Citation: LIN Pei-Bin, YANG Yu, CHEN Wei, GAO Han-Yang, CHEN Xiao-Ping, YUAN Jian, SHANGGUAN Wen-Feng. Hydrothermal Synthesis and Activity of NiS-PdS/CdS Catalysts for Photocatalytic Hydrogen Evolution under Visible Light Irradiation[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1313-1318. doi: 10.3866/PKU.WHXB201303141 shu

Hydrothermal Synthesis and Activity of NiS-PdS/CdS Catalysts for Photocatalytic Hydrogen Evolution under Visible Light Irradiation

1.
Research Center for Combustion and Environmental Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 7 January 2013
Available Online: 14 March 2013
Fund Project: 国家重点基础研究发展规划项目(973) (2009CB220000) (973) (2009CB220000) 国家高技术研究发展计划项目(863) (2012AA051501) (863) (2012AA051501)上海市国际合作项目(12160705700)资助 (12160705700)

To improve the solar energy transformation efficiency, it is necessary to study the efficiency of photocatalysts under visible light irradiation. In this study, the composite photocatalyst NiS-PdS/CdS has been developed using a hydrothermal method from the raw materials cadmium sulfide, palladium chloride, nickel acetate and thiourea. The characteristics of NiS-PdS/CdS were studied by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. In addition, the photocatalytic activities for water splitting were tested using lactic acid as the sacrificial reagent. The results showed that NiS and PdS dispersed well on the surface of CdS. The activity of NiS-PdS/CdS was much higher than that of CdS under visible light irradiation. When the loading amount of NiS and PdS reached 1.5% and 0.41% (w), respectively, NiS-PdS/ CdS showed the highest activity. The H₂ evolution rate increased up to 6556 μmol·h^-1, which was six times higher than that of unloaded CdS and nearly two times higher than that of NiS/CdS. The apparent quantum yield was 47.5% (λ=420 nm). The co-catalysts NiS and PdS prompted the transfer of photogenerated electrons and holes, respectively. Compared with single-loading, co-loading the two co-catalysts could transfer and separate charge carriers more efficiently, resulting in enhancement of the activity for photocatalytic hydrogen production.
- NiS-PdS/CdS,
- Hydrothermal method,
- Co-loading,
- Photocatalysis,
- Hydrogen energy
1. [1]
  
