Citation: YE Yong-Wei, WANG Xi, ZHENG Wan-Fang, LI Mei-Chao, MA Chun-An. Electrooxidation Reaction of 3-Bromobenzoic Acid on Pt Electrode[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 553-558. doi: 10.3866/PKU.WHXB201301101 shu

Electrooxidation Reaction of 3-Bromobenzoic Acid on Pt Electrode

1.
Research Center of Analysis and Measurement, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Received Date: 30 October 2012
Available Online: 10 January 2013
Fund Project: 国家重点基础研究发展计划(973)项目(2012CB722604) (973)项目(2012CB722604)国家自然科学基金(21206147)资助 (21206147)

Electrochemical oxidation of 3-bromobenzoic acid (3-BBA) on a Pt electrode in alkali solution was studied by cyclic voltammetry and in situ Fourier transform infrared (FTIR) spectroscopy. The Pt electrode exhibited od performance for the electrooxidation of 3-BBA. At low oxidation potential (1000 mV), one electron was removed from the 3-BBA radical anion and the corresponding free radical was generated. A Bbromobenzene free radical cation and carbon dioxide were obtained after decarboxylation. The bromobenzene cation was then attacked by the hydroxyl radical, which was adsorbed on the anode, and the bromobenzene cation intermediate product was debrominated to form phenol. When the potential shifted to more positive values, phenol was electrooxided to produce dihydroxybenzene and benzoquinone. Maleic acid and fumaric acid were also detected as the reaction products of the ring-opening reaction.
- 3-Bromobenzoic acid,
- In situ Fourier transform infrared spectroscopy,
- Electrooxidation,
- Decarboxylation reaction,
- Debromination reaction
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