Citation: LIU Nian-Ping, SHEN Jun, GUAN Da-Yong, LIU Dong, ZHOU Xiao-Wei, LI Ya-Jie. Effect of Carbon Aerogel Activation on Electrode Lithium Insertion Performance[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 966-972. doi: 10.3866/PKU.WHXB201302281 shu

Effect of Carbon Aerogel Activation on Electrode Lithium Insertion Performance

1.
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, Institute of Physical Science and Engineering of Tongji University, Shanghai 200092, P. R. China

Received Date: 12 November 2012
Available Online: 28 February 2013
Fund Project: 国家自然科学基金(51072137, 50802064, 11074189) (51072137, 50802064, 11074189) 国家科技支撑计划重点项目(2009BAC62B02) (2009BAC62B02)上海科学技术委员会项目(11nm0501600)资助 (11nm0501600)

Carbon aerogels have received much recent attention as high-capacity insertion anodes for rechargeable lithium ion batteries. Carbon aerogels were synthesized from resorcinol-formaldehyde with a sodium carbonate catalyst via a sol-gel process, ambient drying, carbonization, and activation. Gaseous CO₂-activated carbon aerogels combined the advantages of amorphous and nanoporous structures, with richer porous structures and more lithium insertion points than conventional carbon aerogels. Microporosity analysis indicated a high surface area, and the pore volume effectively retained lithium and its compounds. The mesoporosity allowed the mass transport of Li+ and conferred high ionic conductivity to the electrode. These improvements led to a higher lithium insertion capacity, and the activated carbon aerogel exhibited a specific surface area of 2032 m²·g^-1. X-ray diffraction (XRD) and scanning electron microscopy (SEM) revealed an amorphous structure and nanoparticle network skeleton, respectively. Lithium insertion capacities of 3870 and 352 mAh·g^-1 were exhibited in the 1st and 50th galvanostatic discharge-charge (50 mA·g^-1) cycles, respectively. This corresponded to irreversible capacities of 658 and 333 mAh·g^-1, respectively. This work demonstrates the feasibility of CO₂ activation for improving lithium insertion performance in carbon aerogels, and provides preparation and optimization procedures for other porous electrode materials.
- Carbon aerogel,
- Sol-gel,
- Gas activation,
- Amorphous carbon,
- Lithium ion battery
1. [1]
  
