Citation: LI Jin-Bing, JIANG Zhi-Quan, HUANG Wei-Xin. Adsorption and Decomposition of NO2 on Ag/Pt(110) Bimetallic Surface[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201301241
-
The adsorption and decomposition of NO2 on Ag/Pt(110) bimetallic surfaces have been investigated by Auger electron spectroscopy (AES) and thermal desorption spectroscopy (TDS). At room temperature, NO2 under es dissociative chemisorption on Ag/Pt(110) bimetallic surfaces, forming chemisorbed NO(ads) and O(ads). Upon heating, NO(ads) under es both desorption from the surface and further decomposition. At 500 K, NO2 chemisorbs dissociatively on Ag/Pt(110) bimetallic surfaces, forming O(ads). Electron transfer occurs from Pt to Ag, therefore, the presence of Ag on Pt(110) surface weakens the binding energy of O(ads) with the surface and decreases the temperature required for the recombinative desorption of O(ads) from the surface. We observed the formation of a Ag/Pt(110) alloy structure that exhibits catalytic activity towards NO2 decomposition similar to that of Pt(110)-(1×2) but with a binding energy towards O(ads) much lower than that of Pt(110)-(1×2). Such a Ag/Pt(110) alloy structure may be active in catalyzing the direct decomposition of NOx at relatively low temperatures.
-
-
[1]
(1) Garin, F. Appl. Catal. A 2001, 222 (1-2), 183. doi: 10.1016/S0926-860X(01)00827-4
-
[2]
(2) Zhdanov, V. P.; Kasemo, B. Surf. Sci. Rep. 1997, 29 (2), 31.doi: 10.1016/S0167-5729(97)00009-5
-
[3]
(3) Permana, H.; Ng, K. Y. S.; Peden, C. H. F.; Schmieg, S. J.;Lambert, D. K.; Belton, D. N. J. Catal. 1996, 164 (1), 194.doi: 10.1006/jcat.1996.0375
-
[4]
(4) Nakamura, I.; Fujitani, T.; Hamada, H. Surf. Sci. 2002, 514 (1-3), 409. doi: 10.1016/S0039-6028(02)01660-6
-
[5]
(5) Brown,W. A.; King, D. A. J. Phys. Chem. B 2000, 104 (12),2578. doi: 10.1021/jp9930907
-
[6]
(6) Ge, Q.; Neurock, M. J. Am. Chem. Soc. 2004, 126 (5), 1551.doi: 10.1021/ja036575o
-
[7]
(7) Bartram, M. E.;Windham, R. G.; Koel, B. E. Langmuir 1988, 4 (2), 240. doi: 10.1021/la00080a001
-
[8]
(8) Bartram, M. E.;Windham, R. G.; Koel, B. E. Surf. Sci. 1987,184 (1-2), 57. doi: 10.1016/S0039-6028(87)80272-8
-
[9]
(9) Huang,W. X.; White, J. M. Surf. Sci. 2003, 529, 455. doi: 10.1016/S0039-6028(03)00332-7
-
[10]
(10) Schwalke, U.; Niehus, H.; Comsa, G. Surf. Sci. 1985, 152-153,596.
-
[11]
(11) Parker, D. H.; Bartram, M. E.; Koel, B. E. Surf. Sci. 1989, 217 (3), 489. doi: 10.1016/0039-6028(89)90443-3
-
[12]
(12) Devarajan, S. P.; Hinojosa, J. A.;Weaver, J. F. Surf. Sci. 2008,602 (19), 3116. doi: 10.1016/j.susc.2008.08.008
-
[13]
(13) Huang,W. X.; Jiang, Z. Q.; Jiao, J.; Tan, D. L.; Zhai, R. S.; Bao,X. H. Surf. Sci. 2002, 506 (3), L287.
-
[14]
(14) Jiang, Z. Q.; Huang,W. X.; Tan, D. L.; Zhai, R. S.; Bao, X. H.Surf. Sci. 2006, 600 (21), 4860. doi: 10.1016/j.susc.2006.08.007
-
[15]
(15) Li, J. B.; Huang,W. X.; Jiang, Z. Q.; Bao, X. H. Chin. J. Catal.2006, 27 (1), 65. [李金兵, 黄伟新, 姜志全, 包信和. 催化学报, 2006, 27 (1), 65.]
