Citation: LONG Mei, CONG Ye, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming. Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO₂ Composite[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1344-1350. doi: 10.3866/PKU.WHXB201303263 shu

Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO₂ Composite

1.
Hubei Province Key Laboratory of Coal Conversion and New Carbon Materials, Wuhan University of Science and Technology, Wuhan, Hubei 430081, P. R. China

Received Date: 9 January 2013
Available Online: 26 March 2013
Fund Project: 国家自然科学基金(20803054, 50972110)资助项目 (20803054, 50972110)

Partially reduced graphene oxide/titanium dioxide (R /TiO₂) composite was synthesized using tetrabutyl titanate and graphite oxide by a hydrothermal method. Photocatalytic activity of the material was evaluated by the degradation of methylene blue solution under visible light and UV light. The results suggest that the crystal phase and dispersion of titanium oxide in the composite can be controlled by varying the reaction temperature and amount of graphite oxide. Graphene oxide was partially reduced in the hydrothermal reaction process. Photocatalytic activities of partially reduced graphene oxide/titanium dioxide composites under both visible and UV light irradiation were higher than those of pure TiO₂. Partially reduced graphene oxide may act as a support and electron acceptor, and can also extend and enhance the band edge absorption of TiO₂ into the visible light region, hence effectively enhancing the adsorbability and photocatalytic activity of TiO₂.
- Hydrothermal,
- Partially reduced graphene oxide,
- Titanium dioxide,
- Photocatalysis,
- Support
1. [1]
  
