Citation: CHEN Hong-Li, DING Jian, WANG Yi-Meng. Synthesis of Hierarchical M -Containing Silicalite-1 Zeolites with High Hydrothermal Stability[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1035-1040. doi: 10.3866/PKU.WHXB201302223 shu

Synthesis of Hierarchical M -Containing Silicalite-1 Zeolites with High Hydrothermal Stability

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China

Received Date: 15 November 2012
Available Online: 22 February 2013
Fund Project: 国家自然科学基金(20890124) (20890124)国家科技支撑计划(2012BAE05B02)资助 (2012BAE05B02)

Hierarchical M /silicalite-1 composites were synthesized via hydrothermal treatment of M -supported porous silica using tetrapropylammonium hydroxide (TPAOH) as a template. M species were introduced into porous silica via solid-state grinding and subsequent calcination. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM) results indicated that M was uniformly distributed in the zeolite crystals. The hydrothermal stability of M / silicalite-1 before and after acid washing was detected by treatment at 800℃ in 100% steam for 10 h. The introduction of M increased the hydrothermal stability of M /silicalite-1 samples. Furthermore, acid washing could remove M impurities, increasing the relative crystallinity of samples compared with that of calcined M /silicalite-1 and introducing mesopore into zeolite simultaneously. N₂ adsorption-desorption measurements indicated that mesopores were generated in the zeolite crystals by the removal of M species. The improved hydrothermal stability and the generation of mesopores in these M /silicalite-1 samples play important roles in preserving zeolite structure, enhancing coke tolerance, slowing deactivation, and extending catalyst life during high-temperature reaction.
- M ,
- Zeolite,
- Hydrothermal stability,
- Hierarchical porosity
1. [1]
  
  (1) Quann, R. J.; Green, L. A.; Tabak, S. A.; Krambeck, F. J.Industrial & Engineering Chemistry Research 1988, 27, 565.doi: 10.1021/ie00076a006
2. [2]
  (2) Yamamura, M.; Chaki, K.;Wakatsuki, T.; Okado, H.; Fujimoto,K. Zeolites 1994, 14, 643. doi: 10.1016/0144-2449(94)90121-X
3. [3]
  (3) Jiang, N.; Jin, H.; Jeong, E. Y.; Park, S. E. Journal ofNanoscience and Nanotechnology 2010, 10, 227. doi: 10.1166/jnn.2010.1513
4. [4]
  (4) Asencios, Y. J. O.; Bellido, J. D. A.; Assaf, E. M. AppliedCatalysis A: General 2011, 397, 138. doi: 10.1016/j.apcata.2011.02.023
5. [5]
  (5) Li, X. L.; Yue, B. H.;Wang, X. G.; Yan, Y. F.; Kong, L. H.; Lu,X. G.; Ding,W. Z. Acta Physico-Chimica Sinica 2009, 25, 762.[李雪玲, 岳宝华, 汪学广, 鄢于飞, 孔令华, 鲁雄刚, 丁伟中.物理化学学报, 2009, 25, 762.] doi: 10.3866/PKU.WHXB200904231
6. [6]
  (6) Huber, G.W.; Guymon, C. G.; Conrad, T. L.; Stephenson, B. C.;Bartholomew, C. H. Stud. Surf. Sci. Catal. 2001, 139, 423. doi: 10.1016/S0167-2991(01)80226-3
7. [7]
  (7) Chen, N. Y.; Mitchell, T. O.; Olson, D. H.; Pelrine, B. P. Ind.Eng. Chem., Prod. Res. Dev. 1977, 16, 247.
8. [8]
  (8) Finnerty, C. M.; Coe, N. J.; Cunningham, R. H.; Ormerod, R.M. Catal. Today 1998, 46, 137. doi: 10.1016/S0920-5861(98)00335-6
9. [9]
  (9) Beyne, A. O. E.; Froment, G. F. Chem. Eng. Sci. 1993, 48, 503.doi: 10.1016/0009-2509(93)80304-9
10. [10]
  (10) Beyne, A. O. E.; Froment, G. F. Chem. Eng. Sci. 1990, 45, 2089.doi: 10.1016/0009-2509(90)80081-O
11. [11]
  (11) Chen, D.; Rebo, H. P.; Moljord, K.; Holmen, A. Industrial &Engineering Chemistry Research 1997, 36, 3473. doi: 10.1021/ie9700223
12. [12]
  (12) Triantafyllopoulos, N. C.; Neophytides, S. G. J. Catal. 2003,217, 324.
13. [13]
  (13) Trimm, D. L. Catal. Today 1999, 49, 3. doi: 10.1016/S0920-5861(98)00401-5
14. [14]
  (14) Voskoboynikov, T. V.; Pelekh, A. Y.; Senetar, J. J. OCP Catalystwith Improved Steam Tolerance. US Patent 12/639, 577. X,2011-06-16.
15. [15]
  (15) Choi, M.; Na, K.; Kim, J.; Sakamoto, Y.; Terasaki, O.; Ryoo, R.Nature 2009, 461, 246.
16. [16]
  (16) Verboekend, D.; Groen, J. C.; Pérez-Ramírez, J. Adv. Funct.Mater. 2010, 20, 1441. doi: 10.1002/adfm.200902205
17. [17]
  (17) Chen, L.; Zhu, S. Y.;Wang, H. M.;Wang, Y. M. Solid StateSciences 2011, 13, 2024. doi: 10.1016/j.solidstatesciences.2011.08.033
18. [18]
  (18) Chen, L.; Zhu, S. Y.;Wang, Y. M.; He, M. Y. New J. Chem.2010, 34, 2328. doi: 10.1039/c0nj00316f
19. [19]
  (19) Itoh, H.; Hattori, T.; Suzuki, K.; Murakami, Y. J. Catal. 1983,79, 21. doi: 10.1016/0021-9517(83)90286-5
20. [20]
  (20) Hathaway, P. E.; Davis, M. E. J. Catal. 1989, 119, 497. doi: 10.1016/0021-9517(89)90177-2
21. [21]
  (21) Wieland,W. S.; Davis, R. J.; Garces, J. M. J. Catal. 1998, 173,490. doi: 10.1006/jcat.1997.1952
22. [22]
  (22) Hunger, M.; Schenk, U.;Weitkamp, J. J. Mol. Catal. A: Chem.1998, 134, 97. doi: 10.1016/S1381-1169(98)00026-0
23. [23]
  (23) Yue, B. H.; Kong, L. H.;Wang, X. G.; Lu, X. G.; Ding,W. Z.Chinese Jounal of Catalysis 2010, 31, 218. [岳宝华, 孔令华,汪学广, 鲁雄刚, 丁伟中. 催化学报, 2010, 31, 218.]
24. [24]
  (24) Mao, D. S.; Guo, Q. S.; Meng, T. Acta Physico-Chimica Sinica2010, 26, 2242. [毛东森, 郭强胜, 孟涛. 物理化学学报,2010, 26, 2242.] doi: 10.3866/PKU.WHXB20100814
25. [25]
  (25) Zhang, F.; Miao, C. X.; Yue, Y. H.; Hua,W. M.; Gao, Z. Chin. J.Chem. 2012, 30, 929. [张帆, 缪长喜, 乐英红, 华伟明,高滋. 中国化学, 2012, 30, 929.] doi: 10.1002/cjoc.201100379
26. [26]
  (26) Wang, Y. M.;Wu, Z. Y.; Zhu, J. H. J. Solid State Chem. 2004,177, 3815. doi: 10.1016/j.jssc.2004.07.013
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