Citation: TANG Lin, MA Xiao-Yan, SONG Ying, ZHOU Dong. Ordered Porous Films Prepared by the Breath Figure Method Based on Polystyrene-b-polyacrylonitrile[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1107-1114. doi: 10.3866/PKU.WHXB201303112 shu

Ordered Porous Films Prepared by the Breath Figure Method Based on Polystyrene-b-polyacrylonitrile

1.
Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education, Key Laboratory of Macromolecular Science & Technology of Shaanxi Province, School of Science, Northwestern Polytechnical University, Xi’an, P. R. China

Received Date: 18 January 2013
Available Online: 11 March 2013
Fund Project: 陕西省自然科学基金(2009JZ004) (2009JZ004) 西北工业大学基础研究基金(JC201158) (JC201158)西北工业大学研究生创业种子基金(Z2012157)资助项目 (Z2012157)

Ordered porous films were prepared by the breath figure method based on self-synthetic polystyrene-b-polyacrylonitrile (PS-b-PAN). Their morphologies were characterized by scanning electron microscopy. The influence of polymer concentration, solvent, and polymer structure on the structures of porous films was investigated. Film surfaces were covered with round hexa nally packed pores, and a honeycomb structure resided under film surfaces. With increasing polymer concentration in the chloroform (CHCl₃) solvent, pore spacing increased and the size of honeycomb structure decreased. Multilayer structures were observed at higher concentration. When better volatile carbon disulfide (CS₂) was instead used as the solvent, even highly ordered porous films were produced. Pore diameter and pore spacing increased, and the size of the honeycomb structure decreased. When the polystyrene macro-initiator (PS-Cl) without PAN blocks was adopted as the film material, nest-like structures instead of pores were formed on the film surface. The halo on the film surface suggests that when water droplets were positioned under the liquid film, defects formed on the film surface.
- Polystyrene,
- Block copolymer,
- Breath figure method,
- Porous film,
- Defect,
- Honeycomb structure
1. [1]
  
