Citation: LUO Qian-Qian, ZHOU Shi-Dong, REN Yuan, Li Niu, HUANG Zhi-Peng, GUAN Nai-Jia, XIANG Shou-He. Phenomenon of Structural Transformation of Ethylenediamine- Oriented Synthesis of Microporous Cobalt Phosphate[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 911-919. doi: 10.3866/PKU.WHXB201302273 shu

Phenomenon of Structural Transformation of Ethylenediamine- Oriented Synthesis of Microporous Cobalt Phosphate

1.
Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Department of Materials Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 3 January 2013
Available Online: 27 February 2013
Fund Project: 天津市自然科学基金(12JCYBJC12700) (12JCYBJC12700)国家重大基础研究项目(973)(2009CB623502)资助 (973)(2009CB623502)

Microporous cobalt phosphate structures can be synthesized using ethylenediamine as a structure directing agent. During the syntheses of CoPO-en-1, CoPO-en-2, CoPO-en-3, and CoPO-en-4, it was found that they could interconvert during hydrothermal or calcination conditions. CoPO-en-2 and CoPO-en-4 are the crystallization intermediates of CoPO-en-1 and CoPO-en-3, respectively. During hydrothermal synthesis, CoPO-en-2 and CoPO-en-4 could be obtained at lower temperature or higher temperature during the initial crystallization stage. Extended synthesis time at higher temperature the two former structures transform into the two latter. CoPO-en-2, CoPO-en-3, and CoPO-en-4 could also convert to CoPO-en-1 during calcination, and these transformations indicated the sequence of structure stability. During synthesis under hydrothermal conditions, CoPO-en-2, CoPO-en-3, and CoPO-en-4 could convert to CoPO-en-1. During muffle furnace roasting, CoPO-en-2, CoPO-en-3, and CoPO-en-4 could also convert to CoPO-en-1. Different structures in the liquid or solid phases could be transformed into the same structure using different approaches.
- Cobalt phosphate,
- Ethylenediamine,
- Structural transformation,
- Hydrothermal synthesis,
- Calcination transformation
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