Citation: YANG Bin, WU Hui, HU Song-Wei, LÜ Hui-Ling, SONG Ye, ZHU Xu-Fei. Fabrication and Performance of Electrolytic-Electrochemical Hybrid Capacitors[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1013-1020. doi: 10.3866/PKU.WHXB201303122 shu

Fabrication and Performance of Electrolytic-Electrochemical Hybrid Capacitors

1.
Key Laboratory of Soft Chemistry and Functional Materials of Education Ministry, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

Received Date: 21 January 2013
Available Online: 12 March 2013
Fund Project: 国家自然科学基金(51077072, 61171043)资助项目 (51077072, 61171043)

To solve the issue of comparatively low operation voltage of electrochemical capacitors, a hybrid capacitor consisting of the anode electrode of tantalum electrolytic capacitor and the cathode electrode of polyaniline (PANI)/TiO₂ with high energy density and high working voltage was developed. The PANI/TiO₂ composite electrode for use as the capacitor cathode was prepared by in situ electrochemical polymerization of aniline in porous anodic titania nanotube arrays on titanium foil substrates. The composite electrode showed od rate capability with a specific capacitance of 10.0 mF·cm^-2 and a high power density of 0.55 mW·cm^-2. Using a dielectric coated anode electrode, the single-cell hybrid capacitor could withstand working voltages as high as 100 V. As the PANI/TiO₂ composite cathode only requires a small volume because of its high specific capacitance, available space can be used to enlarge the anode electrode, leading to an increase in specific capacitance of the hybrid capacitor. The hybrid capacitor had high volumetric and gravimetric energy densities, which were about four times and three times higher than those of a tantalum electrolytic capacitor. The short circuit charge-discharge cycle test for the hybrid capacitor at 100 V showed that its capacitance did not decrease, and the equivalent series resistance did not increase after 10000 cycles, indicating excellent cycle stability and power performance. The peak power density was estimated to be 847.5 W·g^-1. In addition, electrochemical impedance spectroscopy data indicated that the hybrid capacitor had od impedance and frequency characteristics.
- Hybrid capacitor,
- Electrochemical capacitor,
- TiO₂,
- Polyaniline,
- Tantalum electrolytic capacitor
1. [1]
  
