Citation: ZHANG Xiao-Hua, ZHONG Jin-Di, YU Ya-Ming, ZHANG Yun-Song, LIU Bo, CHEN Jin-Hua. Well-Dispersed Platinum Nanoparticles Supported on Nitrogen-Doped Hollow Carbon Microspheres for Oxygen-Reduction Reaction[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1297-1304. doi: 10.3866/PKU.WHXB201304011 shu

Well-Dispersed Platinum Nanoparticles Supported on Nitrogen-Doped Hollow Carbon Microspheres for Oxygen-Reduction Reaction

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1 State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China;
2 College of Life and Science, Sichuan Agricultural University, Yaan 625014, P. R. China;
3 Xi’an Taijin Industrial Electrochemical Technology Co., Ltd, Northwest Institute For Non-ferrous Metal Research, Xi’an 710016, P. R. China

Received Date: 25 October 2012
Available Online: 1 April 2013
Fund Project: 长江学者和创新团队发展计划(PCSIRT) (PCSIRT) 湖南省自然科学基金(12JJ2010) (12JJ2010)高等学校年轻教师成长计划(2012) (2012)博士学科点专项科研基金(20110161110009)资助项目 (20110161110009)

Nitrogen-doped hollow carbon microspheres (N-HCMS) were synthesized by carbonization of poly(dopamine). Platinum (Pt) nanoparticles (NPs) were deposited onto the N-HCMS via a microwaveassisted reduction process. The morphology, surface area, and pore size distribution of the N-HCMS supported Pt catalysts (Pt/N-HCMS) were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and surface area and porosimetry measurements. The electrocatalytic properties of the Pt/N-HCMS catalyst towards oxygen-reduction reaction were investigated by cyclic voltammetry and linear sweep voltammetry. The Pt/N-HCMS catalyst showed almost double the specific mass activity of a commercial carbon supported Pt catalyst. This was attributed to a uniform dispersion of the Pt NPs and the unique mesoporous and hollow structure of N-HCMS. In addition, fast electron transfer processes were found to occur on the nitrogen doped N-HCMS and the catalyst exhibited excellent long-term stability. This work is of significance for the development of high-performance cathodic catalysts in fuel cells.
- Nitrogen-doping,
- Hollow carbon microsphere,
- Pt nanoparticle,
- Electrocatalysis,
- Oxygen-reduction reaction
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