Citation: NING Hui, HOU Min-Qiang, YANG De-Zhong, KANG Xin-Chen, HAN Bu-Xing. Ionic Association in Binary Ionic Liquids by Conductivity[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2107-2113. doi: 10.3866/PKU.WHXB201304172 shu

Ionic Association in Binary Ionic Liquids by Conductivity

1.
Institute of Chemistry, Chinese Academy of Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Beijing National Laboratory for Molecular Sciences, Beijing 100190, P. R. China

Received Date: 15 February 2013
Available Online: 17 April 2013
Fund Project: 国家自然科学基金(20903109, 21073207)资助项目 (20903109, 21073207)

In this study, the conductivity of 13 ionic liquids (ILs) and 25 related binary mixtures were determined at temperatures ranging from 293.15-323.15 K. The conductivity data of the pure ILs and their mixtures were fitted using the Vogel-Tammann-Fulcher (VTF) equation. The ionic association in the ILs and IL mixtures was discussed using the parameters of the VTF equation. It was demonstrated that at the same temperature, the ILs with short side chain cations, low charge density anions, and weak hydrogen bonding force between cations and anions usually exhibited high conductivity. Anions had a more obvious effect on conductivity than cations. The ionic association in the mixtures was affected not only by the species but also by the composition of the mixture.
- Ionic liquid,
- Binary mixture,
- Conductivity,
- Ionic association,
- VTF equation
1. [1]
  
