Citation: SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan. Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 460-466. doi: 10.3866/PKU.WHXB201301071 shu

Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin

1.
Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China

Received Date: 2 November 2012
Available Online: 7 January 2013
Fund Project: 国家自然科学基金(21071139) (21071139)

Increased water solubility of molybdenum trioxide (MoO₃) induced by β-cyclodextrin (CD), with solubility dependent on β-CD concentration is reported. The dynamic equilibrium established between MoO₃ precipitation and dissolution shifted towards dissolution upon the addition of aqueous β-CD, to form a bluish-grey product. This was confirmed to be of β-CD and MoO₄^2- by: (1) X-ray photoelectron spectroscopy showed decreased Mo 3d_5/2 and 3d_3/2 binding energies of the product compared with those of MoO₃; (2) a strong band at 213 nm and new broad peak near 775 nm of the product were attributed to Mo＝O and Mo―O bond absorption; (3) a downfield shift of β-CD protons due to the effect of MoO₄^2- ions. An interaction between β-CD and MoO₄^2- has been revealed and hints at the possibility of exploiting it for improving MoO₃ physical properties
- β-Cyclodextrin,
- Molybdenum trioxide,
- Molecule-ion interaction,
- Water solubility
1. [1]
  
  (1) Liu, Y.; Chen, Y. Accounts Chem. Res. 2006, 39, 681. doi: 10.1021/ar0502275
2. [2]
  (2) Liu, Y.; Zhang, N.; Chen, Y.;Wang, L. H. Org. Lett. 2007, 9,315. doi: 10.1021/ol062816w
3. [3]
  (3) Cai,W. S.; Xia, B. Y.; Shao, X. G.; Maigret, B.; Pan, Z. X.Chem. Phys. Lett. 2000, 319, 708. doi: 10.1016/S0009-2614(00)00177-9
4. [4]
  (4) Jiang, J. Q.; Jiang, T.; Zhang, C. B.; Cheng, H.; Liu, X. Y.;Zhang, S.W.; Chen, M. Q. Acta Phys. -Chim. Sin. 2011, 27,2691. [江金强, 姜韬, 张成邦, 成浩, 刘晓亚, 张胜文, 陈明清. 物理化学学报, 2011, 27, 2691.] doi: 10.3866/PKU.WHXB20111019
5. [5]
  (5) Liu, L. H.; ng, Z. Q.; Zheng, Y. J.; Zhang, Q. F.; Guan, L. X.Acta Phys. -Chim. Sin. 2002, 18, 604. [刘立华, 龚竹青, 郑雅杰, 张钦发, 关鲁雄. 物理化学学报, 2002, 18, 604.] doi: 10.3866/PKU.WHXB20020707
6. [6]
  (6) Qu, X. K.; Sun, D. Z.; Zheng,W. Q.; Liu, M.;Wei, X. L. Acta Phys. -Chim. Sin. 2007, 23, 116. [曲秀葵, 孙德志, 郑文清,刘敏, 魏西莲. 物理化学学报, 2007, 23, 116.] doi: 10.3866/PKU.WHXB20070124
7. [7]
  (7) Xu, P.; Song, L. X. Acta Phys. -Chim. Sin. 2008, 24, 2214.[徐鹏, 宋乐新. 物理化学学报, 2008, 24, 2214.] doi: 10.3866/PKU.WHXB20081212
8. [8]
  (8) Xu, P.; Song, L. X. Acta Phys. -Chim. Sin. 2008, 24, 729.[徐鹏, 宋乐新. 物理化学学报, 2008, 24, 729.] doi: 10.3866/PKU.WHXB20080433
9. [9]
  (9) Chen, Y.; Liu, Y. Chem. Soc. Rev. 2010, 39, 495. doi: 10.1039/b816354p
10. [10]
  (10) Zhang, Y. M.; Yang, Z. X.; Chen, Y.; Ding, F.; Liu, Y. Cryst. Growth Des. 2012, 12, 1370. doi: 10.1021/cg201446x
11. [11]
  (11) Song, L. X.;Wang, M.; Dang, Z.; Du, F. Y. J. Phys. Chem. B2010, 114, 3404. doi: 10.1021/jp100308x
