Citation: XU Gui-Yin, DING Bing, NIE Ping, LUO Hong-Jun, ZHANG Xiao-Gang. Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 546-552. doi: 10.3866/PKU.WHXB201301081 shu

Preparation and Electrochemical Performance of Carbon Nanotubes/ Graphene Oxide/Sulfur Complex Cathode Material

1.
College of Material Science & Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P.R. China

Received Date: 8 October 2012
Available Online: 8 January 2013
Fund Project: 国家自然科学基金(21173120) (21173120) 江苏省自然科学基金重点专项(BK2011030) (BK2011030)南京航空航天大学研究生创新基地(实验室)开放基金(kfjj120209)资助 (实验室)开放基金(kfjj120209)

Three-dimensional (3D) hierarchical CNTs/ /S ternary composites were prepared by solution-based reaction-deposition, using graphene oxide ( ) and carbon nanotubes (CNTs) as precursors. Scanning electron microscopy (SEM) and transmission electron microscope (TEM) indicated a uniform S coating on CNTs/ which arose because of the large specific surface area. CNTs interspersed between the layers to form a 3D porous structure. Constant current charge-discharge tests showed that CNTs/ /S composites had a high discharge capacity and excellent cycling stability, and delivered a high initial discharge capacity of 904 mAh·g^-1 at 1C rate. After 50 cycles at the same rate, the reversible capacity remained at 578 mAh·g^-1.
- Lithium-sulfur battery,
- Graphene oxide,
- Carbon nanotube,
- Composite,
- Cycling performance
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