  (1) Conway, B. E. Electrochemical Supercapacitors, 1st ed.; KluwerAcademic Publishing/Plenum Publisher: New York, 1999; pp11-30.
2. [2]
  (2) Burke, A. J. Power Sources 2000, 91, 37. doi: 10.1016/S0378-7753(00)00485-7
3. [3]
  (3) Wu, Q.; Xu, Y.; Yao, Z.; Liu, A.; Shi, G. ACS Nano 2010, 4,1963. doi: 10.1021/nn1000035
4. [4]
  (4) Yang, X.; Zhu, J.; Qiu, L.; Li, D. Adv. Mater. 2011, 23, 2833.doi: 10.1016/S0378-7753(00)00485-7
5. [5]
  (3) Wu, Q.; Xu, Y.; Yao, Z.; Liu, A.; Shi, G. ACS Nano 2010, 4,1963. doi: 10.1021/nn1000035
6. [6]
  (4) Yang, X.; Zhu, J.; Qiu, L.; Li, D. Adv. Mater. 2011, 23, 2833.
7. [7]
  (5) Zhu, J. B.; Xu, Y. L.;Wang, J.;Wang, J. P. Acta Phys. -Chim.Sin. 2012, 28 (2), 373. [朱剑波, 徐友龙, 王杰, 王景平.物理化学学报, 2012, 28 (2), 373.] doi: 10.3866/PKU.WHXB201112021
8. [8]
  (6) Zhu, Y.; Murali, S.; Stoller, M. D.; Ganesh, K. J.; Cai,W.;Ferreira, P. J.; Pirkle, A.;Wallace, R. M.; Cychosz, K. A.;Thommes, M.; Su, D.; Stach, E. A.; Ruoff, R. S. Science 2011,332, 1537. doi: 10.1126/science.1200770
9. [9]
  (7) Yang, H. S.; Zhou, X.; Zhang, Q.W. Acta Phys. -Chim. Sin.2005, 21 (4), 414. [杨红生, 周啸, 张庆武. 物理化学学报,2005, 21 (4), 414.] doi: 10.3866/PKU.WHXB20050414
10. [10]
  (8) Evans, D. A. High Energy Density Electrolytic-ElectrochemicalHybrid Capacitor. http://www.evanscap.com/pdf/carts14.pdf." target=_blank>10.3866/PKU.WHXB201112021
11. [11]
  (6) Zhu, Y.; Murali, S.; Stoller, M. D.; Ganesh, K. J.; Cai,W.;Ferreira, P. J.; Pirkle, A.;Wallace, R. M.; Cychosz, K. A.;Thommes, M.; Su, D.; Stach, E. A.; Ruoff, R. S. Science 2011,332, 1537. doi: 10.1126/science.1200770
12. [12]
  (7) Yang, H. S.; Zhou, X.; Zhang, Q.W. Acta Phys. -Chim. Sin.2005, 21 (4), 414. [杨红生, 周啸, 张庆武. 物理化学学报,2005, 21 (4), 414.] doi: 10.3866/PKU.WHXB20050414
13. [13]
  (8) Evans, D. A. High Energy Density Electrolytic-ElectrochemicalHybrid Capacitor. http://www.evanscap.com/pdf/carts14.pdf.
14. [14]
  (9) Jun, Y.; Park, J. H.; Kang, M. G. Chem. Commun. 2012, 48,6456. doi: 10.1039/c2cc30733b
15. [15]
  (10) Wang, D. A.; Liu, Y.;Wang, C.W.; Zhou, F. Prog. Chem. 2010,22 (6), 1035. [王道爱, 刘盈, 王成伟, 周峰. 化学进展,2010, 22 (6), 1035.]doi: 10.1039/c2cc30733b
16. [16]
  (10) Wang, D. A.; Liu, Y.;Wang, C.W.; Zhou, F. Prog. Chem. 2010,22 (6), 1035. [王道爱, 刘盈, 王成伟, 周峰. 化学进展,2010, 22 (6), 1035.]
17. [17]
  (11) Zhu, X. F.; Han, H.; Song, Y.; Duan,W. Q. Acta Phys. -Chim.Sin. 2012, 28 (6), 1291. [朱绪飞, 韩华, 宋晔, 段文强.物理化学学报, 2012, 28 (6), 1291.] doi: 10.3866/PKU.WHXB201204093
18. [18]
  (12) Xie, K. Y.; Li, J.; Lai, Y. Q.; Zhang, Z. A.; Liu, Y. X.; Zhang, G.G.; Huang, H. T. Nanoscale 2011, 3, 2202. doi: 10.1039/c0nr00899k
19. [19]
  (13) Han, S. C.; Doh, J. M.; Yoon, J. K.; Kim, G. H.; Byun, J. Y.;Han, S. H.; Hong, K. T.; Kwun, S. I. Met. Mater. Int. 2009, 15 (3), 493. doi: 10.1007/s12540-009-0493-x
20. [20]
  (14) Yu, Q. Q.; Chu, C. L.; Lin, P. H.; Sheng, X. B.; Guo, C.; Dong,Y. S. Rare Metal Mat. Eng. 2011, 40 (Suppl.2), 201. [余青青,储成林, 林萍华, 盛晓波, 郭超, 董寅生. 稀有金属材料与工程, 2011, 40 (Suppl.2), 201.]" target=_blank>10.3866/PKU.WHXB201204093
21. [21]
  (12) Xie, K. Y.; Li, J.; Lai, Y. Q.; Zhang, Z. A.; Liu, Y. X.; Zhang, G.G.; Huang, H. T. Nanoscale 2011, 3, 2202. doi: 10.1039/c0nr00899k