12. [12]
  (12) Hubert, C.; Denicourt-Nowicki, A.; Roucoux, A.; Landy, D.;Leger, B.; Crowyn, G.; Monflier, E. Chem. Commun. 2009,1228.
13. [13]
  (13) Yang, J.; Song, L. X.; Yang, J.; Dang, Z.; Chen, J. Dalton Trans.2012, 41, 2393. doi: 10.1039/c2dt11666a
14. [14]
  (14) Pan, S. Z.; Song, L. X.; Bai, L.;Wang, M.; Zhu, L. H.; Chen, J.Curr. Org. Chem. 2011, 15, 862. doi: 10.2174/138527211794518916
15. [15]
  (15) Dang, Z.; Song, L. X.; Pan, S. Z.;Wang, M. Acta Phys. -Chim. Sin. 2009, 25, 1059. [党政, 宋乐新, 潘淑珍, 王莽. 物理化学学报, 2009, 25, 1059.] doi: 10.3866/PKU.WHXB20090529
16. [16]
  (16) Song, L. X.; Bai, L. J. Phys. Chem. B 2009, 113, 11724. doi: 10.1021/jp902456h
17. [17]
  (17) Mhamdi, T. M.; Ghorbel, A.; Delahay, G. Catal. Today 2009,142, 239. doi: 10.1016/j.cattod.2008.07.026
18. [18]
  (18) Liu, Q.; Dong, X. H.; Xiao, G. L.; Zhao, F.; Chen, F. L. Adv. Mater. 2010, 22, 5478. doi: 10.1002/adma.v22.48
19. [19]
  (19) Bose, A. C.; Shimizu, Y.; Mariotti, D.; Sasaki, T.; Terashima, K.;Koshizaki, N. Nanotechnology 2006, 17, 5976. doi: 10.1088/0957-4484/17/24/012
20. [20]
  (20) Li, X. J.; Zhang,W. P.; Li, X.; Liu, S. L.; Huang, H. J.; Han, X.W.; Xu, L. Y.; Bao, X. H. J. Phys. Chem. C 2009, 113, 8228.doi: 10.1021/jp901103e
21. [21]
  (21) Gao, Y. L.; Fang, X. C.; Cheng, Z. M. Catal. Today 2010, 158,496. doi: 10.1016/j.cattod.2010.07.024
22. [22]
  (22) Lu, Y. K.; Xu, J. N.; Cui, X. B.; Jin, J.; Shi, S. Y.; Xu, J. Q.Inorg. Chem. Commun. 2010, 13, 46. doi: 10.1016/j.inoche.2009.10.003
23. [23]
  (23) Itoh, T.; Matsubara, I.; Shin,W.; Izu, N.; Nishibori, M. J. Ceram. Soc. Jpn. 2010, 118, 171. doi: 10.2109/jcersj2.118.171
24. [24]
  (24) Harada, A.; Kawaguchi, Y.; Nishiyama, T.; Kamachi, M.Macromol. Rapid Commun. 1997, 18, 535. doi: 10.1002/marc.1997.030180701
25. [25]
  (25) Li, J.; Li, X.; Toh, K. C.; Ni, X. P.; Zhou, Z. H.; Leong, K.W.Macromolecules 2001, 34, 8829. doi: 10.1021/ma011129b
26. [26]
  (26) Chen, Y.; Pang, Y.;Wu, J. L.; Su, Y.; Liu, J. Y.;Wang, R. B.;Zhu, B. S.; Yao, Y. F.; Yan, D. Y.; Zhu, X. Y.; Chen, Q.Langmuir 2010, 26, 9011. doi: 10.1021/la9048133
27. [27]
  (27) Okamoto, Y.; Oshima, N.; Kobayashi, Y.; Terasaki, O.;Kodairad, T.; Kubotaa, T. Phys. Chem. Chem. Phys. 2002, 4,2852.
28. [28]
  (28) Song, L. X.;Wang, M.; Pan, S. Z.; Yang, J.; Chen, J.; Yang, J.J. Mater. Chem. 2011, 21, 7982. doi: 10.1039/c1jm10252d
29. [29]
  (29) Xue, S. J.; Xiang, C. S.;Wei, Y. G.; Tao, Z.W.; Chai, A.; Bian,W. D.; Xu, Z. Cryst. Growth Des. 2008, 8, 2437. doi: 10.1021/cg8000174
30. [30]
  (30) Hayden, T. F.; Dumesic, J. A.; Sherwood, R. D.; Baker, R. T. K.J. Catal. 1987, 105, 299. doi: 10.1016/0021-9517(87)90060-1
31. [31]
  (31) Pal, M.; Hirota, K.; Tsujigami, Y.; Sakata, H. J. Phys. D: Appl. Phys. 2001, 34, 459. doi: 10.1088/0022-3727/34/4/303
32. [32]
