Citation: YUAN Rui, LI Ying, FANG Hong-Bo, WANG Wei. Relationship between Molecular Configuration and Phase Behavior of Partially Hydrolyzed Hydrophobically Modified Polyacrylamide[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201301313 shu

Relationship between Molecular Configuration and Phase Behavior of Partially Hydrolyzed Hydrophobically Modified Polyacrylamide

YUAN Rui ¹ ,
LI Ying ^1, ,
FANG Hong-Bo ² ,
WANG Wei ²

1.
1 Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China;
2 Design Institute, Shengli Oilfield, Dongying 257015, Shandong Province, P. R. China

Received Date: 26 October 2012
Available Online: 31 January 2013
Fund Project: 国家自然科学基金(21173134) (21173134)国家科技重大专项(2008ZX05011-002)资助项目 (2008ZX05011-002)

The relationship between the molecular configuration and bulk behavior of partially hydrolyzed hydrophobically modified polyacrylamide (HMHPAM) in aqueous solution was studied via dissipative particle dynamics (DPD) simulation. The influence of the polymer concentration, polymerization process, degree of hydrolysis, and the hydrophobic modified group of HMHPAM on the polymer solution, especially the extent of expansion of the polymer and the viscosity of the polymer solution, were investigated quantitatively by calculating the root-mean-square (RMS) end-to-end distance of the polymer and the water molecule diffusivity. The influencing mechanisms of the type and the arrangement of the repeating unit of the polymer chains on the HMHPAM solution properties were studied to direct the practical synthesis, modification, and application of the polymer.
1. [1]
  