  (1) ng, Y. Y.; Liu, M.; Jia, S. Y.; Feng, J. P.; Song, C. S.; Guo, X.W. Acta Phys. -Chim. Sin. 2012, 28, 686. [公艳艳, 刘民, 贾松岩,冯建萍, 宋春山,郭新闻. 物理化学学报, 2012, 28, 686.]doi: 10.3866/PKU.WHXB201112292
2. [2]
  (2) Yuan, X.; Lou, S. J.; Kou, Y. Acta Phys. -Chim. Sin. 2010, 26,908. [苑晓,娄舒洁, 寇元. 物理化学学报, 2010, 26,908.] doi: 10.3866/PKU.WHXB20100433
3. [3]
  (3) Chen, Y.; Han, J.; Wang, T.; Mu, T. C. Energy & Fuels 2011, 25,5810. doi: 10.1021/ef201519g
4. [4]
  (4) Zhao, X. Y.; Cao, Y. R.; Cao, G. R.; Xiao, R. J. Acta Phys. -Chim. Sin. 2012, 28, 1411. [赵学艳, 曹宇容, 曹桂荣,肖瑞杰. 物理化学学报, 2012, 28, 1411.] doi: 10.3866/PKU.WHXB201203262
5. [5]
  (5) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. Acta Phys. -Chim. Sin. 2012, 28, 2641. [仲皓想,赵春宝,骆浩,张灵志. 物理化学学报, 2012, 28, 2641.] doi: 10.3866/PKU.WHXB201207181
6. [6]
  (6) Dong, K.; Song, Y. T.; Liu, X. M.; Cheng, W. G.; Yao, X. Q.;Zhang, S. J. J. Phys. Chem. B 2012, 116, 1007. doi: 10.1021/jp205435u
7. [7]
  (7) Xu, W. G.; Li, L.; Ma, X. X.; Wei, J.; Duan, W. B.; Guan, W.;Yang, J. Z. J. Chem. Eng. Data 2012, 57, 2177. doi: 10.1021/je3000348
8. [8]
  (8) Zhang, Q. G.; Wei, Y.; Sun, S. S.; Wang, C.; Yang, M.; Liu, Q.S.; Gao, Y. A. J. Chem. Eng. Data 2012, 57, 2185. doi: 10.1021/je300153f
9. [9]
  (9) Wang, D.; Tian, G. C. Acta Phys. -Chim. Sin. 2012, 28, 2558.[王丁, 田国才.物理化学学报, 2012, 28, 2558.] doi: 10.3866/PKU.WHXB201208271
10. [10]
  (10) Ren, S. H.; Hou, Y. C.; Wu, W. Z.; Liu, Q. Y.; Xiao, Y. F.; Chen,X. T. J. Phys. Chem. B 2010, 114, 2175. doi: 10.1021/jp9108859
11. [11]
  (11) Zhang, L. Q.; Li, H. R. Acta Phys. -Chim. Sin. 2010, 26, 2877.[张力群,李浩然. 物理化学学报, 2010, 26, 2877.] doi: 10.3866/PKU.WHXB20101123
12. [12]
  (12) Zhai, C. P.; Liu, X. J.; Zhao, Y.; Wang, J. J. Acta Phys. -Chim. Sin. 2009, 25, 1185. [翟翠萍, 刘学军,赵扬,王键吉.物理化学学报, 2009, 25, 1185.] doi: 10.3866/PKU.WHXB20090628
13. [13]
  (13) Zhang, Q. G.; Wang, N. N.; Yu, Z. W. J. Phys. Chem. B 2010,114, 4747. doi: 10.1021/jp1009498
14. [14]
  (14) Niedermeyer, H.; Hallett, J. P.; Villar-Garcia, I. J.; Hunt, P. A.;Welton, T. Chem. Soc. Rev. 2012, 41, 7780. doi: 10.1039/c2cs35177c
15. [15]
  (15) Castiglione, F.; Raos, G.; Battista Appetecchi, G.; Montanino,M.; Passerini, S.; Moreno, M.; Famulari, A.; Mele, A. Phys. Chem. Chem. Phys. 2010, 12, 1784. doi: 10.1039/b921816e
16. [16]
  (16) Fletcher, K. A.; Baker, S. N.; Baker, G. A.; Pandey, S. New J. Chem. 2003, 27, 1706. doi: 10.1039/b305965k
17. [17]
  (17) Ma, L. L.; Liu, Y. F.; Yuan, J.; Wu, Y. H. Chemical Journal of Chinese Universities 2006, 27, 2182. [马亮亮,刘逸枫,袁俊,吴益华. 高等学校化学学报, 2006, 27, 2182.]
18. [18]
  (18) Annat, G.; Forsyth, M.; MacFarlane, D. R. J. Phys. Chem. B2012, 116, 8251. doi: 10.1021/jp3012602
19. [19]
  (19) Widegren, J. A.; Saurer, E. M.; Marsh, K. N.; Magee, J. W.J. Chem. Thermodyn. 2005, 37, 569. doi: 10.1016/j.jct.2005.04.009
20. [20]
  (20) Zech, O.; Stoppa, A.; Buchner, R.; Kunz, W. J. Chem. Eng. Data2010, 55, 1774. doi: 10.1021/je900793r
21. [21]
  (21) Tokuda, H.; Hayamizu, K.; Ishii, K.; Abu Bin Hasan Susan, M.;Watanabe, M. J. Phys. Chem. B 2004, 108, 16593. doi: 10.1021/jp047480r
22. [22]
  (22) Zhang, J. M.; Yang, C. H.; Hou, Z. S.; Han, B. X.; Jiang, T.; Li,X. H.; Zhao, G. Y.; Li, Y. F.; Liu, Z. M.; Zhao, D. B.; Kou, Y.New J. Chem. 2003, 27, 333. doi: 10.1039/b206526f
23. [23]
  (23) Burrell, G. L.; Burgar, I. M.; ng, Q.; Dunlop, N. F.;Separovic, F. J. Phys. Chem. B 2010, 114, 11436.
24. [24]
  (24) Tokuda, H.; Hayamizu, K.; Ishii, K.; Susan, M.; Watanabe, M.J. Phys. Chem. B 2005, 109, 6103. doi: 10.1021/jp044626d
25. [25]
  (25) Tokuda, H.; Ishii, K.; Susan, M.; Tsuzuki, S.; Hayamizu, K.;Watanabe, M. J. Phys. Chem. B 2006, 110, 2833. doi: 10.1021/jp053396f
26. [26]
  (26) Hagiwara, R.; Matsumoto, K.; Nakamori, Y.; Tsuda, T.; Ito, Y.;Matsumoto, H.; Momota, K. J. Electrochem. Soc. 2003, 150,D195.
27. [27]
  (27) Yoshida, Y.; Baba, O.; Saito, G. J. Phys. Chem. B 2007, 111,4742. doi: 10.1021/jp067055t
28. [28]
  (28) Leys, J.; Rajesh, R. N.; Menon, P. C.; Glorieux, C.; Longuemart,S.; Nockemann, P.; Pellens, M.; Binnemans, K. J. Chem. Phys.2010, 133, 034503. doi: 10.1063/1.3455892
29. [29]
  (29) Bandres, I.; Montano, D. F.; Gascon, I.; Cea, P.; Lafuente, C.Electrochim. Acta 2010, 55, 2252. doi: 10.1016/j.electacta.2009.11.073
30. [30]
  (30) Liu, Q. S.; Yan, P. F.; Yang, M.; Tan, Z. C.; Li, C. P.; Welz-Biermann, U. Acta Phys. -Chim. Sin. 2011, 27, 2762. [刘青山,颜佩芳, 杨淼, 谭志诚, 李长平, Welz-Biermann, U. 物理化学学报, 2011, 27, 2762.] doi: 10.3866/PKU.WHXB20112762
31. [31]
  (31) Noda, A.; Hayamizu, K.; Watanabe, M. J. Phys. Chem. B 2001,105, 4603. doi: 10.1021/jp004132q
32. [32]
  (32) Leys, J.;Wubbenhorst, M.; Menon, C. P.; Rajesh, R.; Thoen, J.;Glorieux, C.; Nockemann, P.; Thijs, B.; Binnemans, K.;Longuemart, S. J. Chem. Phys. 2008, 128, 64509. doi: 10.1063/1.2827462
33. [33]
  (33) Every, H.; Bishop, A. G.; Forsyth, M.; MacFarlane, D. R.Electrochim. Acta 2000, 45, 1279. doi: 10.1016/S0013-4686(99)00332-1
34. [34]
  (34) Stoppa, A.; Buchner, R.; Hefter, G. J. Mol. Liq. 2010, 153, 46.
35. [35]
  (35) Ning, H.; Hou, M. Q.; Mei, Q. Q.; Liu, Y. H.; Yang, D. Z.; Han,B. X. Science China Chemistry 2012, 55, 1509. [宁汇,侯民强,梅清清, 刘元会,杨德重, 韩布兴.中国科学:化学, 2012,55, 1509.] doi: 10.1007/s11426-012-4655-1
1. [1]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
2. [2]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
3. [3]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
4. [4]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
5. [5]
  Yang Chen , Xiuying Wang , Nengqin Jia . Ideological and Political Design, Blended Teaching Practice of Physical Chemistry Experiment: Pb-Sn Binary Metal Phase Diagram. University Chemistry, 2025, 40(3): 223-229. doi: 10.12461/PKU.DXHX202405184
6. [6]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
7. [7]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
8. [8]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
9. [9]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
10. [10]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
11. [11]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
12. [12]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
13. [13]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
14. [14]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
15. [15]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
16. [16]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
17. [17]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
18. [18]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
19. [19]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
20. [20]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015

Get Citation

PDF

XML

Metrics

PDF Downloads(747)
Abstract views(990)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142