Citation: SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan. Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 460-466. doi: 10.3866/PKU.WHXB201301071 shu

Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin

1.
Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China

Received Date: 2 November 2012
Available Online: 7 January 2013
Fund Project: 国家自然科学基金(21071139) (21071139)

Increased water solubility of molybdenum trioxide (MoO₃) induced by β-cyclodextrin (CD), with solubility dependent on β-CD concentration is reported. The dynamic equilibrium established between MoO₃ precipitation and dissolution shifted towards dissolution upon the addition of aqueous β-CD, to form a bluish-grey product. This was confirmed to be of β-CD and MoO₄^2- by: (1) X-ray photoelectron spectroscopy showed decreased Mo 3d_5/2 and 3d_3/2 binding energies of the product compared with those of MoO₃; (2) a strong band at 213 nm and new broad peak near 775 nm of the product were attributed to Mo＝O and Mo―O bond absorption; (3) a downfield shift of β-CD protons due to the effect of MoO₄^2- ions. An interaction between β-CD and MoO₄^2- has been revealed and hints at the possibility of exploiting it for improving MoO₃ physical properties
- β-Cyclodextrin,
- Molybdenum trioxide,
- Molecule-ion interaction,
- Water solubility
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