Citation: CUI Ying, KUANG Yin-Jie, ZHANG Xiao-Hua, LIU Bo, CHEN Jin-Hua. Spontaneous Deposition of Pt Nanoparticles on Poly(diallyldimethylammonium chloride)/Carbon Nanotube Hybrids and Their Electrocatalytic Oxidation of Methanol[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 989-995. doi: 10.3866/PKU.WHXB201303121 shu

Spontaneous Deposition of Pt Nanoparticles on Poly(diallyldimethylammonium chloride)/Carbon Nanotube Hybrids and Their Electrocatalytic Oxidation of Methanol

1.
1 State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, P. R. China;
2 Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, School of Chemistry and Biological Engineering, Changsha University of Science & Technology, Changsha, 410114, P.R. China;
3 Xi’an Taijin Industrial Electrochemical Technology Co., Ltd, Northwest Institute For Non-ferrous Metal Research, Xi’an 710016, PR China

Received Date: 17 December 2012
Available Online: 12 March 2013
Fund Project: 国家自然科学基金(21275041, 21235002, 21221003) (21275041, 21235002, 21221003) 湖南省自然科学基金(12JJ2010) (12JJ2010)高等学校博士学科点专项科研基金(20110161110009)资助项目 (20110161110009)

Carbon nanotubes were non-covalently functionalized by poly(diallyldimethylammonium chloride) (PDDA). Here, PDDA has three roles: reductant for the metal precursor of PtCl₆^2-, stabilizer for in-situ produced Pt nanoparticles (Pt NPs), and anti-corrosion film for carbon nanotubes (CNTs). Surface-functionalization of CNTs with PDDA was characterized by Fourier transform infrared (FTIR) spectrometry, thermogravimetric analysis, and Raman spectroscopy. The results indicated that the surface of CNTs was successfully coated with PDDA film by π-π stacking interactions, and the functionalization process had no detrimental effect on the structure of the CNTs. The obtained catalyst (Pt NPs/ CNTs-PDDA) was characterized by transmission electron microscopy, and the results showed that Pt NPs with an average diameter of ca 2 nm were highly dispersed on the surface of CNTs-PDDA. The electrocatalytic properties of Pt NPs/CNTs-PDDA nanohybrids for methanol oxidation were further characterized by cyclic voltammetry and chronoamperometry. Compared with Pt NPs supported on the pristine CNTs, the Pt NPs/CNTs-PDDA catalyst had higher electrochemical surface area and specific mass activity, and better stability towards methanol electro-oxidation.
- Pt nanoparticle,
- Methanol,
- Electrocatalytic oxidation,
- PDDA,
- Carbon nanotube
1. [1]
  
