Citation: ZHAO Jian, ZHOU Wei, XU Jun-Ke, MA Jian-Xin. Effect of Pretreatment Routes on the Performance and Structure of Ni-Co Bimetallic Catalysts[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201301315 shu

Effect of Pretreatment Routes on the Performance and Structure of Ni-Co Bimetallic Catalysts

ZHAO Jian ^1,2 ,
ZHOU Wei ^2,3, ,
XU Jun-Ke ^2,4 ,
MA Jian-Xin ^1,2,3

1.
1 School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China;
2 Clean Energy Automotive Engineering Center, Tongji University, Shanghai 201804, P. R. China;
3 School of Automotive Studies, Tongji University, Shanghai 201804, P. R. China;
4 Shanghai Baoshan Environmental Monitoring Station, Shanghai 201901, P. R. China

Received Date: 4 December 2012
Available Online: 31 January 2013
Fund Project: 科技部国际合作项目先进储氢技术研发及系统示范(2010DFA64080)资助 (2010DFA64080)

Ni-Co/La₂O₃-γ-Al₂O₃ catalysts for biogas reforming were prepared by conventional incipient wetness impregnation and pretreated first by hydrogen reduction and then by pure carbon monoxide, methane and carbon dioxide, respectively. The effect of pretreatment route on the biogas reforming performance of the catalysts was investigated. The catalysts were characterized with X-ray diffraction (XRD), thermogravimetric and differential scanning calorimetry (TG-DSC), and transmission electron microscopy (TEM), and the relationship between the performance and the structural properties of the catalysts was investigated. The results indicated that, compared with the performance of catalysts pretreated by the traditional hydrogen reduction, the performance of catalysts pretreated by hydrogen and carbon monoxide did not change significantly, while the performance of catalysts pretreated by hydrogen and methane deteriorated obviously. Nevertheless, the performance of catalysts pretreated by hydrogen and carbon dioxide was dramatically enhanced and the long adjustment period of the biogas reforming catalysts was basically eliminated. The characterization results showed that the active metal particle size of the catalysts pretreated by hydrogen and carbon dioxide was smaller on average and distributed more evenly and much more narrowly, which notably enhanced the catalysts' carbon resistance and prolonged the catalysts' longevity.
- Pretreatment,
- Ni-Co,
- Bimetallic catalyst,
- Biogas reforming,
- Hydrogen production,
- Adjustment period
1. [1]
  
