Citation: ZHANG Xiao-Tong, YU Wen-Guang, QIN Yu-Cai, DONG Shi-Wei, PEI Ting-Ting, WANG Lin, SONG Li-Juan. Influence of Surface Acidity of Y Zeolites on the Adsorption of Organic Molecules by In situ Fourier Transform Infrared Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1273-1280. doi: 10.3866/PKU.WHXB201303183 shu

Influence of Surface Acidity of Y Zeolites on the Adsorption of Organic Molecules by In situ Fourier Transform Infrared Spectroscopy

1.
1 Key Laboratory of Petrochemical Catalytic Science and Technology, Liaoning Province, Liaoning ShiHua University, Fushun 113001, Liaoning Province, P. R. China;
2 College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266426, Shandong Province, P. R. China

Received Date: 2 January 2013
Available Online: 18 March 2013
Fund Project: 国家自然科学基金(20976077, 21076100) (20976077, 21076100) 中国石油天然气股份有限公司炼油催化剂重大专项(10-01A-01-01-01) (10-01A-01-01-01) 辽宁省高校创新团队项目(200T110) (200T110)

The surface acidity of Y-type zeolites (HY and NaY) modified by solid state ion exchange (SSIE) and liquid phase ion exchange were characterized by in situ Fourier transform infrared (FTIR) spectroscopy using pyridine as the probe molecule (Py-FTIR). The adsorption of single probe molecules (thiophene, cyclohexene and benzene) and double probe molecules (thiophene and cyclohexene, thiophene and benzene) compared with sorbents were studied using in situ FTIR spectroscopy. The results indicated that the Brönsted acid (B acid) of HY (L-CeY) is the catalytic center of cyclohexene dimerized alkenyl carbenium ions and thiophene oli merization, while the Lewis acid (L acid) is the major center of adsorption of thiophene, cyclohexene, and benzene. In addition, there is strong chemisorption and competitive adsorption of cyclohexene and thiophene, which provides evidence for the poor performance of removing sulfur. The S-CeY zeolite has abundant of weak Lewis acid sites. The sorbent is od at absorbing thiophene, while the influence of the competition adsorption of cyclohexene was not predominately. As to NaY zeolite, there is no preference for adsorption of thiophene, cyclohexene and benzene.
- In situ Fourier tansform infrared spectroscopy,
- Modified Y zeolite,
- Surface acidity,
- Competitive adsorption,
- Catalytic reaction
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