Citation: PEI Qi-Fei, HUA Yi-Xin, XU Cun-Ying, ZHANG Qi-Bo, LI Yan, RU Juan-Jian, NG Kai. Dissolution Process of an Aluminum Anode in Acidic AlCl₃-BMIC Ionic Liquid[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 946-952. doi: 10.3866/PKU.WHXB201302261 shu

Dissolution Process of an Aluminum Anode in Acidic AlCl₃-BMIC Ionic Liquid

1.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan Province, P. R. China

Received Date: 19 November 2012
Available Online: 26 February 2013
Fund Project: 国家自然科学基金(51204080, 51274108, 21263007) (51204080, 51274108, 21263007) 云南省自然科学基金(2011FA009) (2011FA009) 云南省应用基础研究基金(2011FZ020) (2011FZ020)昆明理工大学人才培养项目(14118441)资助 (14118441)

The dissolution process of an aluminum electrode in Lewis acidic ionic liquid aluminum chloride (AlCl₃)-1-butyl-3-methylimidazolium chloride (BMIC) was studied using linear sweep voltammetry. Passivation was observed upon anodic polarization of the aluminum electrode that was caused by formation of a solid AlCl₃ layer on the surface of the aluminum electrode. The electrochemical dissolution process of aluminum can be divided into electrochemically-controlled, transition, and passivation regimes. In the electrochemically-controlled regime, the dissolution rate of aluminum increased with increasing potential. In the transition regime, the dissolution rate of aluminum decreased as the potential increased because of the formation of solid AlCl₃ caused by changes in the concentration of AlCl₄^- and Al₂Cl₇^-. After a passivation layer formed, the dissolution rate of aluminum depended on the diffusion of AlCl₄^- was independent of potential; that is, the electrochemical dissolution process entered the passivation regime. The anodic limiting current density increased with agitation, increasing temperature, and decreasing mole fraction of AlCl₃ in the ionic liquid.
- Aluminum,
- Anodic dissolution,
- AlCl₃-BMIC ionic liquid,
- Passivation phenomenon,
- AlCl₃ layer
1. [1]
  