  (1) Xu, J. K.; Shen, L. H.; Zhou, W.; Ma, J. X. Acta Phys. -Chim.Sin. 2011, 27 (3), 697. [徐军科,沈利红,周伟,马建新. 物理化学学报, 2011, 27 (3), 697.] doi: 10.3866/PKU.WHXB20110309
2. [2]
  (2) Feng, Y. Z.; u, Y.; Yang, G. H.; Qin, X. W.; Song, Z. L.Renew. Sust. Energ. Rev. 2012, 16 (8), 5617.
3. [3]
  (3) Li, C. L.; Fu, Y. L.; Bian, G. Z. Acta Phys. -Chim. Sin. 2003, 19 (10), 902. [李春林, 伏义路, 卞国柱. 物理化学学报, 2003, 19 (10), 902.] doi: 10.3866/PKU.WHXB20031004
4. [4]
  (4) Meshkani, F.; Rezaei, M. J. Nat. Gas. Chem. 2011, 20, 198.doi: 10.1016/S1003-9953(10)60169-7
5. [5]
  (5) Corthals, S.; Nederkassel, J. V.; Winne, H. D.; Geboers, J.;Jacobs, P.; Sels, B. Appl. Catal. B-Environ. 2011, 105, 263. doi: 10.1016/j.apcatb.2011.04.008
6. [6]
  (6) Tao, X. M.; Bai, M. G.; Li, X.; Long, H. L.; Shang, S. Y.; Yin, Y.X.; Dai, X. Y. Prog. Energ. Combust. Sci. 2011, 37, 113. doi: 10.1016/j.pecs.2010.05.001
7. [7]
  (7) Yu, C. C.; Ding, X. J. Chin. J. Mol. Catal. 1993, 7, 151. [余长春,丁雪加. 分子催化, 1993, 7, 151.]
8. [8]
  (8) Sun, X. X.; Li, X. M.; Li, J. H.; Fan, Y. M.; Xu, H. Y.; Su, Y.;Shi, K. Y.; Xu, G. L. Chem. J. Chin. Univ. 1992, 10, 1302.[孙希贤,李新民, 李建华,范业梅,徐恒泳,苏玉,史克英,徐国林. 高等学校化学学报, 1992, 10, 1302.]
9. [9]
  (9) Ni, J.; Chenb, L. W.; Lin, J. Y.; Kawi, S. Nano Energ. 2012, 1 (5), 674. doi: 10.1016/j.nanoen.2012.07.011
10. [10]
  (10) Xu, J. K.; Li, Z. J.; Wang, J. H.; Zhou, W.; Ma, J. X. ActaPhys. -Chim. Sin. 2009, 25 (2), 253. [徐军科,李兆静, 汪吉辉,周伟,马建新.物理化学学报, 2009, 25 (2), 253.] doi: 10.3866/PKU.WHXB20090210
11. [11]
  (11) Yu, X. P.; Wang, N.; Chu, W.; Liu, M. Chem. Eng. J. 2012, 209,623.
12. [12]
  (12) Lv, X. Y.; Chen, J. F.; Tan, Y. S.; Zhang, Y. Catal. Commun.2012, 20, 6. doi: 10.1016/j.catcom.2012.01.002
13. [13]
  (13) Chen, J. X.; Qiu, Y. J.; Zhang, J. Y.; Su, W. H. Acta Phys. -Chim.Sin. 2004, 20 (1), 76. [陈吉祥, 邱业君,张继炎, 苏万华.物理化学学报, 2004, 20 (1), 76.] doi: 10.3866/PKU.WHXB20040116
14. [14]
  (14) Husserl, J. J.; Velen, J. P. V. M. J.; Koser, R. Activation Route ofCatalysts for Fischer Tropsch Synthesis. CN Patent 10 1796166A, 2010-08-04. [胡塞尔·J·J, 扬塞梵维伦·M·J,科泽·R.费-托催化剂的活化方法: 中国, CN101796166A[P].2010-08-04.]
15. [15]
  (15) Green, M. L. H.; Xiao, T. C. Activation Route for CobaltCompound Based and Carried Catalysts. CN Patent 1541139A,2004-01-27. [马尔科姆·莱斯利·候德·格林, 肖天存. 含有钴化合物和载体的催化剂的活化方法:中国, CN1541139A[P].2004-01-27.]
16. [16]
  (16) Xu, J. K.; Ren, K. W.; Wang, X. L.; Zhou, W.; Pan, X. M.; Ma,J. X. Acta Phys. -Chim. Sin. 2008, 24 (9), 1568. [徐军科, 任克威,王晓蕾,周伟,潘相敏,马建新. 物理化学学报, 2008, 24 (9), 1568.] doi: 10.3866/PKU.WHXB20080907
17. [17]
  (17) Benito, M.; García, S.; Ferreira-Aparicio, P.; Serrano, L. G.;Daza, L. J. Power Sources 2007, 169 (1), 177. doi: 10.1016/j.jpowsour.2007.01.046
18. [18]
  (18) Xu, J. K.; Li, Z. J.; Wang, J. H.; Zhou, W.; Ma, J. X. Int. J.Hydrog. Energy 2010, 35 (23), 13013.
19. [19]
  (19) Tomishige, K.; Chen, Y. G.; Fujimoto, K. J. Catal. 1999, 181,91. doi: 10.1006/jcat.1998.2286
20. [20]
  (20) Solymosi, F. J. Mol. Catal. 1991, 65 (3), 337. doi: 10.1016/0304-5102(91)85070-I
21. [21]
  (21) Damyanova, S.; Bueno, J. M. C. Appl. Catal. A 2003, 253 (1),135. doi: 10.1016/S0926-860X(03)00500-3
22. [22]
  (22) Nagaoka, K.; Seshan, K.; Aika, K.; Lercher, J. A. J. Catal. 2001,197, 34. doi: 10.1006/jcat.2000.3062
1. [1]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240085
2. [2]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240102
3. [3]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406020
4. [4]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240028
5. [5]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309002
6. [6]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202404012
7. [7]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240371
8. [8]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240409
9. [9]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202407020
10. [10]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)₂₇团簇用于硝酸盐电还原制氨：一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202403008
11. [11]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202312014
12. [12]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202312010
13. [13]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, doi: 10.3866/PKU.DXHX202312046
14. [14]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, doi: 10.12461/PKU.DXHX202403044
15. [15]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230421
16. [16]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240037
17. [17]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240201
18. [18]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240386
19. [19]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230454
20. [20]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230276

Get Citation

PDF

XML

Metrics

PDF Downloads(666)
Abstract views(843)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142