  (1) Geim, A. K. Science 2009, 324, 1530. doi: 10.1126/science.1158877
2. [2]
  (2) Allen, M. J.; Tung, V. C.; Kaner, R. B. Chem. Rev. 2010, 110,132. doi: 10.1021/cr900070d
3. [3]
  (3) Zhang, H. B.; Zheng,W. G.; Yan, Q.; Yang, Y.;Wang, J.W.; Lu,Z. H.; Ji, G. Y.; Yu, Z. Z. Polymer 2010, 51, 1191. doi: 10.1016/j.polymer.2010.01.027
4. [4]
  (4) Wan, C.; Peng, T. J.; Sun, H. J.; Huang, Q. Chin. J. Inorg. Chem. 2012, 28 (5), 915. [万臣, 彭同江, 孙红娟, 黄桥.无机化学学报, 2012, 28 (5), 915.]
5. [5]
  (5) Chen, D.; Feng, H. B.; Li, J. H. Chem. Rev. 2012, 112, 6027.doi: 10.1021/cr300115g
6. [6]
  (6) Zhang, X. Y.; Sun, M. X.; Sun, Y. J.; Li, J.; Song, P.; Sun, T.;Cui, X. L. Acta Phys. -Chim. Sin. 2011, 27, 2831. [张晓艳,孙明轩, 孙钰珺, 李靖, 宋鹏, 孙通, 崔晓莉. 物理化学学报, 2011, 27, 2831.] doi: 10.3866/PKU.WHXB20112831
7. [7]
  (7) Zhang, X.; Yang, R.;Wang, C.; Heng, C. L. Acta Phys. -Chim. Sin. 2012, 28, 1520. [张晓, 杨蓉, 王琛, 衡成林. 物理化学学报, 2012, 28, 1520.] doi: 10.3866/PKU.WHXB201203131
8. [8]
  (8) Xu, Z. X.; Du, Y. J.; Jiao, Y. P.; Feng,W. Journal of Anhui University (Natural Science Edition) 2012, 36 (5), 73.[许志献, 杜燕军, 焦延鹏, 冯伟. 安徽大学学报(自然科学版), 2012, 36( 5), 73.]
9. [9]
  (9) Fan,W. Q.; Lai, Q. H.; Zhang, Q. H.;Wang, Y. J. Phys. Chem. C 2011, 115, 10694. doi: 10.1021/jp2008804
10. [10]
  (10) Cong, Y.; Zhang, J. L.; Chen, F.; Anpo, M. J. Phys. Chem. C2007, 111, 6976. doi: 10.1021/jp0685030
11. [11]
  (11) Zhang, X.; Liu, Q. Appl. Surf. Sci. 2008, 254, 4780.doi: 10.1016/j.apsusc.2008.01.094
12. [12]
  (12) Xing, M. Y.; Fang,W. Z.; Nasir, M.; Ma, Y. F.; Zhang, J. L.;Anpo, M. Journal of Catalysis 2013, 297, 236. doi: 10.1016/j.jcat.2012.10.014
13. [13]
  (13) Zhang, X. Y.; Li, H. P.; Cui, X. L. Chin. J. Inorg. Chem. 2009,25, 1903. [张晓艳, 李浩鹏, 崔晓莉. 无机化学学报, 2009,25, 1903.]
14. [14]
  (14) Cong, Y.; Li, X. K.; Qin, Y.; Dong, Z. J.; Yuan, G. M.; Cui, Z.W.; Lai, X. J. Appl. Catal. B 2011, 107, 128. doi: 10.1016/j.apcatb.2011.07.005
15. [15]
  (15) Rincón, M. E.; Trujillo-Camacho, M. E.; Cuentas-Galle s, A.K. Catal. Today 2005, 107-108, 606.
16. [16]
  (16) Soldano, C.; Mahmood, A.; Dujardin, E. Carbon 2010, 48,2127. doi: 10.1016/j.carbon.2010.01.058
17. [17]
  (17) Cong, Y.; Qin, Y.; Li, X. K.; Dong, Z. J.; Yuan, G. M.; Cui, Z.W. Acta Phys. -Chim. Sin. 2011, 27, 1509. [丛野, 秦云,李轩科, 董志军, 袁观明, 崔正威. 物理化学学报, 2011, 27,1509.] doi: 10.3866/PKU.WHXB201203272
18. [18]
  (18) Xiang, Q. J.; Yu, J. G.; Jaroniec, M. Chem. Soc. Rev. 2012, 41,782.
19. [19]
  (19) Jiang, G. D.; Lin, Z. F.; Chen, C.; Zhu, L. H.; Chang, Q.;Wang,N.;Wei,W.; Tang, H. Q. Carbon 2011, 49, 2693. doi: 10.1016/j.carbon.2011.02.059
20. [20]
  (20) Min, Y. L.; Zhang, K.; Zhao,W.; Zheng, F. C.; Chen, Y. C.;Zhang, Y. G. Chemical Engineering Journal 2012, 193-194,203.
21. [21]
  (21) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
22. [22]
  (22) Liu, J.; Bai, H.;Wang, Y.; Liu, Z.; Zhang, X.; Sun, D. D. Adv. Funct. Mater. 2010, 20, 4175. doi: 10.1002/adfm.201001391
23. [23]
  (23) Nethravathi, C.; Rajamathi, M. Carbon 2008, 46, 1994.doi: 10.1016/j.carbon.2008.08.013
24. [24]
  (24) Zhou, K. F.; Zhu, Y. H.; Yang, X. L.; Jiang, X.; Li, C. Z. New J. Chem. 2011, 35, 353. doi: 10.1039/c0nj00623h
25. [25]
  (25) Zhang, J. L.; Yang, H. J.; Shen, G. X.; Cheng, P.; Zhang, J. Y.;Guo, S.W. Chem. Commun. 2010, 46, 1112. doi: 10.1039/b917705a
26. [26]
  (26) Wang,W. G.; Yu, J. G.; Xiang, Q. J.; Cheng, B. Appl. Catal. B: Environ. 2012, 119-120, 109.
27. [27]
  (27) Zhang, L.W.; Fu, H. B.; Zhu, Y. F. Adv. Funct. Mater. 2008, 18,2180. doi: 10.1002/adfm.v18:15
28. [28]
  (28) Ma, L. J.; Guo, L. J. Acta Chim. Sin. 2006, 24 (9), 863. [马利静, 郭烈锦. 化学学报, 2006, 24 (9), 863.]
29. [29]
  (29) Zhou, Y.; Bao, Q. L.; Tang, L. A. L.; Zhong, Y. L.; Loh, K. P.Chem. Mater. 2009, 21, 2950. doi: 10.1021/cm9006603
30. [30]
  (30) Yang, Y. H.; Sun, H. J.; Peng, T. J. Chin. J. Inorg. Chem. 2010,26 (11), 2083. [杨勇辉, 孙红娟, 彭同江. 无机化学学报,2010, 26 (11), 2083.
31. [31]
  (31) Zhang, X. Y.; Sun, Y. J.; Cui, X. L.; Jiang, Z. Y. Int. J. hydrog. Energy 2012, 37, 811. doi: 10.1016/j.ijhydene.2011.04.053
32. [32]
  (32) Lei, Y.; Zhang, L. D.; Fan, J. C. Chem. Phys. Lett. 2001, 338,231. doi: 10.1016/S0009-2614(01)00263-9
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
4. [4]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
5. [5]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
8. [8]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
9. [9]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
10. [10]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
11. [11]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
12. [12]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
13. [13]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
14. [14]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
15. [15]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
17. [17]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
18. [18]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
19. [19]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
20. [20]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019

Get Citation

PDF

XML

Metrics

PDF Downloads(2138)
Abstract views(1808)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO2 Composite

Metrics

通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO₂ Composite