Citation: LI Shang, CHEN Rui-Xin, ZHAO Wei, QIAN Liu, PAN Mu, . Catalytic Performance of Heat-Treated Fe-Melamine/C and Fe-g-C₃N₄/C Electrocatalysts for Oxygen Reduction Reaction[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201302221 shu

Catalytic Performance of Heat-Treated Fe-Melamine/C and Fe-g-C₃N₄/C Electrocatalysts for Oxygen Reduction Reaction

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China

Corresponding author: ,
Received Date: 15 October 2012
Available Online: 22 February 2013
Fund Project: 湖北省自然科学基金项目(2012FFB05106) (2012FFB05106)国家重点基础研究发展计划项目(973) (2012CB215504)资助 (973) (2012CB215504)

Melamine and its polymer (g-C₃N₄) were used as ligands to prepare Fe-N/C electrocatalysts for the oxygen reduction reaction (ORR) by an impregnation method. The composition, morphology and electrocatalytic activity of the catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and electrochemical measurements. The Fe-N/C catalyst using g-C₃N₄ as a complex ligand showed higher activity in the ORR than that with melamine. The formation of quaternary N active sites on the surface of the catalyst during heat treatment helps to improve their performance in the ORR.
- Melamine,
- Non-noble metal electrocatalyst,
- Oxygen reduction reaction,
- Graphitic N,
- Proton exchange membrane fuel cell
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Performance of Heat-Treated Fe-Melamine/C and Fe-g-C3N4/C Electrocatalysts for Oxygen Reduction Reaction

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通讯作者: 陈斌, bchen63@163.com

Catalytic Performance of Heat-Treated Fe-Melamine/C and Fe-g-C₃N₄/C Electrocatalysts for Oxygen Reduction Reaction