Citation: XU Jing, ZHU Yong-Fa. Elimination of Bisphenol A from Water via Graphene Oxide Adsorption[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201301211 shu

Elimination of Bisphenol A from Water via Graphene Oxide Adsorption

XU Jing ¹ ,
ZHU Yong-Fa ^1,2,

1.
1 Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China;
2 Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science and Technology, Nanjing 210044, P.R. China

Received Date: 31 October 2012
Available Online: 21 January 2013
Fund Project: 国家重点基础研究发展计划(973) (2013CB632403) (973) (2013CB632403) 国家高技术研究发展计划(863) (2012AA062701) (863) (2012AA062701) 科技部创新方法工作专项(2009IM030500) (2009IM030500)江苏省大气环境监测与污染控制高技术研究重点实验室开放基金(AEMPC201103)资助项目 (AEMPC201103)

The elimination of bisphenol A (BPA) from aqueous solution by adsorption on graphene oxide ( ) was investigated. The maximum adsorption capacity (q_m) of for BPA estimated from the Langmuir isotherm was 87.80 mg·g^-1 at 25℃. The required contact time to reach adsorption equilibrium was about 30 min, which was much shorter than that of activated carbon. The adsorption kinetics and isotherm data fitted well with the pseudo-second-order kinetic model and the Langmuir isotherm, respectively. Neutral pH and low solution temperature were favorable for adsorption, whereas the presence of NaCl in the solution was unfavorable. The had od recyclability and could be reused several times with a slight decline in adsorption ability. Both hydrogen bonding and π-π interaction were thought to be responsible for the adsorption of BPA on . The excellent adsorption capacity and high adsorption rate of result from its sheet-like structure and the abundant oxygen-containing groups on its surface. Although q_m of for BPA is lower than that of graphene, has the benefits of large scale production, a hydrophilic surface with plenty of oxygen-containing groups, and od dispersion in water. Therefore, can be regarded as a od potential adsorbent for water treatment.
- Adsorption,
- Graphene oxide,
- Bisphenol A,
- Endocrine-disrupting chemicals,
- Water treatment
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