Citation: YAO Fang-Fang, WU Bao-Shan, ZHOU Li-Ping, GAO Jun-Hu, LI Ying, LI Yong-Wang. Effect of Alcohol Addition on Fischer-Tropsch Synthesis over Cobalt-Based Catalysts[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1063-1072. doi: 10.3866/PKU.WHXB201303072 shu

Effect of Alcohol Addition on Fischer-Tropsch Synthesis over Cobalt-Based Catalysts

YAO Fang-Fang ^1,2,3 ,
WU Bao-Shan ^1,3,4, ,
ZHOU Li-Ping ^3,4 ,
GAO Jun-Hu ^3,4 ,
LI Ying ^3,4 ,
LI Yong-Wang ^1,3,4

1.
1 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan 030001, P. R. China;
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3 National Engineering Laboratory for Coal Indirect Liquefaction, Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan 030001, P. R. China;
4 Synfuels China Co. Ltd., Taiyuan 030001, P. R. China

Received Date: 21 January 2013
Available Online: 7 March 2013
Fund Project: 国家重点基础研究发展计划(973) (2011CB201401) (973) (2011CB201401)中国科学院知识创新工程项目(KJCX2-YW-N41)资助 (KJCX2-YW-N41)

C_nH_2n+1OH (n=2, 3, 5, 6) primary alcohol activation, hydrogenation and its additional effects on the performance of the Fischer-Tropsch (FT) synthesis over a cobalt catalyst were investigated in a fixed bed micro-reactor. All products were analyzed using an on-line gas chromatography. The diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to investigate intermediates on the catalyst surface. In the presence of ar n or hydrogen, C_nH_2n+1OH underwent two main reactions: direct de-carbonylation to produce (CH₂)_n_-1 hydrocarbons, and dehydration to produce (CH₂)_n hydrocarbons. The addition of lower carbon number alcohol (ethanol or 1-propanol) into the FT synthesis reaction had no significant effect on the hydrocarbon product distribution. While co-feeding higher carbon number alcohol (1-pentanol or 1-hexanol) into the FT synthesis reaction, the selectivity to hydrocarbons with carbon numbers greater than or equal to n-1 increased markedly because of the additive?s chain initiation on the catalyst surface.
- Cobalt-based catalyst,
- Fischer-Tropsch synthesis,
- On-line analysis of all products,
- C₂-C₆ primary alcohols,
- Co-feeding experiment,
- Reaction mechanism
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