Citation: ZHOU Hong-Wei, MI Li, LIU Li-Xia, XU Sheng-hua, SUN Zhi-Wei. Experimental Measurements of the Surface Effective Charge of Colloidal Particles[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1260-1265. doi: 10.3866/PKU.WHXB201303262 shu

Experimental Measurements of the Surface Effective Charge of Colloidal Particles

ZHOU Hong-Wei ¹ ,
MI Li ^1,2 ,
LIU Li-Xia ¹ ,
XU Sheng-hua ^1, ,
SUN Zhi-Wei ¹

1.
1 Key Laboratory of Microgravity, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2 College of Chemistry, Chemical Engineering and Material Science, Shandong Normal University, Jinan 250014, P. R. China

Received Date: 27 December 2012
Available Online: 26 March 2013
Fund Project: 国家自然科学基金(11172302, 11032011)资助项目 (11172302, 11032011)

The effective surface charge of colloidal particles is an important parameter for calculating inter-particle interaction potentials. In this study, we investigated the effective charge of seven kinds of polystyrene particles having different diameters and surface charges. Two methods, conductivity-number density relationships and conductometric titration, were used to measure the effective charges. The results obtained from the two different methods show small variations of 7%. The effective charges were also calculated from empirical formulas and found to be twice as large as the experimental values, indicating these formulas cannot be universally applied to all colloidal dispersions.
- Colloidal crystal,
- Effective charge,
- Interaction,
- Conductometric titration
1. [1]
  
