Citation: CAI Feng, LIU Wei, FAN Xue-Hua, ZHANG Jing, LU Min-Xu. Electrochemical Corrosion Behavior of X70 Pipeline Steel in Turbulence Zone under Jet Impingement at High Temperature and High Pressure CO₂ Environment[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1003-1012. doi: 10.3866/PKU.WHXB201302251 shu

Electrochemical Corrosion Behavior of X70 Pipeline Steel in Turbulence Zone under Jet Impingement at High Temperature and High Pressure CO₂ Environment

CAI Feng ¹ ,
LIU Wei ^1, ,
FAN Xue-Hua ² ,
ZHANG Jing ¹ ,
LU Min-Xu ¹

1.
1 Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, P. R. China;
2 Beijing Branch of China Petroleum Engineering Co., Ltd., Beijing 100085, P. R. China

Received Date: 13 November 2012
Available Online: 25 February 2013
Fund Project: 国家重大科技专项经费(2008ZX05026-003-04)资助 (2008ZX05026-003-04)

The corrosion behavior of X70 pipeline steel in the turbulent zone was investigated in situ with a micro-electrode technique using loop jet impingement under high temperature and high pressure CO₂ environment. The morphology of the corrosion product formed on the surface and corrosion behavior of X70 steel after different periods were investigated by scanning electron microscopy and in situ electrochemical methods, respectively. The electrochemical behavior of X70 steel was closely related to the evolution of corrosion scales on the steel surface. The surface of the steel changed gradually from the presence of both substrate and corrosion product to loose, porous corrosion scales during the first 12 h. After 12 h, the corrosion scales were mainly composed of inner and outer scales. Because of the effect of high wall shear stress in the turbulent zone, the porous, less-protective outer scale was thinned and then removed from the steel surface. Consequently, the surface was increasingly covered by the compact inner scale, which decreases the corrosion rate of the steel considerably. Correspondingly, during the first 12 h, the corrosion potential E_corr and linear polarization resistance R_p of the sample decreased continuously. Meanwhile, electrochemical impedance spectroscopy (EIS) exhibited high- and medium-frequency capacitive loops and a low-frequency inductive loop. Analysis of EIS revealed that the resistance R_f of the corrosion film increased slowly and charge transfer resistance R_t decreased steadily, while the double-layer capacitance C_dl and corrosion film capacitance C_f decreased rapidly. After 12 h, the protectiveness of the corrosion scales improved with time, and thus the E_corr and R_p increased. As the inductive component weakened with time and finally disappeared at 48 h, EIS changed to double capacitive loops. The R_f, Rr, and C_dl increased quickly. Furthermore, the C_f stabilized.
- CO₂ corrosion,
- Turbulent zone,
- Corrosion electrochemistry,
- Corrosion morphology,
- X70 pipeline steel
1. [1]
  