  (1) Sabhapondit, A.; Borthakur, A.; Haque, I. Energy Fuels 2003,17, 683. doi: 10.1021/ef010253t
2. [2]
  (2) Li, Y.; Shao, M. G.; Horton, R. Procedia EnvironmentalSciences 2011, 11, 763. doi: 10.1016/j.proenv.2011.12.118
3. [3]
  (3) Sojika, R. E.; Entry, J. A. Environ. Pollut. 2000, 108, 405. doi: 10.1016/S0269-7491(99)00194-3
4. [4]
  (4) Zhao, X. F.; Liu, L. X.;Wang, Y. C.; Dai, H. X.;Wang, D.; Cai,H. Sep. Purif. Technol. 2008, 62, 199. doi: 10.1016/j.seppur.2008.01.019
5. [5]
  (5) Zong, H.;Wang, L.; Fang, H. B.; Mao, L. T.;Wang, Y. H.;Zhang, L.; Zhao, S.; Yu, J. Y. Acta Phys. -Chim. Sin. 2010, 26,2982. [宗华, 王磊, 方洪波, 毛雷霆, 王宇慧, 张路,赵濉, 俞稼镛. 物理化学学报, 2010, 26, 2982.] doi: 10.3866/PKU.WHXB20101105
6. [6]
  (6) Klaveness, T. M.; Ruoff, P. J. Phys. Chem. 1994, 98, 10119. doi: 10.1021/j100091a029
7. [7]
  (7) Branham, K. D.; Scott Snowden, H.; McCormick, C. L.Macromolecules 1996, 29, 254. doi: 10.1021/ma950794f
8. [8]
  (8) Peng, S. F.;Wu, C. Macromolecules 1999, 32, 585. doi: 10.1021/ma9809031
9. [9]
  (9) Cao, X. R.; Xu, G. Y.; Li, Y. M.; Zhang, Z. Q. J. Phys. Chem. A2005, 109, 10418. doi: 10.1021/jp053636r
10. [10]
  (10) Pang, J. Y.; Lü, X.; Zhang, J.; Yuan, S. L.; Xu, G. Y. ActaPhys. -Chim. Sin. 2011, 27, 520. [庞瑾瑜, 吕鑫, 张健,苑世领, 徐桂英. 物理化学学报, 2011, 27, 520.] doi: 10.3866/PKU.WHXB20110328
11. [11]
  (11) Yuan, S. L.;Wu, R.; Cai, Z. T. Acta Phys. -Chim. Sin. 2004, 20,811. [苑世领, 吴锐, 蔡政亭. 物理化学学报, 2004, 20,811.] doi: 10.3866/PKU.WHXB20040806
12. [12]
  (12) Yuan, S. L.; Xu, G. Y.; Cai, Z. T. China Surfactant Detergent &Cosmetics 2002, 32, 1. [苑世领, 徐桂英, 蔡政亭. 日用化学工业, 2002, 32, 1.]
13. [13]
  (13) Guo, X. D.; Zhang, L. J.;Wu, Z. M.; Qian, Y. Macromolecules2010, 43, 7839. doi: 10.1021/ma101132n
14. [14]
  (14) Rekvig, L.; Kranenburg, M.; Vreede, J.; Hafskjold, B.; Smit, B.Langmuir 2003, 19, 8195. doi: 10.1021/la0346346
15. [15]
  (15) Hoogerbrugge, P. J.; Koelman, J. M. V. A. Europhys. Lett. 1992,19, 155. doi: 10.1209/0295-5075/19/3/001
16. [16]
  (16) Ginzburg, V. V.; Chang, K.; Jog, P. K.; Argenton, A. B.; Rakesh,L. J. Phys. Chem. B 2011, 115, 4654. doi: 10.1021/jp109234u
17. [17]
  (17) Zhu, P. F.; Li, Y.; Li, Q.W.; Song, X.W.; Cao, X. L.; Li, Z. Q.Acta Chim. Sin. 2011, 69, 2420. [朱鹏飞, 李英, 李全伟, 宋新旺, 曹绪龙, 李振泉. 化学学报, 2011, 69, 2420.]
18. [18]
  (18) Li, Y.; He, X. J.; Cao, X. L.; Zhao, G. Q.; Tian, X. X.; Cui, X.H. J. Colloid Interface Sci. 2007, 307, 215. doi: 10.1016/j.jcis.2006.11.026
19. [19]
  (19) Wu, H.; Xu, J. B.; He, X. F.; Zhao, Y. H.;Wen, H. Colloids andSurfaces A: Physicochem. Eng. Aspects 2006, 290, 239. doi: 10.1016/j.colsurfa.2006.05.029
20. [20]
  (20) Li, Y. M.; Zhang, H. X.; Bao, M. T.;Wang, Z. N. Comput.Mater. Sci. 2012, 63, 154. doi: 10.1016/j.commatsci.2012.06.007
21. [21]
  (21) Fang, Y.; Lai, Z. Y.; Pang, P. P.; Jiang, M. Acta Phys. -Chim. Sin.2011, 27, 1712. [方云, 赖中宇, 庞萍萍, 江明. 物理化学学报, 2011, 27, 1712.] doi: 10.3866/PKU.WHXB20110703
22. [22]
  (22) Chen, H.; Han, L. J.; Xu, P.; Luo, P. Y. Acta Phys. -Chim. Sin.2003, 19, 1020. [陈洪, 韩利娟, 徐鹏, 罗平亚. 物理化学学报, 2003, 19, 1020.] doi: 10.3866/PKU.WHXB20031107
23. [23]
  (23) Li, Y. M.; Guo, Y. Y.; Bao, M. T.; Gao, X. L. J. Colloid InterfaceSci. 2011, 361, 573. doi: 10.1016/j.jcis.2011.05.078
24. [24]
  (24) Feng, Y. J.; Billon, L.; Grassl, B.; Khoukh, A.; Francois, J.Polymer 2002, 43, 2055. doi: 10.1016/S0032-3861(01)00774-1
25. [25]
  (25) Dobrynin, A. V. Curr. Opin. Colloid Interface Sci. 2008, 13,376. doi: 10.1016/j.cocis.2008.03.006
26. [26]
  (26) Zhao, F.; Du, Y. K.; Li, X. C.; Tang, J. A.; Yang, P. ActaPhys. -Chim. Sin. 2004, 20, 1385. [赵丰, 杜玉扣, 李兴长,唐季安, 杨平. 物理化学学报, 2004, 20, 1385.] doi: 10.3866/PKU.WHXB20041120
27. [27]
  (27) Soppimath, K. S.; Kulkarni, A. R.; Aminabhavi, T. M.J. Controlled Release 2001, 75, 311.
1. [1]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, doi: 10.3866/PKU.DXHX202310029
2. [2]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, doi: 10.3866/PKU.DXHX202311093
3. [3]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, doi: 10.3866/PKU.DXHX202308044
4. [4]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, doi: 10.3866/PKU.DXHX202309052
5. [5]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, doi: 10.12461/PKU.DXHX202403048
6. [6]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, doi: 10.3866/PKU.DXHX202309074
7. [7]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, doi: 10.3866/PKU.DXHX202309053
8. [8]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, doi: 10.3866/PKU.DXHX202309063
9. [9]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, doi: 10.3866/PKU.DXHX202401074
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240189
11. [11]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202403028
12. [12]
  Yong Shu , Xing Chen , Sai Duan , Rongzhen Liao . How to Determine the Equilibrium Bond Distance of Homonuclear Diatomic Molecules: A Case Study of H₂. University Chemistry, doi: 10.3866/PKU.DXHX202310102
13. [13]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406027
14. [14]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, doi: 10.3866/PKU.DXHX202310126
15. [15]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230169
16. [16]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, doi: 10.3866/PKU.DXHX202302060
17. [17]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, doi: 10.3866/PKU.DXHX202310050
18. [18]
  Wenbing Hu , Jin Zhu . Flipped Classroom Approach in Teaching Professional English Reading and Writing to Polymer Graduates. University Chemistry, doi: 10.3866/PKU.DXHX202310015
19. [19]
  Jia Yao , Xiaogang Peng . Theory of Macroscopic Molecular Systems: Theoretical Framework of the Physical Chemistry Course in the Chemistry “101 Plan”. University Chemistry, doi: 10.12461/PKU.DXHX202408117
20. [20]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, doi: 10.3866/PKU.DXHX202311094

Get Citation

PDF

XML

Metrics

PDF Downloads(781)
Abstract views(921)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142