Citation: LIN Pei-Bin, YANG Yu, CHEN Wei, GAO Han-Yang, CHEN Xiao-Ping, YUAN Jian, SHANGGUAN Wen-Feng. Hydrothermal Synthesis and Activity of NiS-PdS/CdS Catalysts for Photocatalytic Hydrogen Evolution under Visible Light Irradiation[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1313-1318. doi: 10.3866/PKU.WHXB201303141 shu

Hydrothermal Synthesis and Activity of NiS-PdS/CdS Catalysts for Photocatalytic Hydrogen Evolution under Visible Light Irradiation

1.
Research Center for Combustion and Environmental Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 7 January 2013
Available Online: 14 March 2013
Fund Project: 国家重点基础研究发展规划项目(973) (2009CB220000) (973) (2009CB220000) 国家高技术研究发展计划项目(863) (2012AA051501) (863) (2012AA051501)上海市国际合作项目(12160705700)资助 (12160705700)

To improve the solar energy transformation efficiency, it is necessary to study the efficiency of photocatalysts under visible light irradiation. In this study, the composite photocatalyst NiS-PdS/CdS has been developed using a hydrothermal method from the raw materials cadmium sulfide, palladium chloride, nickel acetate and thiourea. The characteristics of NiS-PdS/CdS were studied by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. In addition, the photocatalytic activities for water splitting were tested using lactic acid as the sacrificial reagent. The results showed that NiS and PdS dispersed well on the surface of CdS. The activity of NiS-PdS/CdS was much higher than that of CdS under visible light irradiation. When the loading amount of NiS and PdS reached 1.5% and 0.41% (w), respectively, NiS-PdS/ CdS showed the highest activity. The H₂ evolution rate increased up to 6556 μmol·h^-1, which was six times higher than that of unloaded CdS and nearly two times higher than that of NiS/CdS. The apparent quantum yield was 47.5% (λ=420 nm). The co-catalysts NiS and PdS prompted the transfer of photogenerated electrons and holes, respectively. Compared with single-loading, co-loading the two co-catalysts could transfer and separate charge carriers more efficiently, resulting in enhancement of the activity for photocatalytic hydrogen production.
- NiS-PdS/CdS,
- Hydrothermal method,
- Co-loading,
- Photocatalysis,
- Hydrogen energy
1. [1]
  
  (1) Osterloh, F. E. Chem. Mater. 2008, 20, 35. doi: 10.1021/cm7024203
2. [2]
  (2) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/b800489g
3. [3]
  (3) Maeda, K.; Domen, K. J. Phys. Chem. C 2007, 111, 7851 doi: 10.1021/jp070911w
4. [4]
  (4) Kato, H.; Asakura, K.; Kudo, A. J. Am. Chem. Soc. 2003, 125,3082. doi: 10.1021/ja027751g
5. [5]
  (5) Chen,W.; Gao, H. Y.; Yang, Y.; Lin, P. B.; Yuan, J.; Shangguan,W. F.; Su, J. C.; Sun, Y. Z. Acta Phys. -Chim. Sin. 2012, 28,2911. [陈威, 高寒阳, 杨俞, 林培宾, 袁坚, 上官文峰,苏佳纯, 孙洋洲. 物理化学学报, 2012, 28, 2911.] doi: 10.3866/PKU.WHXB201208011
6. [6]
  (6) Murphy, A. B.; Barnes, P. R. F.; Randeniya, L. K.; Plumb, I. C.;Grey, I. E.; Horne, M. D.; Glasscock, J. A. Int. J. Hydrog. Energy 2006, 31, 1999. doi: 10.1016/j.ijhydene.2006.01.014
7. [7]
  (7) Chen, X. P.; Shangguan,W. F. Front. Energy doi: 10.1007/s11708-012-0228-4
8. [8]
  (8) Wen, F. Y.; Yang, J. H.; Zong, X.; Ma, Y.; Xu, Q.; Ma, B. J.; Li,C. Progress in Chemistry 2009, 21, 2285. [温福宇, 杨金辉,宗旭, 马艺, 徐倩, 马保军, 李灿. 化学进展, 2009, 21,2285.]
9. [9]
  (9) Williams, R. J. Chem. Phys. 1960, 32, 1505. doi: 10.1063/1.1730950
10. [10]
  (10) Sathish, M.; Viswanathan, B.; Viswanath, R. P. J. Hydrog. Energy 2006, 31, 891. doi: 10.1016/j.ijhydene.2005.08.002
11. [11]
  (11) Li, Y. X.; Xie, Y. Z.; Peng, S. Q.; Lu, G. X.; Li, S. B.Chemosphere 2006, 63, 1312. doi: 10.1016/j.chemosphere.2005.09.004
12. [12]
  (12) Sakata, T.; Hashimoto, K.; Kawai, T. J. Phys. Chem. 1984, 88,5214
13. [13]
  (13) Zong, X.; Han, J. F.; Ma, G. J.; Yan, H. J.;Wu, G. P.; Li, C.J. Phys. Chem. C 2011, 115, 12202. doi: 10.1021/jp2006777
14. [14]
  (14) Zong, X.; Yan, H. J.;Wu, G. P.; Ma, G. J.;Wen, F. Y.;Wang, L.;Li, C. J. Am. Chem. Soc. 2008, 130, 7176. doi: 10.1021/ja8007825
15. [15]
  (15) Yan, H. J.; Yang, J. H.; Ma, G. J.;Wu, G. P.; Zong, X.; Lei, Z.B.; Shi, J. Y.; Li, C. J. Catal. 2009, 266, 165. doi: 10.1016/j.jcat.2009.06.024
16. [16]
  (16) Bao, N. Z.; Shen, L. M.; Takata, T.; Domen, K. Chem. Mater.2008, 20, 110. doi: 10.1021/cm7029344
17. [17]
  (17) Zhang,W.;Wang, Y.;Wang, Z.; Zhong, Z.; Xu, R. Chem. Commun. 2010, 46, 7631. doi: 10.1039/c0cc01562h
18. [18]
  (18) Harada, H.; Sakata, T.; Ueda, T. J. Am. Chem. Soc. 1985, 107,1773. doi: 10.1021/ja00292a060
19. [19]
  (19) Lin, K.; Chuang, C.; Lee, Y.; Li, F.; Chang, Y. J. Phys. Chem. C2012, 116, 1550. doi: 10.1021/jp209353j
20. [20]
  (20) Spanhel, L.;Weller, H.; Henglein, A. J. Am. Chem. Soc. 1987,109, 6632. doi: 10.1021/ja00256a012
21. [21]
  (21) Hurum, D. C.; Agrios, A. G.; Gray, K. A. J. Phys. Chem. B2003, 107, 4545. doi: 10.1021/jp0273934
22. [22]
  (22) Zou, Z. G.; Ye, J. H.; Sayama, K.; Arakawa, H. Nature 2001,414, 625. doi: 10.1038/414625a
23. [23]
  (23) Assuncao, N.; Giz, M.; Tremiliosi, G.; nzalez, E.J. Electrochem. Soc. 1997, 144, 2794. doi: 10.1149/1.1837897
24. [24]
  (24) Yang, J. H.; Yan, H. J.;Wang, X. L.;Wen, F. Y.;Wang, Z. J.;Fan, D. Y.; Shi, J. Y.; Li, C. J. Catal. 2012, 290, 151.
25. [25]
  (25) Min, S. X.; Lü, G. X. Acta Phys. -Chim. Sin. 2011, 27, 2178.[敏世雄, 吕功煊. 物理化学学报, 2011, 27, 2178.] doi: 10.3866/PKU.WHXB20110904
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