-
[16]
(16) Sasaki, M.; Hamada, H.; Kintaichi, Y.; Ito, T. Catal. Lett. 1992,15 (3), 297. doi: 10.1007/BF00765274
-
[17]
(17) Iwamoto, M.; Zengyo, T.; Hernandez, A. M.; Araki, H. Appl.Catal. B 1998, 17 (3), 259. doi: 10.1016/S0926-3373(98)00018-6
-
[18]
(18) Iwamoto, M.; Yahiro, H. Catal. Today 1994, 22 (1), 5.doi: 10.1016/0920-5861(94)80089-8
-
[19]
(19) Amirnazmi, A.; Benson, J. E.; Boudart, M. J. Catal. 1973, 30 (1), 55. doi: 10.1016/0021-9517(73)90051-1
-
[20]
(20) Iwamoto, M.; Yahiro, H.; Shundo, S.; Yoshihiro, Y.; Mizuno, N.Appl. Catal. 1991, 69 (2), L15.
-
[21]
(21) Hamada, H.; Kintaichi, Y.; Sasaki, M.; Ito, T. Chem. Lett. 1990,19 (7), 1069.
-
[22]
(22) Wu, R. J.; Chou, T. Y.; Yeh, C. T. Appl. Catal. B 1995, 6 (2),105. doi: 10.1016/0926-3373(95)00005-4
-
[23]
(23) Huang,W. X.; Jiang, Z. Q.; Tan, D. L.; Zhai, R. S.; Bao, X. H.Surf. Sci. 2001, 478 (1-2), L345.
-
[24]
(24) Huang,W. X.; Jiang, Z. Q.; Dong, F.; Bao, X. H. Surf. Sci. 2002,514 (1-3), 420. doi: 10.1016/S0039-6028(02)01662-X
-
[25]
(25) Li, J. B.; Jiang, Z. Q.; Huang,W. X. Chin. J. Chem. Phys. 2011,24 (6), 735. doi: 10.1088/1674-0068/24/06/735-740
-
[26]
(26) rte, R. J.; Gland, J. L. Surf. Sci. 1981, 102 (2-3), 348.doi: 10.1016/0039-6028(81)90034-0
-
[27]
(27) Wilf, M.; Dawson, P. T. Surf. Sci. 1977, 65 (2), 399.doi: 10.1016/0039-6028(77)90456-3
-
[28]
(28) Imbihl, R.; Sander, M.; Ertl, G. Surf. Sci. 1988, 204 (1-2), L701.
-
[29]
(29) Rodriguez, J. A.; Kuhn, M. J. Phys. Chem. 1994, 98 (44),11251. doi: 10.1021/j100095a004
-
[30]
(30) Härtel, T.; Strüber, U.; Küppers, J. Thin Solid Films 1993, 229 (2), 163. doi: 10.1016/0040-6090(93)90359-W
-
[1]
-
-
[1]
Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, doi: 10.3866/PKU.DXHX202311102
-
[2]
Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202309005
-
[3]
Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240014
-
[4]
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240067
-
[5]
Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230346
-
[6]
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240149
-
[7]
Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO2 Conversion. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406029
-
[8]
Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr2O72−: A Physical Chemistry Innovation Experiment. University Chemistry, doi: 10.3866/PKU.DXHX202401008
-
[9]
Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230385
-
[10]
Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230374
-
[11]
Shuang Meng , Haixin Long , Zhou Zhou , Meizhu Rong . Inorganic Chemistry Curriculum Design and Implementation of Based on “Stepped-Task Driven + Multi-Dimensional Output” Model: A Case Study on Intermolecular Forces. University Chemistry, doi: 10.3866/PKU.DXHX202309008
-
[12]
Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O2的理论计算研究. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202407013
-
[13]
Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS2惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406024
-
[14]
Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH2 Lewis Basicity in CTF-NH2 through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202405005
-
[15]
Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240061
-
[16]
Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, doi: 10.3866/PKU.DXHX202312013
-
[17]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230369
-
[18]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240043
-
[19]
Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202407005
-
[20]
Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, doi: 10.3866/PKU.DXHX202401056
-
[1]
Metrics
- PDF Downloads(667)
- Abstract views(874)
- HTML views(19)