  (1) Kermani, M. B.; Morshed, A. B. Corrosion 2003, 59, 659. doi: 10.5006/1.3277596
2. [2]
  (2) López, D. A.; Simison, S. N.; de Sánchez, S. R. Electrochim.Acta 2003, 48, 845. doi: 10.1016/S0013-4686(02)00776-4
3. [3]
  (3) Nesic, S.; Postlethwaite, J.; Olsen, S. Corrosion 1996, 52, 280.doi: 10.5006/1.3293640
4. [4]
  (4) Nesic, S. Corrosion Sci. 2007, 49, 4308. doi: 10.1016/j.corsci.2007.06.006
5. [5]
  (5) Song, F. M. Electrochim. Acta 2010, 55, 689. doi: 10.1016/j.electacta.2009.07.087
6. [6]
  (6) Zheng, Y. G.; Yao, Z. M.; Ke,W. Corrosion Science andProtection Technology 2000, 12, 36. [郑玉贵, 姚治铭,柯伟. 腐蚀科学与防护技术, 2000, 12, 36.]
7. [7]
  (7) Hu, X.; Neville, A. Wear 2009, 267, 2027. doi: 10.1016/j.wear.2009.07.023
8. [8]
  (8) Hussain, E. A. M.; Robinson, M. J. Corrosion Sci. 2007, 49,1737. doi: 10.1016/j.corsci.2006.08.023
9. [9]
  (9) Efird, K. D.;Wright, E. J.; Boros, J. A.; Hailey, T. G. Corrosion1993, 49, 992. doi: 10.5006/1.3316026
10. [10]
  (10) Dube, N. M.; Dube, A.; Veere wda, D. H.; Lyer, S. B. Wear2009, 267, 259. doi: 10.1016/j.wear.2009.02.013
11. [11]
  (11) Zhang, G. A.; Cheng, Y. F. Corrosion Sci. 2010, 52, 2716. doi: 10.1016/j.corsci.2010.04.029
12. [12]
  (12) Wu, X. Q.; Jing, H. M.; Zheng, Y. G.; Yao, Z. M.; Ke,W.Journal of Chinese Society for Corrosion and Protection 2002,22, 1. [吴欣强, 敬和民, 郑玉贵, 姚治铭, 柯伟. 中国腐蚀与防护学报, 2002, 22, 1.]
13. [13]
  (13) Wu, X. Q.; Jing, H. M.; Zheng, Y. G.; Yao, Z. M.; Ke,W. Wear2004, 256, 133. doi: 10.1016/S0043-1648(03)00370-3
14. [14]
  (14) Tahara, A.; Shinohara, T. Corrosion Sci. 2005, 47, 2589. doi: 10.1016/j.corsci.2004.10.019
15. [15]
  (15) Hu, B.; Peng, L. M.; Ding,W. J. Tribology 2010, 30, 537.[胡斌, 彭立明, 丁文江. 摩擦学学报, 2010, 30, 537.]
16. [16]
  (16) Zhang, G. A.; Lu, M. X.;Wu, Y. S. Chinese Journal ofMaterials Research 2005, 19, 537. [张国安, 路民旭, 吴荫顺.材料研究学报, 2005, 19, 537.]
17. [17]
  (17) Gao, M.; Pang, X.; Gao, K. Corrosion Sci. 2011, 53, 557. doi: 10.1016/j.corsci.2010.09.060
18. [18]
  (18) Heitz, E. Corrosion 1991, 47, 135. doi: 10.5006/1.3585229
19. [19]
  (19) Poulson, B.; Robinson, R. Corrosion Sci. 1986, 26, 265. doi: 10.1016/0010-938X(86)90048-X
20. [20]
  (20) Poulson, B. Corrosion Sci. 1993, 35, 655. doi: 10.1016/0010-938X(93)90201-Q
21. [21]
  (21) Starn, M.; Geary, A. L. J. Electrochem. Soc. 1957, 104, 56.
22. [22]
  (22) Xu, L. Y.; Cheng, Y. F. Corrosion Sci. 2009, 51, 2330. doi: 10.1016/j.corsci.2009.06.005
23. [23]
  (23) Zou, Y.;Wang, J.; Zheng, Y. Y. Acta Phys. -Chim. Sin. 2010, 26,2361. [邹妍, 王佳, 郑莹莹. 物理化学学报, 2010, 26,2361.] doi: 10.3866/PKU.WHXB20100825
24. [24]
  (24) Miranda, E.; Bethencourt, M.; Botana, F. J.; Cano, M. J.;Sánchez-Amaya, J. M.; Corzo, A.; Carcía de Lomas, J.;Faradean, M. L.; Ollivier, B. Corrosion Sci. 2006, 48, 2417.doi: 10.1016/j.corsci.2005.09.005
25. [25]
  (25) Liu,W.; Zhao, Y. L.; Lu, M. X. Acta Phys. -Chim. Sin. 2008, 24,393. [柳伟, 赵艳亮, 路民旭. 物理化学学报, 2008, 24,393.] doi: 10.3866/PKU.WHXB20080307
1. [1]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
2. [2]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
3. [3]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
4. [4]
  Shuyong Zhang , Shu'e Song . Ideological and Political Case Design of Experiment of Corrosion and Protection Linking with National Major Projects. University Chemistry, 2024, 39(2): 57-60. doi: 10.3866/PKU.DXHX202304078
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
8. [8]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
9. [9]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
10. [10]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
11. [11]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
12. [12]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
13. [13]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
14. [14]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
15. [15]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
16. [16]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
17. [17]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
18. [18]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
19. [19]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
20. [20]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

Get Citation

PDF

XML

Metrics

PDF Downloads(614)
Abstract views(787)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Corrosion Behavior of X70 Pipeline Steel in Turbulence Zone under Jet Impingement at High Temperature and High Pressure CO2 Environment

Metrics

通讯作者: 陈斌, bchen63@163.com

Electrochemical Corrosion Behavior of X70 Pipeline Steel in Turbulence Zone under Jet Impingement at High Temperature and High Pressure CO₂ Environment