Citation: ZHAO Jian, ZHOU Wei, XU Jun-Ke, MA Jian-Xin. Effect of Pretreatment Routes on the Performance and Structure of Ni-Co Bimetallic Catalysts[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201301315 shu

Effect of Pretreatment Routes on the Performance and Structure of Ni-Co Bimetallic Catalysts

ZHAO Jian ^1,2 ,
ZHOU Wei ^2,3, ,
XU Jun-Ke ^2,4 ,
MA Jian-Xin ^1,2,3

1.
1 School of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China;
2 Clean Energy Automotive Engineering Center, Tongji University, Shanghai 201804, P. R. China;
3 School of Automotive Studies, Tongji University, Shanghai 201804, P. R. China;
4 Shanghai Baoshan Environmental Monitoring Station, Shanghai 201901, P. R. China

Received Date: 4 December 2012
Available Online: 31 January 2013
Fund Project: 科技部国际合作项目先进储氢技术研发及系统示范(2010DFA64080)资助 (2010DFA64080)

Ni-Co/La₂O₃-γ-Al₂O₃ catalysts for biogas reforming were prepared by conventional incipient wetness impregnation and pretreated first by hydrogen reduction and then by pure carbon monoxide, methane and carbon dioxide, respectively. The effect of pretreatment route on the biogas reforming performance of the catalysts was investigated. The catalysts were characterized with X-ray diffraction (XRD), thermogravimetric and differential scanning calorimetry (TG-DSC), and transmission electron microscopy (TEM), and the relationship between the performance and the structural properties of the catalysts was investigated. The results indicated that, compared with the performance of catalysts pretreated by the traditional hydrogen reduction, the performance of catalysts pretreated by hydrogen and carbon monoxide did not change significantly, while the performance of catalysts pretreated by hydrogen and methane deteriorated obviously. Nevertheless, the performance of catalysts pretreated by hydrogen and carbon dioxide was dramatically enhanced and the long adjustment period of the biogas reforming catalysts was basically eliminated. The characterization results showed that the active metal particle size of the catalysts pretreated by hydrogen and carbon dioxide was smaller on average and distributed more evenly and much more narrowly, which notably enhanced the catalysts' carbon resistance and prolonged the catalysts' longevity.
- Pretreatment,
- Ni-Co,
- Bimetallic catalyst,
- Biogas reforming,
- Hydrogen production,
- Adjustment period
1. [1]
  
