Citation: NING Hui, HOU Min-Qiang, YANG De-Zhong, KANG Xin-Chen, HAN Bu-Xing. Ionic Association in Binary Ionic Liquids by Conductivity[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2107-2113. doi: 10.3866/PKU.WHXB201304172 shu

Ionic Association in Binary Ionic Liquids by Conductivity

1.
Institute of Chemistry, Chinese Academy of Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Beijing National Laboratory for Molecular Sciences, Beijing 100190, P. R. China

Received Date: 15 February 2013
Available Online: 17 April 2013
Fund Project: 国家自然科学基金(20903109, 21073207)资助项目 (20903109, 21073207)

In this study, the conductivity of 13 ionic liquids (ILs) and 25 related binary mixtures were determined at temperatures ranging from 293.15-323.15 K. The conductivity data of the pure ILs and their mixtures were fitted using the Vogel-Tammann-Fulcher (VTF) equation. The ionic association in the ILs and IL mixtures was discussed using the parameters of the VTF equation. It was demonstrated that at the same temperature, the ILs with short side chain cations, low charge density anions, and weak hydrogen bonding force between cations and anions usually exhibited high conductivity. Anions had a more obvious effect on conductivity than cations. The ionic association in the mixtures was affected not only by the species but also by the composition of the mixture.
- Ionic liquid,
- Binary mixture,
- Conductivity,
- Ionic association,
- VTF equation
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