  (32) Song, L. X.; Chen, J.; Zhu, L. H.; Xia, J.; Yang, J. Inorg. Chem.2011, 50, 7988. doi: 10.1021/ic200137f
33. [33]
  (33) Song, L. X.; Xia, J.; Dang, Z.; Yang, J.; Chen, J.;Wang, L. B.CrystEngComm 2012, 14, 2675. doi: 10.1039/c2ce06567c
34. [34]
  (34) Aritani, H.; Tanaka, T.; Funabiki, T.; Yoshida, S. J. Phys. Chem.1996, 100, 5440. doi: 10.1021/jp9525245
35. [35]
  (35) Xue, X. Y.; Chen, Z. H.; Xing, L. L.; Yuan, S.; Chen, Y. J.Chem. Commun. 2011, 47, 5205. doi: 10.1039/c1cc00076d
36. [36]
  (36) Debecker, D. P.; Schimmoeller, B.; Stoyanova, M.; Poleunis, C.;Bertrand, P.; Rodemerck, U.; Gaigneaux, E. M. J. Catal. 2011,277, 154. doi: 10.1016/j.jcat.2010.11.003
37. [37]
  (37) Dang, Z.; Song, L. X.; Yang, J.; Chen, J.; Teng, Y. Dalton Trans.2012, 41, 3006. doi: 10.1039/c2dt11794k
38. [38]
  (38) Chen, L. M.; Liu, Y. N. CrystEngComm 2011, 13, 6481. doi: 10.1039/c1ce05557g
39. [39]
  (39) Chen, J.; Song, L. X.; Yang, J.; Xia, J.; Shao, Z. C. J. Mater. Chem. 2012, 22, 6251. doi: 10.1039/c2jm00082b
1. [1]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
2. [2]
  Shuang Meng , Haixin Long , Zhou Zhou , Meizhu Rong . Inorganic Chemistry Curriculum Design and Implementation of Based on “Stepped-Task Driven + Multi-Dimensional Output” Model: A Case Study on Intermolecular Forces. University Chemistry, 2024, 39(3): 122-131. doi: 10.3866/PKU.DXHX202309008
3. [3]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
4. [4]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
5. [5]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
6. [6]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
7. [7]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
8. [8]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
9. [9]
  Fengmiao Yu , Yang Sheng , Chanyue Li , Bao Li . The Three Lives of Aspirin. University Chemistry, 2024, 39(9): 115-121. doi: 10.12461/PKU.DXHX202402033
10. [10]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
11. [11]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
12. [12]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
13. [13]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
14. [14]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
15. [15]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
18. [18]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
19. [19]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
20. [20]
  Liangyu Gong , Jie Wang , Fengyu Du , Lubin Xu , Chuanli Ma , Shihai Yan , Zhuwei Song , Fuheng Liu , Xiuzhong Wang . Construction and Practice of “One-Point, Two-Lines and Three-Sides” Innovative Experimental Platform. University Chemistry, 2024, 39(4): 26-32. doi: 10.3866/PKU.DXHX202308023

Get Citation

PDF

XML

Metrics

PDF Downloads(876)
Abstract views(793)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142