  (1) Xu, J. K.; Shen, L. H.; Zhou, W.; Ma, J. X. Acta Phys. -Chim.Sin. 2011, 27 (3), 697. [徐军科,沈利红,周伟,马建新. 物理化学学报, 2011, 27 (3), 697.] doi: 10.3866/PKU.WHXB20110309
2. [2]
  (2) Feng, Y. Z.; u, Y.; Yang, G. H.; Qin, X. W.; Song, Z. L.Renew. Sust. Energ. Rev. 2012, 16 (8), 5617.
3. [3]
  (3) Li, C. L.; Fu, Y. L.; Bian, G. Z. Acta Phys. -Chim. Sin. 2003, 19 (10), 902. [李春林, 伏义路, 卞国柱. 物理化学学报, 2003, 19 (10), 902.] doi: 10.3866/PKU.WHXB20031004
4. [4]
  (4) Meshkani, F.; Rezaei, M. J. Nat. Gas. Chem. 2011, 20, 198.doi: 10.1016/S1003-9953(10)60169-7
5. [5]
  (5) Corthals, S.; Nederkassel, J. V.; Winne, H. D.; Geboers, J.;Jacobs, P.; Sels, B. Appl. Catal. B-Environ. 2011, 105, 263. doi: 10.1016/j.apcatb.2011.04.008
6. [6]
  (6) Tao, X. M.; Bai, M. G.; Li, X.; Long, H. L.; Shang, S. Y.; Yin, Y.X.; Dai, X. Y. Prog. Energ. Combust. Sci. 2011, 37, 113. doi: 10.1016/j.pecs.2010.05.001
7. [7]
  (7) Yu, C. C.; Ding, X. J. Chin. J. Mol. Catal. 1993, 7, 151. [余长春,丁雪加. 分子催化, 1993, 7, 151.]
8. [8]
  (8) Sun, X. X.; Li, X. M.; Li, J. H.; Fan, Y. M.; Xu, H. Y.; Su, Y.;Shi, K. Y.; Xu, G. L. Chem. J. Chin. Univ. 1992, 10, 1302.[孙希贤,李新民, 李建华,范业梅,徐恒泳,苏玉,史克英,徐国林. 高等学校化学学报, 1992, 10, 1302.]
9. [9]
  (9) Ni, J.; Chenb, L. W.; Lin, J. Y.; Kawi, S. Nano Energ. 2012, 1 (5), 674. doi: 10.1016/j.nanoen.2012.07.011
10. [10]
  (10) Xu, J. K.; Li, Z. J.; Wang, J. H.; Zhou, W.; Ma, J. X. ActaPhys. -Chim. Sin. 2009, 25 (2), 253. [徐军科,李兆静, 汪吉辉,周伟,马建新.物理化学学报, 2009, 25 (2), 253.] doi: 10.3866/PKU.WHXB20090210
11. [11]
  (11) Yu, X. P.; Wang, N.; Chu, W.; Liu, M. Chem. Eng. J. 2012, 209,623.
12. [12]
  (12) Lv, X. Y.; Chen, J. F.; Tan, Y. S.; Zhang, Y. Catal. Commun.2012, 20, 6. doi: 10.1016/j.catcom.2012.01.002
13. [13]
  (13) Chen, J. X.; Qiu, Y. J.; Zhang, J. Y.; Su, W. H. Acta Phys. -Chim.Sin. 2004, 20 (1), 76. [陈吉祥, 邱业君,张继炎, 苏万华.物理化学学报, 2004, 20 (1), 76.] doi: 10.3866/PKU.WHXB20040116
14. [14]
  (14) Husserl, J. J.; Velen, J. P. V. M. J.; Koser, R. Activation Route ofCatalysts for Fischer Tropsch Synthesis. CN Patent 10 1796166A, 2010-08-04. [胡塞尔·J·J, 扬塞梵维伦·M·J,科泽·R.费-托催化剂的活化方法: 中国, CN101796166A[P].2010-08-04.]
15. [15]
  (15) Green, M. L. H.; Xiao, T. C. Activation Route for CobaltCompound Based and Carried Catalysts. CN Patent 1541139A,2004-01-27. [马尔科姆·莱斯利·候德·格林, 肖天存. 含有钴化合物和载体的催化剂的活化方法:中国, CN1541139A[P].2004-01-27.]
16. [16]
  (16) Xu, J. K.; Ren, K. W.; Wang, X. L.; Zhou, W.; Pan, X. M.; Ma,J. X. Acta Phys. -Chim. Sin. 2008, 24 (9), 1568. [徐军科, 任克威,王晓蕾,周伟,潘相敏,马建新. 物理化学学报, 2008, 24 (9), 1568.] doi: 10.3866/PKU.WHXB20080907
17. [17]
  (17) Benito, M.; García, S.; Ferreira-Aparicio, P.; Serrano, L. G.;Daza, L. J. Power Sources 2007, 169 (1), 177. doi: 10.1016/j.jpowsour.2007.01.046
18. [18]
  (18) Xu, J. K.; Li, Z. J.; Wang, J. H.; Zhou, W.; Ma, J. X. Int. J.Hydrog. Energy 2010, 35 (23), 13013.
19. [19]
  (19) Tomishige, K.; Chen, Y. G.; Fujimoto, K. J. Catal. 1999, 181,91. doi: 10.1006/jcat.1998.2286
20. [20]
  (20) Solymosi, F. J. Mol. Catal. 1991, 65 (3), 337. doi: 10.1016/0304-5102(91)85070-I
21. [21]
  (21) Damyanova, S.; Bueno, J. M. C. Appl. Catal. A 2003, 253 (1),135. doi: 10.1016/S0926-860X(03)00500-3
22. [22]
  (22) Nagaoka, K.; Seshan, K.; Aika, K.; Lercher, J. A. J. Catal. 2001,197, 34. doi: 10.1006/jcat.2000.3062
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