Citation: ZHANG Xiao-Tong, YU Wen-Guang, QIN Yu-Cai, DONG Shi-Wei, PEI Ting-Ting, WANG Lin, SONG Li-Juan. Influence of Surface Acidity of Y Zeolites on the Adsorption of Organic Molecules by In situ Fourier Transform Infrared Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1273-1280. doi: 10.3866/PKU.WHXB201303183 shu

Influence of Surface Acidity of Y Zeolites on the Adsorption of Organic Molecules by In situ Fourier Transform Infrared Spectroscopy

1.
1 Key Laboratory of Petrochemical Catalytic Science and Technology, Liaoning Province, Liaoning ShiHua University, Fushun 113001, Liaoning Province, P. R. China;
2 College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266426, Shandong Province, P. R. China

Received Date: 2 January 2013
Available Online: 18 March 2013
Fund Project: 国家自然科学基金(20976077, 21076100) (20976077, 21076100) 中国石油天然气股份有限公司炼油催化剂重大专项(10-01A-01-01-01) (10-01A-01-01-01) 辽宁省高校创新团队项目(200T110) (200T110)

The surface acidity of Y-type zeolites (HY and NaY) modified by solid state ion exchange (SSIE) and liquid phase ion exchange were characterized by in situ Fourier transform infrared (FTIR) spectroscopy using pyridine as the probe molecule (Py-FTIR). The adsorption of single probe molecules (thiophene, cyclohexene and benzene) and double probe molecules (thiophene and cyclohexene, thiophene and benzene) compared with sorbents were studied using in situ FTIR spectroscopy. The results indicated that the Brönsted acid (B acid) of HY (L-CeY) is the catalytic center of cyclohexene dimerized alkenyl carbenium ions and thiophene oli merization, while the Lewis acid (L acid) is the major center of adsorption of thiophene, cyclohexene, and benzene. In addition, there is strong chemisorption and competitive adsorption of cyclohexene and thiophene, which provides evidence for the poor performance of removing sulfur. The S-CeY zeolite has abundant of weak Lewis acid sites. The sorbent is od at absorbing thiophene, while the influence of the competition adsorption of cyclohexene was not predominately. As to NaY zeolite, there is no preference for adsorption of thiophene, cyclohexene and benzene.
- In situ Fourier tansform infrared spectroscopy,
- Modified Y zeolite,
- Surface acidity,
- Competitive adsorption,
- Catalytic reaction
1. [1]
  
