Citation: ZHONG Bei-Jing, XIONG Peng-Fei, YANG Fan, YU Ya-Wei. Thermal and Chemical Effects of Hydrogen in Catalytic Ignition of n-Butane/Air Mixture[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 897-902. doi: 10.3866/PKU.WHXB201302252 shu

Thermal and Chemical Effects of Hydrogen in Catalytic Ignition of n-Butane/Air Mixture

1.
Scool of Aerospace, Tsinghua University, Beijing 100084, P. R. China

Received Date: 4 December 2012
Available Online: 25 February 2013
Fund Project: 国家自然科学基金(51276096)资助项目 (51276096)

The kinetics of the catalytic ignition processes of hydrogen/n-butane/air on Pt surface is studied to reveal the catalytic ignition mechanism. It is found that the ignition temperature of n-butane is lower when a certain amount of hydrogen is added. However, the effect of hydrogen on the catalytic ignition process and temperature of n-butane depends on the percentage of hydrogen added. When a small amount of hydrogen is added, it has a thermal effect. Adding more hydrogen gas causes it to have a chemical effect. A od fit is obtained between simulated and experimental data for the catalytic ignition temperatures. The ranges of hydrogen content with different effects are also predicted. Furthermore, this kinetic study shows that a different onset reaction of n-butane will lead to different ignition temperatures and mechanisms.
- C₄H₁₀/H₂/air mixture,
- Catalytic reaction mechanism,
- Catalytic ignition,
- Thermal effect and chemical effect,
- Platinum catalyst
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沈阳化工大学材料科学与工程学院沈阳 110142