  (1) Ise, N.; Sogami, I. S. Structure Formation in Solution; ShaanxiScience and Technology Press: Xi'an, 2007; pp 38-45; translatedby Chen, S. R. [Ise, N.; Sogami, I. S. 高分子·胶体化学新论.陈声荣, 译. 西安: 陕西科学技术出版社, 2007: 38-45.]
2. [2]
  (2) Hiemenz, P. C. Principles of Colloidal and Surface Chemistry;Peking University Press: Beijing, 1986; pp 504-515; translatedby Zhou, Z. K., Ma, J. M. [Hiemenz, P. C. 胶体与表面化学原理. 周祖康, 马季铭, 译. 北京: 北京大学出版社, 1986: 504-515.]
3. [3]
  (3) Okubo, T. Polym. J. 2008, 40, 882. doi: 10.1295/polymj.PJ2007182
4. [4]
  (4) Auer, S.; Frenkel, D. J. Phys.: Condes. Matter 2002, 14, 7667.doi: 10.1088/0953-8984/14/33/308
5. [5]
  (5) Gu, L. Y.; Xu, S. H.; Sun, Z.W.;Wang, J. T. J. Colloid Interface Sci. 2010, 350, 409. doi: 10.1016/j.jcis.2010.07.009
6. [6]
  (6) Sogami, I.; Ise, N. J. Chem. Phys. 1984, 81, 6320. doi: 10.1063/1.447541
7. [7]
  (7) Ise, N. Phys. Chem. Chem. Phys. 2010, 12, 10279. doi: 10.1039/c000729c
8. [8]
  (8) Gisler, T.; Schulz, S. F.; Borkovec, M.; Sticher, H.;Schurtenberger, P.; Daguanno, B.; Klein, R. J. Chem. Phys.1994, 101, 9924. doi: 10.1063/1.467894
9. [9]
  (9) Strubbe, F.; Beunis, F.; Neyts, K. J. Colloid Interface Sci. 2006,301, 302. doi: 10.1016/j.jcis.2006.04.034
10. [10]
  (10) Tirado-Miranda, M.; Haro-Pérez, C.; Quesada-Pérez, M.;Callejas-Fernández, J.; Hidal -Álvarez, R. J. Colloid Interface Sci. 2003, 263, 74. doi: 10.1016/S0021-9797(03)00324-2
11. [11]
  (11) Wette, P.; Schöpe, H. J.; Palberg, T. J. Chem. Phys. 2002, 116,10981. doi: 10.1063/1.1480010
12. [12]
  (12) Hessinger, D.; Evers, M.; Palberg, T. Phys. Rev. E 2000, 61,5493. doi: 10.1103/PhysRevE.61.5493
13. [13]
  (13) Salh, R. J. Non-Cryst. Solids 2011, 357 (3), 1044. doi: 10.1016/j.jnoncrysol.2010.11.042
14. [14]
  (14) Yamanaka, J.; Hayashi, Y.; Ise, N.; Yamaguchi, T. Phys. Rev. E1997, 55, 3028. doi: 10.1103/PhysRevE.55.3028
15. [15]
  (15) ng, Y. K.; Nakashima, K.; Xu, R. Langmuir 2001, 17, 2889.doi: 10.1021/la001483n
16. [16]
  (16) Tata, B. V. R.; Jena, S. S. Solid State Commun. 2006, 139, 562.doi: 10.1016/j.ssc.2006.06.005
17. [17]
  (17) Yamanaka, J.; Matsuoka, H.; Kitano, H.; Ise, N. J. Colloid Interface Sci. 1990, 134, 92. doi: 10.1016/0021-9797(90)90255-M
18. [18]
  (18) Shouldice, G. T. D.; Vandezande, G. A.; Rudin, A. Eur. Polym. J. 1994, 30, 179. doi: 10.1016/0014-3057(94)90157-0
19. [19]
  (19) Sun, Z.W.; Zeng, F.;Wang, Z. Y.; Xie, X. L.; Tong, Z. J. Funct. Polym. 2001, 14, 381. [孙再武, 曾钫, 王朝阳, 谢小莉,童真. 功能高分子学报, 2001, 14, 381.]
20. [20]
  (20) Madaeni, S. S.; Ghanbarian, M. Polym. Int. 2000, 49, 1356.
21. [21]
  (21) Kim, J. H.; Chainey, M.; Elaasser, M. S.; Vanderhoff, J.W.Journal of Polymer Science Part A-Polymer Chemistry 1992,30, 171. doi: 10.1002/pola.1992.080300201
22. [22]
  (22) Du, X.; Xu, S. H.; Sun, Z.W.; Aa, Y. Acta Phys. -Chim. Sin.2010, 26, 2807. [杜嬛, 徐升华, 孙祉伟, 阿燕. 物理化学学报, 2010, 26, 2807. ] doi: 10.3866/PKU.WHXB20100941
23. [23]
  (23) Suzuki, D.; Hori me, K. Langmuir 2011, 27, 12368.doi: 10.1021/la203035e
24. [24]
  (24) Wette, P.; Schope, H. J.; Palberg, T. J. Chem. Phys. 2005, 123,174902. doi: 10.1063/1.2075047
25. [25]
  (25) Evers, M.; Garbow, N.; Hessinger, D.; Palberg, T. Phys. Rev. E1998, 57, 6774. doi: 10.1103/PhysRevE.57.6774
26. [26]
  (26) Xu, S.; Zhou, H.; Sun, Z.; Xie, J. Phys. Rev. E 2010, 82,010401. doi: 10.1103/PhysRevE.82.010401
27. [27]
  (27) Oman, S. Electrochimica Acta 1991, 36, 943. doi: 10.1016/0013-4686(91)85298-L
28. [28]
  (28) Labib, M. E.; Robertson, A. A. J. Colloid Interface Sci. 1980,77, 151. doi: 10.1016/0021-9797(80)90426-9
29. [29]
  (29) Ito, K.; Ise, N.; Okubo, T. J. Chem. Phys. 1985, 82, 5732.doi: 10.1063/1.448561
1. [1]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
2. [2]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
3. [3]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
4. [4]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
5. [5]
  Shanying Chen , Kangning Huo , Ke Qi , Jingyi Li , Shuxin Li , Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067
6. [6]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
7. [7]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
8. [8]
  Limin Shao , Na Li . A Unified Equation Derived from the Charge Balance Equation for Constructing Acid-Base Titration Curve and Calculating Endpoint Error. University Chemistry, 2024, 39(11): 365-373. doi: 10.3866/PKU.DXHX202401086
9. [9]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
10. [10]
  Yunchao Li , Shanying Chen , Ke Qi , Kangning Huo , Shuxin Li , Jingyi Li , Ying Wei , Louzhen Fan . A New Colloid Electrophoresis Experiment Incorporating Characteristics of Inquiry Learning and Ideological and Political Education. University Chemistry, 2024, 39(2): 47-51. doi: 10.3866/PKU.DXHX202308063
11. [11]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009
12. [12]
  Jiarui Wu , Gengxin Wu , Yan Wang , Yingwei Yang . Crystal Engineering Based on Leaning Towerarenes. University Chemistry, 2024, 39(3): 58-62. doi: 10.3866/PKU.DXHX202304014
13. [13]
  Na Li , Limin Shao . Deduction of the General Formula of the Inverse Function of the Titration Curve. University Chemistry, 2025, 40(3): 390-401. doi: 10.12461/PKU.DXHX202409134
14. [14]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
15. [15]
  Cheng Rong , Jiang Jiang , Xinyu Zheng . Constructivism and Deconstructivism in General Chemistry Teaching: Taking the Teaching of Colloidal Solutions as an Example. University Chemistry, 2024, 39(2): 292-297. doi: 10.3866/PKU.DXHX202308035
16. [16]
  Zongpei Zhang , Yanyang Li , Yanan Si , Kai Li , Shuangquan Zang . Developing a Chemistry Experiment Center Employing a Multifaceted Approach to Serve High-Quality Laboratory Education. University Chemistry, 2024, 39(7): 13-19. doi: 10.12461/PKU.DXHX202404041
17. [17]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
18. [18]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
19. [19]
  Hongwei Ma , Fang Zhang , Hui Ai , Niu Zhang , Shaochun Peng , Hui Li . Integrated Crystallographic Teaching with X-ray,TEM and STM. University Chemistry, 2024, 39(3): 5-17. doi: 10.3866/PKU.DXHX202308107
20. [20]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003

Get Citation

PDF

XML

Metrics

PDF Downloads(1133)
Abstract views(920)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142