  (1) (a) McGrath, K. M.; Prakash, G. K. S.; Olah, G. A. J. Ind. Eng.Chem. 2004, 10 (7), 1063.
2. [2]
  (b) Aricò, A. S.; Srinivasan, S.; Antonucci, V. Fuel Cells 2001, 1
3. [3]
  (2), 133.
4. [4]
  (c) Liu, H. S.; Song, C. J.; Zhang, L.; Zhang, J. J.;Wang, H. J.;Wilkinson, D. P. J. Power Sources 2006, 155 (2), 95.
5. [5]
  (2) (a) Colón-Mercado, H. R.; Kim, H.; Popov, B. N. Electrochem.Commun. 2004, 6 (8), 795. doi: 10.1016/j.elecom.2004.05.028
6. [6]
  (b) Liu, Z. L.; Ling, X. Y.; Su, X. D.; Lee, J. Y. J. Phys. Chem. B2004, 108 (24), 8234.
7. [7]
  (3) (a)Wang, J. J.; Yin, G. P.; Shao, Y. Y.; Zhang, S.;Wang, Z. B.;Gao, Y. Z. J. Power Sources 2007, 171 (2), 331. doi: 10.1016/j.jpowsour.2007.06.084
8. [8]
  (b) Rao, V.; Simonov, P. A.; Savinova, E. R.; Plaksin, G. V.;Cherepanova, S. V.; Kryukova, G. N.; Stimming, U. J. PowerSources 2005, 145 (2), 178.
9. [9]
  (c)Wang, Z. B.; Yin, G. P.; Shi, P. F. Carbon 2006, 44 (1), 133.
10. [10]
  (d) Zhao, Y.; E. Y.; Fan, L. Z.; Qiu, Y. F.; Yang, S. H.Electrochim. Acta 2007, 52 (19), 5873.
11. [11]
  (e) Xu, Q. J.; Zhou, X. J.; Li, Q. X. Acta Phys. -Chim. Sin. 2010,26 (8), 2135. [徐群杰, 周小金, 李巧霞, 李金光. 物理化学学报, 2010, 26 (8), 2135.] doi: 10.3866/PKU.WHXB20100802
12. [12]
  (4) Quinn, B. M.; Dekker, C.; Lemay, S. G. J. Am. Chem. Soc.2005, 127 (17), 6146. doi: 10.1021/ja0508828
13. [13]
  (5) (a) Hernadi, K.; Siska, A.; Thiên-Nga, L.; Forró, L.; Kiricsi, I.Solid State Ionics 2001, 141-142, 203.
14. [14]
  (b) Li, Y. L.; Hu, F. P.;Wang, X.; Shen, P. K. Electrochem.Commun. 2008, 10 (7), 1101.
15. [15]
  (c) Xu, H.; Zeng, L. P.; Xing, S. J.; Shi, G. Y.; Xian, Y. Z.; Jin,L. T. Electrochem. Commun. 2008, 10 (12), 1839.
16. [16]
  (6) (a)Wang, S. Y.; Jiang, S. P.;Wang, X. Nanotechnology 2008, 19 (26), 265601. doi: 10.1088/0957-4484/19/26/265601
17. [17]
  (b)Wang, S. Y.; Jiang, S. P.; White, T. J.; Guo, J.;Wang, X.J. Phys. Chem. C 2009, 113 (43), 18935.
18. [18]
  (c) Sanles-Sobrido, M.; Correa-Duarte, M. A.; Carregal-Romero, S.; Rodríguez- nzález, B.; Álvarez-Puebla, R. A.;Hervés, P.; Liz-Marzán, L. M. Chem. Mater. 2009, 21 (8), 1531.
19. [19]
  (7) Chen, J.;Wang, M.; Liu, B.; Fan, Z.; Cui, K.; Kuang, Y. J. Phys.Chem. B 2006, 110 (24), 11775.
20. [20]
  (8) (a) Shrestha, S.; Liu, Y.; Mustain,W. E. Catal. Rev. 2011, 53 (3),256. doi: 10.1080/01614940.2011.596430
21. [21]
  (b) Shao, Y.; Yin, G.; Gao, Y. J. Power Sources 2007, 171 (2),558.
22. [22]
  (9) Colmenares, L. C.;Wurth, A.; Jusys, Z.; Behm, R. J. J. PowerSources 2009, 190 (1), 14.
23. [23]
  (10) Zhang, S.; Shao, Y. Y.; Liao, H. G.; Engelhard, M. H.; Yin, G.P.; Lin, Y. H. ACS Nano 2011, 5 (3), 1785.
24. [24]
  (11) (a) He,W.; Zou, L. L.; Zhou, Y.; Lu, X. J.; Li, Y.; Zhang, X. G.;Yang, H. Chem. J. Chin. Univ. 2012, 33 (1), 133. [何卫, 邹亮亮, 周毅, 卢向军, 李媛, 张校刚, 杨辉. 高等学校化学学报, 2012, 33 (1), 133.]
25. [25]
  (b) He,W.; Jiang, H. J.; Zhou, Y.; Yang, S. D.; Xue, X. Z.; Zou,Z. Q.; Zhang, X. G.; Akins, D. L.; Yang, H. Carbon 2012, 50 (1), 265.
26. [26]
  (c) Shen, X. F.; Chen, Q.; Pang, Y. H.; Cui, Y.; Qian, H. Sci.China Chem. 2011, 41 (7), 1184. 沈晓芳, 陈沁, 庞月红,崔燕, 钱和. 中国科学: 化学, 2011, 41 (7), 1184.]
27. [27]
  (d) Qin, X.;Wang, H.;Wang, X.; Miao, Z.; Chen, L.; Zhao,W.;Shan, M.; Chen, Q. Sensors and Actuators B: Chemical 2010,147 (2), 593.
28. [28]
  (12) (a) Chakraborty, S.; Raj, C. R. Carbon 2010, 48 (11), 3242. doi: 10.1016/j.carbon.2010.05.014
29. [29]
  (b) Yang, D. Q.; Rochette, J. F.; Sacher, E. J. Phys. Chem. B2005, 109 (10), 4481.
30. [30]
  (13) Chen, H. J.;Wang, Y. L.;Wang, Y. Z.; Dong, S. J.;Wang, E.Polymer 2006, 47 (2), 763. doi: 10.1016/j.polymer.2005.11.034
31. [31]
  (14) Wang, S. Y.; Yu, D. S.; Dai, L. M. J. Am. Chem. Soc. 2011, 133 (14), 5182.
32. [32]
  (15) Hsin, Y. L.; Hwang, K. C.; Yeh, C. T. J. Am. Chem. Soc. 2007,129 (32), 9999.
33. [33]
  (16) Li, L.; Xing, Y. J. Electrochem. Soc. 2006, 153 (10), A1823.
34. [34]
  (17) (a)Wang, J.; Yin, G.; Shao, Y.;Wang, Z.; Gao, Y. J. PowerSources 2008, 176 (1), 128. doi: 10.1016/j.jpowsour.2007.10.057
35. [35]
  (b) Li, L.; Xing, Y. J. Power Sources 2008, 178 (1), 75.
36. [36]
  (18) Pozio, A.; De Francesco, M.; Cemmi, A.; Cardellini, F.; Giorgi,L. J. Power Sources 2002, 105 (1), 13.
37. [37]
  (19) (a) Leger, J. M.; Lamy, C. Berichte der Bunsengesellschaft fürPhysikalische Chemie 1990, 94 (9), 1021. doi: 10.1002/bbpc.v94:9
38. [38]
  (b) Hamnett, A. Catal. Today 1997, 38 (4), 445.
39. [39]
  (20) Zhang, S.; Shao, Y. Y.; Yin, G. P.; Lin, Y. H. J. Mater. Chem.2009, 19 (42), 7995. doi: 10.1039/b912104h
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
3. [3]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
5. [5]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
6. [6]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
7. [7]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
8. [8]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
9. [9]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
10. [10]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
11. [11]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
12. [12]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
13. [13]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
14. [14]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
15. [15]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
16. [16]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
17. [17]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
18. [18]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
19. [19]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
20. [20]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117

Get Citation

PDF

XML

Metrics

PDF Downloads(660)
Abstract views(1302)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142