  (1) Wild ose, G. G.; Leventis, H. C.; Simm, A. O.; Jones, J. H.;Compton, R. G. Chem. Commun. 2005, 3694.
2. [2]
  (2) Tamai, H.; Sumi, T.; Yasuda, H. J. Colloid Interface Sci. 1996,177, 325.
3. [3]
  (3) ng, Q.;Wang, H.; Liao, X. Z.; Ma,W.; He, Y. S.; Ma, Z. F.Acta Phys. -Chim. Sin. 2012, 28, 100. [龚强, 王红, 廖小珍, 麻微, 何雨石, 马紫峰. 物理化学学报, 2012, 28, 100.]doi: 10.3866/PKU.WHXB201228100
4. [4]
  (4) Ikeda, S.; Ishino, S.; Harada, T.; Okamoto, N.; Sakata, T.; Mori,H.; Kuwabata, S.; Torimoto, T.; Matsumura, M. Angew. Chem.Int. Edit. 2006, 45, 7063.
5. [5]
  (5) Pekala, R.W. J. Mater. Sci. 1989, 24, 3221. doi: 10.1007/BF01139044
6. [6]
  (6) Kim, H. J.; Kim, J. H.; Kim,W. I.; Suh, D. J. Korean J. Chem.Eng. 2005, 22, 740. doi: 10.1007/BF02705792
7. [7]
  (7) Mayer, S. T.; Pekala, R.W.; Kaschmitter, J. L. J. Electrochem.Soc. 1993, 140, 446. doi: 10.1149/1.2221066
8. [8]
  (8) Lu, X.; Caps, R.; Fricke, J.; Alviso, C. T.; Pekala, R.W.J. Non-Cryst. Solids 1995, 188, 226. doi: 10.1016/0022-3093(95)00191-3
9. [9]
  (9) Probstle, H.; Schmitt, C.; Frick, J. J. Power Sources 2002, 105,189. doi: 10.1016/S0378-7753(01)00938-7
10. [10]
  (10) Ping, L. N.; Zheng, J. M.; Shi, Z. Q.;Wang, C. Y. ActaPhys. -Chim. Sin. 2012, 28, 1733. [平丽娜, 郑嘉明, 时志强,王成扬. 物理化学学报, 2012, 28, 1733.] doi: 10.3866/PKU.WHXB201205092
11. [11]
  (11) Le, D. B.; Passerini, S.; Guo, J.; Ressler, J.; Owens, B. B.;Smyrl,W. H. J. Electrochem. Soc. 1996, 143, 2099. doi: 10.1149/1.1836965
12. [12]
  (12) Xu, K.; Shen, L. F.; Mi, C. H.; Zhang, X. G. Acta Phys. -Chim.Sin. 2012, 28, 105. [徐科, 申来法, 米常焕, 张校刚. 物理化学学报, 2012, 28, 105.] doi: 10.3866/PKU.WHXB201228105
13. [13]
  (13) Gao,W. C.; Huang, T.; Shen, Y. D.; Yu, A. S. Acta Phys. -Chim.Sin. 2011, 27, 2129. [高文超, 黄桃, 沈宇栋, 余爱水. 物理化学学报, 2011, 27, 2129.] doi: 10.3866/PKU.WHXB20110933
14. [14]
  (14) Slides, C. R.; Li, N. C.; Patrissi, C. J.; Scrosati, B.; Martin, C. R.MRS Bulletin 2002, 8, 604.
15. [15]
  (15) Zhang, D.W.; Zhao, Y. B.; odenough, J. B.; Lu, Y. H.; Chen,C. H.;Wang, L.; Liu, J.W. Electrochem. Commun. 2011, 13,125. doi: 10.1016/j.elecom.2010.11.031
16. [16]
  (16) Tanaike, O.; Aoike, S.; Ohno, H.; Hatori, H.; Yamada, Y.Materials Science and Engineering B 2008, 148, 237. doi: 10.1016/j.mseb.2007.09.001
17. [17]
  (17) Skowronski, J. M.; Knofczynski, K. J. Power Sources 2009,194, 81. doi: 10.1016/j.jpowsour.2009.04.048
18. [18]
  (18) Kunowsky, M.; Marco-Lozar, J. P.; Oya, A.; Linares-Solano, A.Carbon 2012, 50, 407.
19. [19]
  (19) Liu, H. Y.;Wang, K. P.; Teng, H. S. Carbon 2005, 43, 559. doi: 10.1016/j.carbon.2004.10.020
20. [20]
  (20) Liu, N. P.; Shen, J.; Liu, D. Microporous Mesoporous Mat.2013, 167, 176. doi: 10.1016/j.micromeso.2012.09.009
21. [21]
  (21) Pekala, R.W.; Farmer, J. C.; Alviso, C. T.; Tram, T. D.; Mayer,S. T.; Miller, J. M.; Dunn, B. J. Non-Cryst. Solids 1998, 225, 74.doi: 10.1016/S0022-3093(98)00011-8
22. [22]
  (22) Xu, J. J.; Yang, J. Electrochem. Commun. 2003, 5, 230. doi: 10.1016/S1388-2481(03)00024-9
23. [23]
  (23) Probstle, H.;Wiener, M.; Fricke, J. J. Porous Mater. 2003, 10,213. doi: 10.1023/B:JOPO.0000011381.74052.77
24. [24]
  (24) Wu, D. C.; Fu, R.W.; Zhang, S. T.; Dresselhaus, M. S.;Dresselhaus, G. Carbon 2004, 42, 2033. doi: 10.1016/j.carbon.2004.04.003
25. [25]
  (25) Wei, Y. Z.; Fang, B.; Iwasa, S.; Kumagai, M. J. Power Sources2005, 141, 386. doi: 10.1016/j.jpowsour.2004.10.001
26. [26]
  (26) Antonio, B.; Pico, F.; Rojo, J. M. J. Power Sources 2004, 133,329. doi: 10.1016/j.jpowsour.2004.02.013
27. [27]
  (27) Tarazona, P. Surf. Sci. 1995, 331, 989. doi: 10.1016/0039-6028(95)00170-0
28. [28]
  (28) Sing, K. S.W.; Everett, D. H.; Haul, R. A.W.; Moscou, L.;Pierotti, R. A.; Rouquerol, J.; Siemieniewska, T. Pure Appl.Chem. 1985, 57, 603. doi: 10.1351/pac198557040603
29. [29]
  (29) Bonino, F.; Brutti, S.; Piana, M.; Natale, S.; Scrosati, B.;Gherghel, L.; Mullen, K. Electrochim. Acta 2006, 51, 3407. doi: 10.1016/j.electacta.2005.09.036
30. [30]
  (30) Giraudet, J.; Dubois, M.; Inacio, J.; Hamwi, A. Carbon 2003,41, 453. doi: 10.1016/S0008-6223(02)00341-X
31. [31]
  (31) Besenhard, J. O.;Winter, M.; Yang, J.; Biberacher,W. J. PowerSources 1995, 54, 228. doi: 10.1016/0378-7753(94)02073-C
32. [32]
  (32) Aurbach, D.; Eineli, Y. J. Electrochem. Soc. 1995, 142, 1746.doi: 10.1149/1.2044188
33. [33]
  (33) Aurbach, D.; Markovsky, B.;Weissman, I.; Levi, E.; Ein-Eli, Y.Electrochim. Acta 1999, 45, 67. doi: 10.1016/S0013-4686(99)00194-2
34. [34]
  (34) Zoo, G. F.; Zhang, D.W.; Dong, C.; Li, H.; Xiong, K.; Fei, L.F.; Qian, Y. T. Carbon 2006, 44, 2277.
35. [35]
  (35) Wu, G. T.;Wang, C. S.; Zhang, X. B.; Yang, H. S.; Qi, Z. F.; He,P. M.; Li,W. Z. J. Electrochem. Soc. 1999, 5, 1696.
36. [36]
  (36) Zhao, J.; Gao, Q. Y.; Gu, C.; Yang, Y. Chem. Phys. Lett. 2002,358, 77. doi: 10.1016/S0009-2614(02)00580-8
37. [37]
  (37) Yang, Z. H.;Wu, H. Q. Solid State Ionics 2001, 143, 173. doi: 10.1016/S0167-2738(01)00852-9
38. [38]
  (38) Flandrois, S.; Simon, B. Carbon 1999, 37, 165. doi: 10.1016/S0008-6223(98)00290-5
39. [39]
  (39) Lee, H. Y.; Baek, J. K.; Jang, S.W. J. Power Sources 2001, 101,206. doi: 10.1016/S0378-7753(01)00671-1
1. [1]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
2. [2]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
6. [6]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
7. [7]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
8. [8]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
9. [9]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
10. [10]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
11. [11]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084
12. [12]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
13. [13]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
16. [16]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
17. [17]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
18. [18]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
19. [19]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
20. [20]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069

Get Citation

PDF

XML

Metrics

PDF Downloads(700)
Abstract views(992)
HTML views(43)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142