Citation: ZHOU Hong-Wei, MI Li, LIU Li-Xia, XU Sheng-hua, SUN Zhi-Wei. Experimental Measurements of the Surface Effective Charge of Colloidal Particles[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1260-1265. doi: 10.3866/PKU.WHXB201303262 shu

Experimental Measurements of the Surface Effective Charge of Colloidal Particles

ZHOU Hong-Wei ¹ ,
MI Li ^1,2 ,
LIU Li-Xia ¹ ,
XU Sheng-hua ^1, ,
SUN Zhi-Wei ¹

1.
1 Key Laboratory of Microgravity, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2 College of Chemistry, Chemical Engineering and Material Science, Shandong Normal University, Jinan 250014, P. R. China

Received Date: 27 December 2012
Available Online: 26 March 2013
Fund Project: 国家自然科学基金(11172302, 11032011)资助项目 (11172302, 11032011)

The effective surface charge of colloidal particles is an important parameter for calculating inter-particle interaction potentials. In this study, we investigated the effective charge of seven kinds of polystyrene particles having different diameters and surface charges. Two methods, conductivity-number density relationships and conductometric titration, were used to measure the effective charges. The results obtained from the two different methods show small variations of 7%. The effective charges were also calculated from empirical formulas and found to be twice as large as the experimental values, indicating these formulas cannot be universally applied to all colloidal dispersions.
- Colloidal crystal,
- Effective charge,
- Interaction,
- Conductometric titration
1. [1]
  
  (1) Ise, N.; Sogami, I. S. Structure Formation in Solution; ShaanxiScience and Technology Press: Xi'an, 2007; pp 38-45; translatedby Chen, S. R. [Ise, N.; Sogami, I. S. 高分子·胶体化学新论.陈声荣, 译. 西安: 陕西科学技术出版社, 2007: 38-45.]
2. [2]
  (2) Hiemenz, P. C. Principles of Colloidal and Surface Chemistry;Peking University Press: Beijing, 1986; pp 504-515; translatedby Zhou, Z. K., Ma, J. M. [Hiemenz, P. C. 胶体与表面化学原理. 周祖康, 马季铭, 译. 北京: 北京大学出版社, 1986: 504-515.]
3. [3]
  (3) Okubo, T. Polym. J. 2008, 40, 882. doi: 10.1295/polymj.PJ2007182
4. [4]
  (4) Auer, S.; Frenkel, D. J. Phys.: Condes. Matter 2002, 14, 7667.doi: 10.1088/0953-8984/14/33/308
5. [5]
  (5) Gu, L. Y.; Xu, S. H.; Sun, Z.W.;Wang, J. T. J. Colloid Interface Sci. 2010, 350, 409. doi: 10.1016/j.jcis.2010.07.009
6. [6]
  (6) Sogami, I.; Ise, N. J. Chem. Phys. 1984, 81, 6320. doi: 10.1063/1.447541
7. [7]
  (7) Ise, N. Phys. Chem. Chem. Phys. 2010, 12, 10279. doi: 10.1039/c000729c
8. [8]
  (8) Gisler, T.; Schulz, S. F.; Borkovec, M.; Sticher, H.;Schurtenberger, P.; Daguanno, B.; Klein, R. J. Chem. Phys.1994, 101, 9924. doi: 10.1063/1.467894
9. [9]
  (9) Strubbe, F.; Beunis, F.; Neyts, K. J. Colloid Interface Sci. 2006,301, 302. doi: 10.1016/j.jcis.2006.04.034
10. [10]
  (10) Tirado-Miranda, M.; Haro-Pérez, C.; Quesada-Pérez, M.;Callejas-Fernández, J.; Hidal -Álvarez, R. J. Colloid Interface Sci. 2003, 263, 74. doi: 10.1016/S0021-9797(03)00324-2
11. [11]
  (11) Wette, P.; Schöpe, H. J.; Palberg, T. J. Chem. Phys. 2002, 116,10981. doi: 10.1063/1.1480010
12. [12]
  (12) Hessinger, D.; Evers, M.; Palberg, T. Phys. Rev. E 2000, 61,5493. doi: 10.1103/PhysRevE.61.5493
13. [13]
  (13) Salh, R. J. Non-Cryst. Solids 2011, 357 (3), 1044. doi: 10.1016/j.jnoncrysol.2010.11.042
14. [14]
  (14) Yamanaka, J.; Hayashi, Y.; Ise, N.; Yamaguchi, T. Phys. Rev. E1997, 55, 3028. doi: 10.1103/PhysRevE.55.3028
15. [15]
  (15) ng, Y. K.; Nakashima, K.; Xu, R. Langmuir 2001, 17, 2889.doi: 10.1021/la001483n
16. [16]
  (16) Tata, B. V. R.; Jena, S. S. Solid State Commun. 2006, 139, 562.doi: 10.1016/j.ssc.2006.06.005
17. [17]
  (17) Yamanaka, J.; Matsuoka, H.; Kitano, H.; Ise, N. J. Colloid Interface Sci. 1990, 134, 92. doi: 10.1016/0021-9797(90)90255-M
18. [18]
  (18) Shouldice, G. T. D.; Vandezande, G. A.; Rudin, A. Eur. Polym. J. 1994, 30, 179. doi: 10.1016/0014-3057(94)90157-0
19. [19]
  (19) Sun, Z.W.; Zeng, F.;Wang, Z. Y.; Xie, X. L.; Tong, Z. J. Funct. Polym. 2001, 14, 381. [孙再武, 曾钫, 王朝阳, 谢小莉,童真. 功能高分子学报, 2001, 14, 381.]
20. [20]
  (20) Madaeni, S. S.; Ghanbarian, M. Polym. Int. 2000, 49, 1356.
21. [21]
  (21) Kim, J. H.; Chainey, M.; Elaasser, M. S.; Vanderhoff, J.W.Journal of Polymer Science Part A-Polymer Chemistry 1992,30, 171. doi: 10.1002/pola.1992.080300201
22. [22]
  (22) Du, X.; Xu, S. H.; Sun, Z.W.; Aa, Y. Acta Phys. -Chim. Sin.2010, 26, 2807. [杜嬛, 徐升华, 孙祉伟, 阿燕. 物理化学学报, 2010, 26, 2807. ] doi: 10.3866/PKU.WHXB20100941
23. [23]
  (23) Suzuki, D.; Hori me, K. Langmuir 2011, 27, 12368.doi: 10.1021/la203035e
24. [24]
  (24) Wette, P.; Schope, H. J.; Palberg, T. J. Chem. Phys. 2005, 123,174902. doi: 10.1063/1.2075047
25. [25]
  (25) Evers, M.; Garbow, N.; Hessinger, D.; Palberg, T. Phys. Rev. E1998, 57, 6774. doi: 10.1103/PhysRevE.57.6774
26. [26]
  (26) Xu, S.; Zhou, H.; Sun, Z.; Xie, J. Phys. Rev. E 2010, 82,010401. doi: 10.1103/PhysRevE.82.010401
27. [27]
  (27) Oman, S. Electrochimica Acta 1991, 36, 943. doi: 10.1016/0013-4686(91)85298-L
28. [28]
  (28) Labib, M. E.; Robertson, A. A. J. Colloid Interface Sci. 1980,77, 151. doi: 10.1016/0021-9797(80)90426-9
29. [29]
  (29) Ito, K.; Ise, N.; Okubo, T. J. Chem. Phys. 1985, 82, 5732.doi: 10.1063/1.448561
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