) Awual, M. R.; Urata, S.; Jyo, A.; Tamada, M.; Katakai, A. Water Res. 2008, 42, 689. doi: 10.1016/j.watres.2007.08.020
22. [22]
  (22) Vinodhini, V.; Das, N. Desalination 2010, 264, 9. doi: 10.1016/j.desal.2010.06.073
23. [23]
  (23) Han, R. P.; Zou, L. N.; Zhao, X.; Xu, Y. F.; Xu, F.; Li, Y. L.;Wang, Y. Chem. Eng. J. 2009, 149, 123. doi: 10.1016/j.cej.2008.10.015
24. [24]
  (24) Chen, S. H.; Yue, Q. Y.; Gao, B. Y.; Li, Q.; Xu, X.; Fu, K. F.Bioresour. Technol. 2011, 113, 114.
25. [25]
  (25) Baral, S. S.; Das, N.; Ramulu, T. S.; Sahoo, S. K.; Das, S. N.;Chaudhury, G. R. J. Hazard. Mater. 2009, 161, 1427. doi: 10.1016/j.jhazmat.2008.04.127
26. [26]
  (26) Klaus, P. R.; Amita, J.; Richard, H. L. Environ. Sci. Technol.1998, 32, 344. doi: 10.1021/es970421p
27. [27]
  (27) Yan, G. Y.; Viraraghavan, T.; Chen, M. Adsorpt. Sci. Technol.2001, 19, 25. doi: 10.1260/0263617011493953
28. [28]
  (28) Trivedi, H. C.; Patel, V. M.; Patel, R. D. Eur. Polym. J. 1973, 9,525. doi: 10.1016/0014-3057(73)90036-0
29. [29]
  (29) Lv, L.; Zhang, Y.;Wang, K.; Ray, A. K.; Zhao, X. S. J. Colloid Interface Sci. 2008, 325, 57. doi: 10.1016/j.jcis.2008.04.067
30. [30]
  (30) Pokhrel, D.; Viraraghavan, T. Bioresour. Technol. 2008, 99,2067. doi: 10.1016/j.biortech.2007.04.023
31. [31]
  (31) Sontheimer, H.; Crittenden, J. C.; Summers, R. S.; Hubele, C.;Roberts, C.; Snoeyink, V. L. Activated Carbon for Water Treatment, 2nd ed.; DVGW-Forschungsstelle: Karlsruhe,Germany, 1988; pp 258-312.
32. [32]
  (32) Wang, S.; Ma, Z. F.; Yao, H. Q. J. Chem. Eng. Chin. Univ. 2000,14, 65. [王晟, 马正飞, 姚虎卿. 高校化学工程学报, 2000,14, 65.]
33. [33]
  (33) Kirkelund, G. M.; Ottosen, L. M.; Villumsen, A. J. Hazard. Mater. 2009, 169, 685. doi: 10.1016/j.jhazmat.2009.03.149
34. [34]
  (34) Sanchez, F.; Garrabrants, A. C.; Vandecasteele, C.; MoszkowiczC, P.; Kosson, D. S. J. Hazard. Mater. B 2003, 96, 229. doi: 10.1016/S0304-3894(02)00215-7
35. [35]
  (35) Badruzzaman, M.;Westerhoff, P.; Knappe, D. R. Water Res.2004, 38, 4002. doi: 10.1016/j.watres.2004.07.007
36. [36]
  (36) Zhang, M. Y.; He, G. Z.; Pan, G. J. Colloid Interface Sci. 2009,338, 284.
37. [37]
  (37) He, G. Z.; Pan, G.; Zhang, M. Y. J. Colloid Interface Sci. 2011,364, 476. doi: 10.1016/j.jcis.2011.08.040
38. [38]
  (38) Zhang, M. Y.; He, G. Z.; Ding, C. C.; Chen, H.; Pan, G. Acta Phys. -Chim. Sin. 2009, 25, 2034. [张美一, 何广智, 丁程程,陈灏, 潘纲. 物理化学学报, 2009, 25, 2034.] doi: 10.3866/PKU.WHXB20090911
1. [1]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
2. [2]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
5. [5]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
6. [6]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
7. [7]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
8. [8]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
9. [9]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
10. [10]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . Modulating the d-band center of NNU-55(Fe) for enhanced CO₂ adsorption and photocatalytic activity. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
11. [11]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
12. [12]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
13. [13]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
14. [14]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
15. [15]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
16. [16]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
17. [17]
  Yuting Zhang , Zhiqian Wang . Methods and Case Studies for In-Depth Learning of the Aldol Reaction Based on Its Reversible Nature. University Chemistry, 2024, 39(7): 377-380. doi: 10.3866/PKU.DXHX202311037
18. [18]
  Suqing Shi , Anyang Li , Yuan He , Jianli Li , Xinjun Luan . Exploration and Practice of the “Progressive” Integrated Training Mode for Innovative Chemistry Talents at Comprehensive Universities in Western China. University Chemistry, 2024, 39(6): 42-49. doi: 10.3866/PKU.DXHX202402009
19. [19]
  Liping Wang , Huanfeng Wang , Yuling Li , Lingchuan Li , Xiaojing Li , Huifeng Chen , Bowen Ji , Linna Wang . Exploring the Full Process of a Research-Based Teaching Model through the Deep Integration of Theory and Practice: A Case Study of the Self-Designed Scheme for “Determination of Total Acid Content in White Vinegar”. University Chemistry, 2025, 40(5): 244-251. doi: 10.12461/PKU.DXHX202406035
20. [20]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037

Get Citation

PDF

XML

Metrics

PDF Downloads(550)
Abstract views(842)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Adsorption Mode on Metastable-Equilibrium Adsorption of As(V) on TiO2 Particles

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Adsorption Mode on Metastable-Equilibrium Adsorption of As(V) on TiO₂ Particles