  (1) Xu, X. X.; Zhuang, J.;Wang, X. J. Am. Chem. Soc. 2008, 130,12527. doi: 10.1021/ja8040527
2. [2]
  (2) Chari, K.; Lander, C.W.; Sudol, R. J. Appl. Phys. Lett. 2008, 92,111916. doi: 10.1063/1.2901027
3. [3]
  (3) Nurmawati, M. H.; Ajikumar, P. K.; Renu, R.; Valiyaveettil, S.Adv. Funct. Mater. 2008, 18, 3213. doi: 10.1002/adfm.v18:20
4. [4]
  (4) Zhang, Y.;Wang, C. Adv. Mater. 2007, 19, 913.
5. [5]
  (5) Fukuhira, Y.; Kitazono, E.; Hayashi, T.; Kaneko, H.; Tanaka,M.; Shimomura, M.; Sumi, Y. Biomaterials 2006, 27, 1797.doi: 10.1016/j.biomaterials.2005.10.019
6. [6]
  (6) Vohra, V.; Yunus, S.; Attout, A.; Giovanella, U.; Scavia, G.;Tubino, R.; Botta, C.; Bolognesi, A. Soft Matter 2009, 5, 1656.doi: 10.1039/b819811j
7. [7]
  (7) Gugliuzza, A.; Aceto, M. C.; Macedonio, F.; Drioli, E. J. Phys.Chem. B 2008, 112, 10483. doi: 10.1021/jp802130u
8. [8]
  (8) Widawski, G.; Rawieso, M.; François, B. Nature 1994, 369,387. doi: 10.1038/369387a0
9. [9]
  (9) Hernández-Guerrero, M.; Stenzel, M. H. Polym. Chem. 2012, 3,563. doi: 10.1039/c1py00219h
10. [10]
  (10) Stenzel, M. H.; Barner-Kowollik, C.; Davis, T. P. J. Polym. Sci.Pol. Chem. 2006, 44, 2363.
11. [11]
  (11) Sharma,V.; Song, L.; Jones, R. L.; Barrow, M. S.;Williams, P.R.; Srinivasarao, M. Europhysics Letters 2010, 91, 38001. doi: 10.1209/0295-5075/91/38001
12. [12]
  (12) Dong,W. Y.; Zhou, Y. F.; Yan, D. Y.; Mai, Y. Y.; He, L.; Jin, C. Y.Langmuir 2009, 25, 173. doi: 10.1021/la802863m
13. [13]
  (13) Escalé, P.; Rubatat, L.; Billon, L.; Save, M. Eur. Polym. J. 2012,48, 1001. doi: 10.1016/j.eurpolymj.2012.03.001
14. [14]
  (14) Peng, J.; Han, Y. C.; Fu, J.; Yang, Y. M.; Li, B.Y. Macromol.Chem. Phys. 2003, 204, 125.
15. [15]
  (15) Ma, H. Y.; Tian, Y.;Wang, X. L. Polymer 2011, 52, 489. doi: 10.1016/j.polymer.2010.11.031
16. [16]
  (16) Pitois, O.; François, B. Eur. Phys. J. B 1999, 8, 225. doi: 10.1007/s100510050685
17. [17]
  (17) Srinivasarao, M.; Collings, D.; Philips, A.; Patel, S. Science2001, 292, 79. doi: 10.1126/science.1057887
18. [18]
  (18) Song, L.; Bly, R. K.;Wilson, J. N.; Bakbak, S.; Park, J. O.;Srinivasarao, M.; Bunz, U. H. F. Adv. Mater. 2004, 16, 115.doi: 10.1002/(ISSN)1521-4095
19. [19]
  (19) Wang, C. Y.; Mao, Y. D.;Wang, D. Y.; Qu, Q. S.; Yang, G. J.;Hu, X. Y. J. Mater. Chem. 2008, 18, 683. doi: 10.1039/b715520d
20. [20]
  (20) Heiko, U.; Bunz, F. Adv. Mater. 2006, 18, 973.
21. [21]
  (21) Li, J.; Zhao, Q. L.; Chen, J. Z.; Li, L.; Huang, J.; Ma, Z.; Zhong,Y.W. Polym. Chem. 2010, 1, 164. doi: 10.1039/b9py00219g
22. [22]
  (22) Li, L.; Zhong, Y.W.; ng, J. L.; Li, J.; Chen, C. K.; Zeng, B.R.; Ma, Z. Soft Matter 2011, 7, 546. doi: 10.1039/c0sm00809e
23. [23]
  (23) Hernández-Guerrero, M.; Davis, T. P.; Barner-Kowollik, C.;Stenzel, M. H. Eur. Polym. J. 2005, 41, 2264. doi: 10.1016/j.eurpolymj.2005.04.040
24. [24]
  (24) Peng, J.; Han, Y. C.; Yang, Y. M.; Li, B. Y. Polymer 2004, 45,447. doi: 10.1016/j.polymer.2003.11.019
25. [25]
  (25) Billon, L.; Manguian, M.; Pellerin, V.; Joubert, M.; Eterradossi,O.; Garay, H. Macromolecules 2009, 42, 345. doi: 10.1021/ma8020568
26. [26]
  (26) Cui, L.; Peng, J.; Ding, Y.; Li, X.; Han, Y. C. Polymer 2005, 46,5334. doi: 10.1016/j.polymer.2005.04.018
27. [27]
  (27) Tang, L.; Ma, X. Y.; Song, Y.; Yu, J. Colloid Polym. Sci. 2013,291, 893. doi: 10.1007/s00396-012-2806-8.
28. [28]
  (28) Wong, K. H.; Hernández-Guerrero, M.; Granville, A. M.; Davis,T. P.; Barner-Kowollik, C.; Stenzel, M. H. Journal of PorousMaterials 2006, 13, 213. doi: 10.1007/s10934-006-8007-4
29. [29]
  (29) de Boer, B.; Stalmach, U.; Nijland, H.; Hadziioannou, G. Adv.Mater. 2000, 12, 1581.
30. [30]
  (30) Zander, N. E.; Orlicki, J. A.; Karikari, A. S.; Long, T. E.;Rawlett, A. M. Chem. Mater. 2007, 19, 6145. doi: 10.1021/cm0715895
31. [31]
  (31) Yabu, H.; Takebayashi, M.; Tanaka, M.; Shimomura, M.Langmuir 2005, 21, 3235. doi: 10.1021/la050013w
32. [32]
  (32) Cheng, N. L. Solvents Handbook; Chemical Industry Press:Beijing, 2002; pp 200, 838. [程能林. 溶剂手册. 北京: 化学工业出版社, 2002: 200, 838.]
33. [33]
  (33) Li, L.; Zhong, Y.W.; Chen, C. K.; Li, J. Acta Phys. -Chim. Sin.2010, 26 (4), 1135. [李磊, 钟雅文, 陈财康, 李剑. 物理化学学报, 2010, 26 (4), 1135.] doi: 10.3866/PKU.WHXB20100424
1. [1]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
2. [2]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
3. [3]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
4. [4]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
5. [5]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
6. [6]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
7. [7]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
8. [8]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
11. [11]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
12. [12]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
15. [15]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
16. [16]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
17. [17]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
18. [18]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
19. [19]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
20. [20]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050

Get Citation

PDF

XML

Metrics

PDF Downloads(686)
Abstract views(863)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142