22. [22]
  (13) Han, S. C.; Doh, J. M.; Yoon, J. K.; Kim, G. H.; Byun, J. Y.;Han, S. H.; Hong, K. T.; Kwun, S. I. Met. Mater. Int. 2009, 15 (3), 493. doi: 10.1007/s12540-009-0493-x
23. [23]
  (14) Yu, Q. Q.; Chu, C. L.; Lin, P. H.; Sheng, X. B.; Guo, C.; Dong,Y. S. Rare Metal Mat. Eng. 2011, 40 (Suppl.2), 201. [余青青,储成林, 林萍华, 盛晓波, 郭超, 董寅生. 稀有金属材料与工程, 2011, 40 (Suppl.2), 201.]
24. [24]
  (15) Ma, L.; Tang, Q. Journal of Chongqing University (NaturalScience Edition) 2002, 25 (2), 124. [马利, 汤琪. 重庆大学学报(自然科学版), 2002, 25 (2), 124.]
25. [25]
  (16) Prasad, K. R.; Munichandraiah, N. J. Power Sources 2002, 112,443.
26. [26]
  (17) Huang,W. S.; Humphrey, B. D.; MacDiarmid, A. G. J. Chem.Soc. Faraday Trans. I 1986, 82, 2385.
27. [27]
  (18) Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; vanSchalkwijk,W. Nat. Mater. 2005, 4, 366. doi: 10.1038/nmat1368
28. [28]
  (19) Cho, S. I.; Lee, S. B. Accounts Chem. Res. 2008, 41 (6), 699.doi: 10.1021/ar7002094
29. [29]
  (20) Zhang, Q. Q.; Li, Y.; Feng, Y. Y.; Feng,W. Electrochim. Acta2013, 90, 95. doi: 10.1016/j.electacta.2012.11.035
30. [30]
  (21) Tian, S. J.; Baba, A.; Liu, J. Y.;Wang, Z. H.; Knoll,W.; Park, M.K.; Advincula, R. Adv. Funct. Mater. 2003, 13, 473. doi: 10.1002/adfm.200304320
31. [31]
  (22) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. ActaPhys. -Chim. Sin. 2012, 28 (11), 2641. [仲皓想, 赵春宝,骆浩, 张灵志. 物理化学学报, 2012, 28 (11), 2641.]doi: 10.3866/PKU.WHXB201207181
32. [32]
  (23) Dhawale, D. S.; Vinub, A.; Lokhandea, C. D. Electrochim. Acta2011, 56, 9482. doi: 10.1016/j.electacta.2011.08.042
33. [33]
  (24) Pud, A. A. Synth. Met. 1994, 66, 1. doi: 10.1016/0379-6779(94)90155-4
34. [34]
  (25) Zhang, L. Y.; Yao, X. Dielectric Physics; Xi'an Jiao TongUniversity Press: Xi'an, 1991; pp 193-221. [张良莹, 姚熹.电介质物理. 西安: 西安交通大学出版社, 1991: 193-221.]" target=_blank>10.1038/nmat1368
35. [35]
  (19) Cho, S. I.; Lee, S. B. Accounts Chem. Res. 2008, 41 (6), 699.doi: 10.1021/ar7002094
36. [36]
  (20) Zhang, Q. Q.; Li, Y.; Feng, Y. Y.; Feng,W. Electrochim. Acta2013, 90, 95. doi: 10.1016/j.electacta.2012.11.035
37. [37]
  (21) Tian, S. J.; Baba, A.; Liu, J. Y.;Wang, Z. H.; Knoll,W.; Park, M.K.; Advincula, R. Adv. Funct. Mater. 2003, 13, 473. doi: 10.1002/adfm.200304320
38. [38]
  (22) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. ActaPhys. -Chim. Sin. 2012, 28 (11), 2641. [仲皓想, 赵春宝,骆浩, 张灵志. 物理化学学报, 2012, 28 (11), 2641.]doi: 10.3866/PKU.WHXB201207181
39. [39]
  (23) Dhawale, D. S.; Vinub, A.; Lokhandea, C. D. Electrochim. Acta2011, 56, 9482. doi: 10.1016/j.electacta.2011.08.042
40. [40]
  (24) Pud, A. A. Synth. Met. 1994, 66, 1. doi: 10.1016/0379-6779(94)90155-4
41. [41]
  (25) Zhang, L. Y.; Yao, X. Dielectric Physics; Xi'an Jiao TongUniversity Press: Xi'an, 1991; pp 193-221. [张良莹, 姚熹.电介质物理. 西安: 西安交通大学出版社, 1991: 193-221.]
42. [42]
  (26) Chang, T. Y.;Wang, X.; Evans, D. A.; Robinson, S. L.; Zheng, J.P. J. Power Sources 2002, 110, 138.
43. [43]
  (27) Sherrill, S. A.; Banerjee, P.; Rubloff, G.W.; Lee, S. B. Phys.Chem. Chem. Phys. 2011, 13, 20714.
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