  (1) Kondo, M.; Maeda, H.; Mizuguchi, M. Journal of Metals 1990,42, 36.
2. [2]
  (2) Capuano, G. A.; Davenport,W. G. J. Electrochem. Soc. 1971,118, 1688. doi: 10.1149/1.2407813
3. [3]
  (3) Legrand, L.; Tranchant, A.; Messina, R. Electrochim. Acta 1994,39, 1427. doi: 10.1016/0013-4686(94)85054-2
4. [4]
  (4) Hess, I. J.; Betz, J. F. Metal Finish 1971, 69, 38.
5. [5]
  (5) Altgeld,W. Metalloberflache 1986, 40, 253.
6. [6]
  (6) Ziegel, S.; Peled, E.; Gileadi, E. Electrochim. Acta 1978, 23,363. doi: 10.1016/0013-4686(78)80075-9
7. [7]
  (7) Zein El Abedin, S.; Moustafa, E. M.; Hempelmann, R.; Natter,H.; Endres, F. Electrochem. Commun. 2005, 7, 1111. doi: 10.1016/j.elecom.2005.08.010
8. [8]
  (8) Vaughan, J.; Dreisinger, D. J. Electrochem. Soc. 2008, 155, D68.
9. [9]
  (9) Zein El Abedin, S.; Giridhar, P.; Schwab, P.; Endres, F.Electrochem. Commun. 2010, 12, 1084. doi: 10.1016/j.elecom.2010.05.034
10. [10]
  (10) Gao, L. X.;Wang, L. N.; Qi, T.; Li, Y. P.; Chu, J. L.; Qu, J. K.Acta Phys. -Chim. Sin. 2008, 24, 939. [高丽霞, 王丽娜,齐涛, 李玉平, 初景龙, 曲景奎. 物理化学学报, 2008, 24,939.] doi: 10.1016/S1872-1508(08)60040-6
11. [11]
  (11) Li, B.; Fan, C. H.; Chen, Y.; Lou, J.W.; Yan, L. G. Electrochim.Acta 2011, 56, 5478. doi: 10.1016/j.electacta.2011.03.047
12. [12]
  (12) Kamavaram, V.; Mantha, D.; Reddy, R. G. J. Min. Metall.B-Metall. 2003, 39, 43. doi: 10.2298/JMMB0302043K
13. [13]
  (13) Kamavaram, V.; Mantha, D.; Reddy, R. G. Electrochim. Acta2005, 50, 3286. doi: 10.1016/j.electacta.2004.12.002
14. [14]
  (14) Jiang, T.; Chollier Brym, M. J.; Dubé, G.; Lasia, A.; Brisard, G.M. Surf. Coat. Technol. 2007, 201, 6309. doi: 10.1016/j.surfcoat.2006.11.035
15. [15]
  (15) Pradhan, D.; Mantha, D.; Reddy, R. G. Electrochim. Acta 2009,54, 6661. doi: 10.1016/j.electacta.2009.06.059
16. [16]
  (16) Pei, Q. F.; Hua, Y. X.; Li, Y.; ng, K.;Wang, R.; Rao, S.; Li, P.Q. The Chinese Journal of Process Engineering 2012, 12, 247.[裴启飞, 华一新, 李艳, 龚凯, 汪瑞, 饶帅, 李丕强.过程工程学报, 2012, 12, 247.]
17. [17]
  (17) Tang, J.W.; Azumi, K. Electrochim. Acta 2011, 56, 1130. doi: 10.1016/j.electacta.2010.10.056
18. [18]
  (18) Koura, N.; Nagase, H.; Sato, A.; Kumakura, S.; Takeuchi, K.;Ui, K.; Tsuda, T.; Loong, C. K. J. Electrochem. Soc. 2008, 155,D155.
19. [19]
  (19) Perre, E.; Nyholm, L.; Gustafsson, T.; Taberna, P. L.; Simon, P.Electrochem. Commun. 2008, 10, 1467. doi: 10.1016/j.elecom.2008.07.032
20. [20]
  (20) Cammarata, L.; Kazarian, S. G.; Salterb, P. A.;Welton, T. Phys.Chem. Chem. Phys. 2001, 3, 5192. doi: 10.1039/b106900d
21. [21]
  (21) Lai, P. K.; Skyllas-Kazacos, M. Electrochim. Acta 1987, 32,1443. doi: 10.1016/0013-4686(87)85083-1
22. [22]
  (22) Melton, T. J.; Joyce, J.; Maloy, J. T.; Boon, J. A.;Wilkes, J. S.J. Electrochem. Soc. 1990, 137, 3865. doi: 10.1149/1.2086315
23. [23]
  (23) Liu, Q.; Liu, Q. R.; Han, Q.; Tu, G. F. Journal of NortheasternUniversity (Naturnal Science) 2010, 31, 1149. [柳泉, 刘奎仁, 韩庆, 涂赣峰. 东北大学学报(自然科学版), 2010, 31,1149.]
24. [24]
  (24) Hua, Y. X. Introduction to Kinetics of Processing Metallurgy;Metallurgical Industry Press: Beijing, 2004; pp 192-193.[华一新. 冶金过程动力学导论. 北京: 冶金工业出版社, 2004:192-193.]
25. [25]
  (25) Zheng, H. J.; Ma, C. A.;Wang,W.; Huang, J. G. Electrochem.Commum. 2006, 8, 977. doi: 10.1016/j.elecom.2006.03.039
26. [26]
  (26) Fannin, A. A., Jr.; Floreani, D. A.; King, L. A.; Landers, J. S.;Piersma, B. J.; Stech, D. J.; Vaughn, R. L.;Wilkes, J. S.;Williams, J. L. J. Phys. Chem. 1984, 88, 2614. doi: 10.1021/j150656a038
1. [1]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
2. [2]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
3. [3]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
4. [4]
  Qian Huang , Zhaowei Li , Jianing Zhao , Ao Yu . Quantum Chemical Calculations Reveal the Details Below the Experimental Phenomenon. University Chemistry, 2024, 39(3): 395-400. doi: 10.3866/PKU.DXHX202309018
5. [5]
  Yonghui Wang , Weilin Chen , Yangguang Li . Knowledge Construction of “Solubility of Inorganic Substances” in Elemental Chemistry Teaching. University Chemistry, 2024, 39(4): 261-267. doi: 10.3866/PKU.DXHX202312102
6. [6]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
7. [7]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
8. [8]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
9. [9]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
10. [10]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
11. [11]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
12. [12]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
13. [13]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
14. [14]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
15. [15]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
16. [16]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
17. [17]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
18. [18]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
19. [19]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
20. [20]
  . . University Chemistry, 2024, 39(3): 0-0.

Get Citation

PDF

XML

Metrics

PDF Downloads(790)
Abstract views(909)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dissolution Process of an Aluminum Anode in Acidic AlCl3-BMIC Ionic Liquid

Metrics

通讯作者: 陈斌, bchen63@163.com

Dissolution Process of an Aluminum Anode in Acidic AlCl₃-BMIC Ionic Liquid