Citation: ZHAO Feng-Qi, ZHANG Heng, AN Ting, ZHANG Xiao-Hong, YI Jian-Hua, XU Si-Yu, WANG Ying-Lei. Preparation, Characterization and Combustion Catalytic Action of Bismuth/Zirconium Gallate[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB20130111 shu

Preparation, Characterization and Combustion Catalytic Action of Bismuth/Zirconium Gallate

1.
Science and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Xi’an 710065, P. R. China

Received Date: 24 October 2012
Available Online: 11 January 2013
Fund Project: 国家自然科学基金(21173163) (21173163)燃烧与爆炸技术重点实验室基金(9140C350307110C3506)资助项目 (9140C350307110C3506)

Bismuth/zirconium gallate (Gal-BiZr) was synthesized from gallic acid, bismuth nitrate, and zirconyl nitrate firstly, and characterized by elemental analysis, X-ray fluorescence (XRF), and Fourier transform infrared (FTIR) spectroscopies. The thermal behavior and decomposition mechanism of Gal-BiZr in a temperature-programmed mode were investigated by thermogravimetric (TG) analysis, differential scanning colorimetry (DSC), and condensed phase thermolysis/FTIR techniques. The decomposition products of Gal-BiZr are Bi₂O₃, ZrO₂, and C. Samples of propellants containing Gal-BiZr were prepared by extrusion technology, and the effect of Gal-BiZr on double-base (DB) propellant combustion properties was investigated. Gal-BiZr exhibits od catalytic behavior in the combustion of DB and Hexogeon (RDX)- CMDB propellants.
- Physical chemistry,
- Bismuth/zirconium gallate,
- Propellant,
- Thermal behavior,
- Decomposition mechanism,
- Combustion property,
- Catalytic action
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