  (1) Osterloh, F. E. Chem. Mater. 2008, 20, 35. doi: 10.1021/cm7024203
2. [2]
  (2) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/b800489g
3. [3]
  (3) Maeda, K.; Domen, K. J. Phys. Chem. C 2007, 111, 7851 doi: 10.1021/jp070911w
4. [4]
  (4) Kato, H.; Asakura, K.; Kudo, A. J. Am. Chem. Soc. 2003, 125,3082. doi: 10.1021/ja027751g
5. [5]
  (5) Chen,W.; Gao, H. Y.; Yang, Y.; Lin, P. B.; Yuan, J.; Shangguan,W. F.; Su, J. C.; Sun, Y. Z. Acta Phys. -Chim. Sin. 2012, 28,2911. [陈威, 高寒阳, 杨俞, 林培宾, 袁坚, 上官文峰,苏佳纯, 孙洋洲. 物理化学学报, 2012, 28, 2911.] doi: 10.3866/PKU.WHXB201208011
6. [6]
  (6) Murphy, A. B.; Barnes, P. R. F.; Randeniya, L. K.; Plumb, I. C.;Grey, I. E.; Horne, M. D.; Glasscock, J. A. Int. J. Hydrog. Energy 2006, 31, 1999. doi: 10.1016/j.ijhydene.2006.01.014
7. [7]
  (7) Chen, X. P.; Shangguan,W. F. Front. Energy doi: 10.1007/s11708-012-0228-4
8. [8]
  (8) Wen, F. Y.; Yang, J. H.; Zong, X.; Ma, Y.; Xu, Q.; Ma, B. J.; Li,C. Progress in Chemistry 2009, 21, 2285. [温福宇, 杨金辉,宗旭, 马艺, 徐倩, 马保军, 李灿. 化学进展, 2009, 21,2285.]
9. [9]
  (9) Williams, R. J. Chem. Phys. 1960, 32, 1505. doi: 10.1063/1.1730950
10. [10]
  (10) Sathish, M.; Viswanathan, B.; Viswanath, R. P. J. Hydrog. Energy 2006, 31, 891. doi: 10.1016/j.ijhydene.2005.08.002
11. [11]
  (11) Li, Y. X.; Xie, Y. Z.; Peng, S. Q.; Lu, G. X.; Li, S. B.Chemosphere 2006, 63, 1312. doi: 10.1016/j.chemosphere.2005.09.004
12. [12]
  (12) Sakata, T.; Hashimoto, K.; Kawai, T. J. Phys. Chem. 1984, 88,5214
13. [13]
  (13) Zong, X.; Han, J. F.; Ma, G. J.; Yan, H. J.;Wu, G. P.; Li, C.J. Phys. Chem. C 2011, 115, 12202. doi: 10.1021/jp2006777
14. [14]
  (14) Zong, X.; Yan, H. J.;Wu, G. P.; Ma, G. J.;Wen, F. Y.;Wang, L.;Li, C. J. Am. Chem. Soc. 2008, 130, 7176. doi: 10.1021/ja8007825
15. [15]
  (15) Yan, H. J.; Yang, J. H.; Ma, G. J.;Wu, G. P.; Zong, X.; Lei, Z.B.; Shi, J. Y.; Li, C. J. Catal. 2009, 266, 165. doi: 10.1016/j.jcat.2009.06.024
16. [16]
  (16) Bao, N. Z.; Shen, L. M.; Takata, T.; Domen, K. Chem. Mater.2008, 20, 110. doi: 10.1021/cm7029344
17. [17]
  (17) Zhang,W.;Wang, Y.;Wang, Z.; Zhong, Z.; Xu, R. Chem. Commun. 2010, 46, 7631. doi: 10.1039/c0cc01562h
18. [18]
  (18) Harada, H.; Sakata, T.; Ueda, T. J. Am. Chem. Soc. 1985, 107,1773. doi: 10.1021/ja00292a060
19. [19]
  (19) Lin, K.; Chuang, C.; Lee, Y.; Li, F.; Chang, Y. J. Phys. Chem. C2012, 116, 1550. doi: 10.1021/jp209353j
20. [20]
  (20) Spanhel, L.;Weller, H.; Henglein, A. J. Am. Chem. Soc. 1987,109, 6632. doi: 10.1021/ja00256a012
21. [21]
  (21) Hurum, D. C.; Agrios, A. G.; Gray, K. A. J. Phys. Chem. B2003, 107, 4545. doi: 10.1021/jp0273934
22. [22]
  (22) Zou, Z. G.; Ye, J. H.; Sayama, K.; Arakawa, H. Nature 2001,414, 625. doi: 10.1038/414625a
23. [23]
  (23) Assuncao, N.; Giz, M.; Tremiliosi, G.; nzalez, E.J. Electrochem. Soc. 1997, 144, 2794. doi: 10.1149/1.1837897
24. [24]
  (24) Yang, J. H.; Yan, H. J.;Wang, X. L.;Wen, F. Y.;Wang, Z. J.;Fan, D. Y.; Shi, J. Y.; Li, C. J. Catal. 2012, 290, 151.
25. [25]
  (25) Min, S. X.; Lü, G. X. Acta Phys. -Chim. Sin. 2011, 27, 2178.[敏世雄, 吕功煊. 物理化学学报, 2011, 27, 2178.] doi: 10.3866/PKU.WHXB20110904
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
3. [3]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
4. [4]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
5. [5]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
6. [6]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
7. [7]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
8. [8]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
9. [9]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
10. [10]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
11. [11]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
12. [12]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
13. [13]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
14. [14]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
15. [15]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
16. [16]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
17. [17]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
18. [18]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012

Get Citation

PDF

XML

Metrics

PDF Downloads(879)
Abstract views(1296)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142