Citation: MARÍ B., CEMBRERO-COCA P., SINGH K. C., KAUSHIK R. D., OM Hari. Preparation and Luminescence Properties of MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) Phosphors with Perovskite Structure[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1357-1362. doi: 10.3866/PKU.WHXB201304032 shu

Preparation and Luminescence Properties of MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) Phosphors with Perovskite Structure

1.
1 Institut de Disseny per la Fabricació Automatitzada (IDF)-Departament de Física Aplicada, Universitat Politècnica de València, Camí de Vera s/n, 46022 València, Spain;
2 Department of Chemistry, Maharshi Dayanand University, Rohtak 124001, Haryana, India;
3 Department of Chemistry, Gurukul Kangari University, Haridwar-249404, Uttarakhand, India

Received Date: 27 December 2012
Available Online: 3 April 2013
Fund Project: The project was supported by the Spanish vernment through MCINN (MAT2009-14625-C03-03) (MAT2009-14625-C03-03)European Commission through Nano CISproject (FP7-PEOPLE-2010-IRSES ref. 269279). (FP7-PEOPLE-2010-IRSES ref. 269279)

Calcium and barium zirconate powders based upon CaZrO₃:Eu³⁺,A and BaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) were prepared by combustion synthesis method and heating to ~1000℃ to improve crystallinity. The structure and morphology of materials were examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD results showed that CaZrO₃:Eu³⁺,A and BaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) perovskites possessed orthorhombic and cubic structures, respectively. The morphologies of all powders were very similar consisting of small, coagulated, cubical particles with narrow size distributions and smooth and regular surfaces. The characteristic luminescences of Eu³⁺ ions in CaZrO₃:Eu³⁺,A (A=Li⁺, Na⁺, K⁺) lattices were present with strong emissions at 614 and 625 nm for ⁵D₀→⁷F₂ transitions with other weaker emissions observed at 575, 592, 655, and 701 nm corresponding to ⁵D₀→⁷F_n transitions (where n=0, 1, 3, 4 respectively). In BaZrO₃:Eu³⁺ both the ⁵D₀→⁷F₁ and ⁵D₀→⁷F₂ transitions at 595 and 613 nm were strong. Photoluminescence intensities of CaZrO₃:Eu³⁺ samples were higher than those of BaZrO₃:Eu³⁺ lattices. This remarkable increase of photoluminescence intensity (corresponding to ⁵D₀→⁷F_n transitions) was observed in CaZrO₃:Eu³⁺ and BaZrO₃:Eu³⁺ if co-doped with Li⁺ ions. An additional broad band composed of many peaks between 440 to 575 nm was observed in BaZrO₃:Eu³⁺,,A samples. The intensity of this band was greatest in Li⁺ co-doped samples and lowest for K⁺ doped samples.
- CaZrO₃:Eu³⁺, A and BaZrO₃:Eu³⁺, A (A=Li⁺, Na⁺, K⁺),
- Charge compensator,
- Combustion synthesis,
- Photoluminescence
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Preparation and Luminescence Properties of MZrO3:Eu3+,A (M=Ca2+, Ba2+; A=Li+, Na+, K+) Phosphors with Perovskite Structure

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通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescence Properties of MZrO₃:Eu³⁺,A (M=Ca²⁺, Ba²⁺; A=Li⁺, Na⁺, K⁺) Phosphors with Perovskite Structure