  (1) Tang, X. L.; Meng, X.; Shi, L. Ind. Eng. Chem. Res. 2011, 50 (12), 7527. doi: 10.1021/ie200475x
2. [2]
  (2) Shan, J. H.; Liu, X. Q.; Sun, L. B.; Cui, R. Energy Fuels 2008,22 (6), 3955. doi: 10.1021/ef800296n
3. [3]
  (3) Cheng, Z. L.; Liu, X. S.; Lu, J. Q.; Luo, M. F. React. Kinet. Catal. Lett. 2009, 97 (1), 1.
4. [4]
  (4) Shen, Y. S.; Li, P.W.; Xu, X. H.; Liu, H. RSC Adv. 2012, 2,1700. doi: 10.1039/c1ra00944c
5. [5]
  (5) Li, X. C.;Wei, G.; Yang, X. M.; Yang, Y. F.; Zeng, X. F.Phosphoru. Sulfur Silicon Relat. Elem. 2011, 186, 533. doi: 10.1080/10426507.2010.506899
6. [6]
  (6) Hernández-Maldonado, A. J.; Yang, R. T. Catal. Rev. 2004, 46 (2), 111. doi: 10.1081/CR-200032697
7. [7]
  (7) Velu, S.; Ma, X. L.; Song, C. S. Ind. Eng. Chem. Res. 2003, 42 (21), 5293. doi: 10.1021/ie020995p
8. [8]
  (8) Wang, H. G.; Jiang, H.; Xu, J.; Sun, Z. L.; Zhang, X. T.; Zhu, H.L.; Song, L. J. Acta Phys. -Chim. Sin. 2008, 24 (9), 1714. [王洪国, 姜恒, 徐静, 孙兆林, 张晓彤, 朱赫礼, 宋丽娟. 物理化学学报, 2008, 24 (9), 1714.] doi: 10.3866/PKU.WHXB20080933
9. [9]
  (9) Song, L. J.; Pan, M. X.; Qin, Y. C.; Ju, X. F.; Duan, L. H.; Chen,X. L. Chem. J. Chin. Univ. 2011, 32 (3), 787. [宋丽娟, 潘明雪, 秦玉才, 鞠秀芳, 段林海, 陈晓陆. 高等学校化学学报,2011, 32 (3), 787.]
10. [10]
  (10) Wang,W. Y.; Pan, M. X.; Qin, Y. C.;Wang, L. T.; Song, L. J.Acta Phys. -Chim. Sin. 2011, 27 (5), 1176. [王旺银, 潘明雪,秦玉才, 王凌涛, 宋丽娟. 物理化学学报, 2011, 27 (5), 1176.]doi: 10.3866/PKU.WHXB20110442
11. [11]
  (11) Shao, X. C.; Duan, L. H.;Wu, Y. Y.; Qin, Y. C.; Yu,W. G.;Wang, Y.; Li, H. L.; Sun, Z. L.; Song, L. J. Acta Phys. -Chim. Sin. 2012, 28 (6), 1467. [邵新超, 段林海, 武玉叶, 秦玉才,于文广, 王源, 李怀雷, 孙兆林, 宋丽娟. 物理化学学报,2012, 28 (6), 1467.] doi: 10.3866/PKU.WHXB201203312
12. [12]
  (12) Shao, X. C.; Zhang, X. T.; Yu,W. G.;Wu, Y. Y.; Qin, Y. C.; Sun,Z. L.; Song, L. J. Appl. Surf. Sci. 2012, 263, 1. doi: 10.1016/j.apsusc.2012.07.142
13. [13]
  (13) Tang, X. L.; Shi, L. Langmuir 2011, 27, 11999. doi: 10.1021/la2025654
14. [14]
  (14) Gao, J. J.; Li, H. Q.; Zhang, H. X.; Lu,Y. Z.; Meng, H.; Li, C. X.Ind. Eng. Chem. Res. 2012, 51 (12), 4682. doi: 10.1021/ie202831p
15. [15]
  (15) Lamberti, C.; Zecchina, A.; Groppo, E.; Bordiga, S. Chem. Soc. Rev. 2010, 39, 4951. doi: 10.1039/c0cs00117a
16. [16]
  (16) Lercher, J. A.; Gründling, C.; Eder-Mirth, G. Catal. Today 1996,27, 353. doi: 10.1016/0920-5861(95)00248-0
17. [17]
  (17) Jin, L. L.; Li, X. Q.;Wang, H. G.; Ju, X. F.; Liu, L. M.; Song, L.J. Industrial Catalysis 2008, 16 (10), 71. [靳玲玲, 李秀奇, 王洪国, 鞠秀芳, 刘黎明, 宋丽娟. 工业催化, 2008, 16 (10), 71.]
18. [18]
  (18) Kowalak, S.; Szymkowiak, E.; Laniecki, M. J. Fluorine Chem.1999, 93, 175. doi: 10.1016/S0022-1139(98)00312-1
19. [19]
  (19) Coughlan, B.; Keane, M. A. Catal. Lett. 1990, 5, 113.doi: 10.1007/BF00763944
20. [20]
  (20) Yu, S. Q.; Tian, H. P.; Zhu, Y. X.; Dai, Z. Y.; Long, J. Acta Phys. -Chim. Sin. 2011, 27 (11), 2528. [于善青, 田辉平,朱玉霞, 代振宇, 龙军. 物理化学学报, 2011, 27 (11), 2528.]doi: 10.3866/PKU.WHXB20111101
21. [21]
  (21) Liu, X. Y.; Zhou, L. X.; Yin, A. X.; Zheng, L. B. Acta Phys. -Chim. Sin. 1987, 3 (4), 375. [刘献友, 周立辛, 尹安学,郑禄彬. 物理化学学报, 1987, 3 (4), 375.] doi: 10.3866/PKU.WHXB19870408
22. [22]
  (22) Li, Z.; Xie, K. C.; Slade, R. C. T. Appl. Catal. A 2001, 209, 107.doi: 10.1016/S0926-860X(00)00745-6
23. [23]
  (23) Xin, Q.; Zhang, H.; Li, X. S.; Li, C. Journal of Fuel Chemistry and Technology 1991, 19 (4), 333. [辛勤, 张慧, 李新生,李灿. 燃料化学学报, 1991, 19 (4), 333.]
24. [24]
  (24) Geobaldo, F.; Palomino, G. T.; Bordiga, S.; Zecchina, A.; Areán,C. O. Phys. Chem. Chem. Phys. 1999, 1, 561. doi: 10.1039/a807353h
25. [25]
  (25) Deangelis, B. A.; Applerto, G. J. Colloid Interface Sci. 1975, 53,14. doi: 10.1016/0021-9797(75)90029-6
26. [26]
  (26) Yang, S.W.; Kondo, J. N.; Domen, K. Catal. Today 2002, 73,113. doi: 10.1016/S0920-5861(01)00504-1
27. [27]
  (27) Angell, C. L.; Howell, M. V. J. Colloid Interface Sci. 1968, 28,279. doi: 10.1016/0021-9797(68)90131-8
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
6. [6]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
9. [9]
  Yan Yuan , Haitao Wu , Yi Zhang , Li Jiang , Feng Cao , Yanmao Dong . Research on the Talent Training System to Enhance the Core Competence of Employment for Undergraduate Students Majoring in Materials Chemistry. University Chemistry, 2024, 39(11): 52-56. doi: 10.12461/PKU.DXHX202402015
10. [10]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
11. [11]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
12. [12]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
13. [13]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
14. [14]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
15. [15]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
16. [16]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
17. [17]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
18. [18]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
19. [19]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
20. [20]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276

Get Citation

PDF

XML

Metrics

PDF Downloads(992)
Abstract views(1108)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142